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Synthesis of amino-functionalized MCM-41 via direct co-condensation and post-synthesis grafting methods using mono-, di- and tri-amino-organoalkoxysilanesElectronic supplementary information (ESI) available: XRD patterns of (A) x-dNN-MCM-41 and (B) x-dNNN-MCM-41 after the extraction of the surfactant, 29Si MAS NMR spectra of MCM-41 samples prepared by (A) direct co-condensation and (B) post-synthesis grafting methods. See http://www.rsc.org/suppdata/jm/b3/b310576h/

Toshiyuki Yokoi、Hideaki Yoshitake、Takashi Tatsumi2004-01-01OpenAlex

Amino-functionalized mesoporous MCM-41 materials were synthesized directly by co-condensation of 3-aminopropyltrimethoxysilane (N silane), [1-(2-aminoethyl)-3-aminopropyl]trimethoxysilane (NN silane) or 1-[3-(trimethoxysilyl)propyl]diethylenetriamine (NNN silane) with tetraethyl orthosilicate. The maximum proportions…

Mesoporous Materials and CatalysisPolyoxometalates: Synthesis and ApplicationsSupercapacitor Materials and Fabrication

Hydrothermal synthesis of one-dimensional ZnO nanostructures with different aspect ratios

Bin Cheng、Edward T. Samulski2004-01-01OpenAlex

1-D ZnO nanorods with different aspect ratios were synthesized by a one-step, hydrothermal method. The ZnO nanorods grow along the [0001] direction to form single crystals. The experimental results reveal that the growth of polar inorganic crystals is sensitive to the reaction solvents.

ZnO doping and propertiesCopper-based nanomaterials and applicationsGas Sensing Nanomaterials and Sensors

Structural characteristics defining high barrier properties in polymeric materials

José M. Lagarón、Rafael Catalá、Rafael Gavara2004-01-01OpenAlex

The packaging industry has dramatically increased the number of packaging systems and designs made of plastics over recent decades. Plastics, in contrast with more traditional packaging materials such as glass and metals, are permeable systems that permit the exchange of low molecular weight compounds, e.g. gases and…

biodegradable polymer synthesis and propertiesPolymer Nanocomposites and PropertiesPolymer crystallization and properties

Carboxyl group (–CO 2 H) functionalized ferrimagnetic iron oxide nanoparticles for potential bio-applications

Yu Shi、Gan Moog Chow2004-01-01OpenAlex

A new approach to prepare surface-functionalized magnetic nanoparticles by synthesis of poly(methacrylic acid) (PMAA) coated maghemite nanoparticles in aqueous solution is reported. Maghemite (γ-Fe2O3) nanoparticles with an average diameter of 8 ± 2 nm were fabricated and subsequently coated with PMAA by emulsion poly…

Nanomaterials for catalytic reactionsNanoparticle-Based Drug DeliveryGraphene research and applications

Relationship between antibacterial activity of chitosan and surface characteristics of cell wall

Ying-chienCHUNG、Ya-pingSU、Chiing-changCHEN 等 7 位作者2004-01-01OpenAlex

AIM: Five representative waterborne pathogens were used to illustrate the relationship between chitosan's antibac-terial activity and the surface characteristics of the bacterial cell wall. METHODS: Chitosan was prepared with averaged 75 % or 95 % deacetylated degree to examine its antibacterial activity against water…

Nanocomposite Films for Food PackagingAntimicrobial agents and applications

Electrospinning of chitosan solutions in acetic acid with poly(ethylene oxide)

Bin Duan、Cunhai Dong、Xiaoyan Yuan 等 4 位作者2004-01-01OpenAlex

Electrospinning of chitosan solutions with poly(ethylene oxide) (PEO) in an aqueous solution of 2 wt% acetic acid was studied. The properties of the chitosan/PEO solutions, including conductivity, surface tension and viscosity, were measured. Morphology of the electrospun chitosan/PEO was observed by using scanning el…

Electrospun Nanofibers in Biomedical ApplicationsAdvanced Sensor and Energy Harvesting MaterialsConducting polymers and applications

Mechanical Properties and Shape Memory Behavior of Ti-Nb Alloys

Hee Young Kim、Satoru Hashimoto、Jae Il Kim 等 5 位作者2004-01-01OpenAlex

Mechanical properties and shape memory behavior of Ti-(20—29)at%Nb alloys were investigated in order to develop Ni-free biomedical shape memory alloys. The Ti-Nb alloys were fabricated by arc melting method. The ingots were cold-rolled with a reduction up to 95% in thickness and then solution treated at 1173 K for 1.8…

Advanced materials and compositesShape Memory Alloy TransformationsTitanium Alloys Microstructure and Properties

Solvent-drop grinding: green polymorph control of cocrystallisationElectronic supplementary information (ESI) available: additional powder XRD patterns. See http://www.rsc.org/suppdata/cc/b4/b400978a/

A.V. Trask、W. D. Samuel Motherwell、William Jones2004-01-01OpenAlex

By grinding with a minimal addition of a solvent of appropriate polarity, control over the polymorphic outcome of a novel cocrystallisation involving the model pharmaceutical compound caffeine may be achieved.

Crystallography and molecular interactionsDrug Solubulity and Delivery SystemsCrystallization and Solubility Studies

Synthesis and Characterization of (La[sub 0.75]Sr[sub 0.25])Cr[sub 0.5]Mn[sub 0.5]O[sub 3−δ], a Redox-Stable, Efficient Perovskite Anode for SOFCs

Shanwen Tao、John T. S. Irvine2004-01-01OpenAlex

Perovskite-related materials, (LSCM), have been synthesised and examined as potential anode materials for solid oxide fuel cells (SOFCs). exhibits a rhombohedral structure. It appears to be chemically compatible with yttria-stabilized zirconia (YSZ) to at least 1300°C. At 900°C, its electrical conductivity is about 38…

Electronic and Structural Properties of OxidesMagnetic and transport properties of perovskites and related materialsAdvancements in Solid Oxide Fuel Cells

Synthesis of new nanoporous carbon materials using nanostructured silica materials as templates

Jinwoo Lee、Sang Jin Han、Taeghwan Hyeon2004-01-01OpenAlex

In this review, we summarize recent reports on the synthesis of various nanoporous carbon materials. Many nanoporous carbon materials having variable pore sizes and pore structures have been synthesized using appropriate nanostructured silica materials as templates. Nanoporous carbons with high pore volumes and unifor…

Supercapacitor Materials and FabricationCatalytic Processes in Materials ScienceMesoporous Materials and Catalysis

Carbon nanotubes as field emission sources

W. I. Milne、K. B. K. Teo、G.A.J. Amaratunga 等 9 位作者2004-01-01OpenAlex

Micro and nano-structurally rich carbon materials are alternatives to conventional metal/silicon tips for field emission sources. In particular, carbon nanotubes exhibit extraordinary field emission properties because of their high electrical conductivity, their high aspect ratio “whisker-like” shape for optimum geome…

Carbon Nanotubes in CompositesGraphene research and applicationsMechanical and Optical Resonators

Hierarchical self-assembly in polymeric complexes: Towards functional materials

Olli Ikkala、Gerrit ten Brinke2004-01-01OpenAlex

Combination of self-assembly at different length scales leads to structural hierarchies. It offers rich possibilities to construct nanostructured matter, nanoscale parts, and switching (responsive) properties based on the phase transitions of the self-assembled structures. Complexation of oligomeric amphiphiles to pol…

Block Copolymer Self-AssemblyPolymer Surface Interaction StudiesAdvanced Polymer Synthesis and Characterization

Porous calcium carbonate microparticles as templates for encapsulation of bioactive compounds

Gleb B. Sukhorukov、Dmitry Volodkin、Anja M. Günther 等 6 位作者2004-01-01OpenAlex

The paper describes the preparation and characterisation of porous calcium carbonate microparticles with an average size of 5 µm and their use for encapsulation of biomacromolecules. The average pore size of about 30–50 nm enables size selective and time-dependent permeation of different macromolecules. Layer-by-layer…

Electrospun Nanofibers in Biomedical ApplicationsPolymer Surface Interaction Studiesbiodegradable polymer synthesis and properties

Hydrogen in oxides

Truls Norby、Marius Widerøe、Ronny Glöckner 等 4 位作者2004-01-01OpenAlex

The paper reviews the history and present understanding of protons in oxides; their defect chemistry, thermodynamics, and transport. Focus is put on correlations between hydration thermodynamics and other materials properties which may help to predict proton uptake and proton conduction in oxides. Also effects of defe…

Advancements in Solid Oxide Fuel CellsThermal Expansion and Ionic ConductivityNuclear Materials and Properties

Electrochemical Characterization of La[sub 0.6]Sr[sub 0.4]Co[sub 0.2]Fe[sub 0.8]O[sub 3] Cathodes for Intermediate-Temperature SOFCs

Audrey Esquirol、Nigel P. Brandon、John A. Kilner 等 4 位作者2004-01-01OpenAlex

The electrochemical properties of La 0.6 Sr 0.4 Co 0.2 Fe 0.8 O 3 (LSCF) have been assessed for its application as a cathode in intermediate-temperature solid oxide fuel cells. van der Pauw dc conductivity, two-electrode impedance, and three-electrode measurements were carried out to investigate the kinetics of the ox…

Magnetic and transport properties of perovskites and related materialsElectronic and Structural Properties of OxidesAdvancements in Solid Oxide Fuel Cells

Silica formation in diatoms: the function of long-chain polyamines and silaffins

Manfred Sumper、Nils Kröger2004-01-01OpenAlex

The stunning silica structures formed by diatoms are among the most remarkable examples of biological nanofabrication. In recent years, insight into the molecules and mechanism that allow diatoms to perform silica morphogenesis under ambient conditions has been gained.

Paleontology and Stratigraphy of FossilsMesoporous Materials and CatalysisDiatoms and Algae Research

In Vivo Bone Tissue Engineering Using Mesenchymal Stem Cells on a Novel Electrospun Nanofibrous Scaffold

Michael Shin、Hiroshi Yoshimoto、Joseph P. Vacanti2004-01-01OpenAlex

The objective of this study was to assess bone formation from mesenchymal stem cells (MSCs) on a novel nanofibrous scaffold in a rat model. A highly porous, degradable poly(epsilon-caprolactone) (PCL) scaffold with an extracellular matrix-like topography was produced by electrostatic fiber spinning. MSCs derived from…

Tissue Engineering and Regenerative MedicineBone Tissue Engineering MaterialsElectrospun Nanofibers in Biomedical Applications

Bio-inspired crystal morphogenesis by hydrophilic polymers

Shu‐Hong Yu、Helmut Cölfen2004-01-01OpenAlex

The latest advances in hydrophilic polymer controlled morphosynthesis and bio-inspired mineralization of various technically important inorganic crystals are reviewed with a focus on how to generate inorganic crystals with unusual structural specialty and complexity by double hydrophilic block copolymers (DHBCs). The…

Calcium Carbonate Crystallization and InhibitionPolymer Surface Interaction StudiesDiatoms and Algae Research

Supramolecular chirality of self-assembled systems in solution

Miguel A. Mateos‐Timoneda、Mercedes Crego‐Calama、David N. Reinhoudt2004-01-01OpenAlex

Self-assembly plays an important role in the formation of many (chiral) biological structures, such as DNA, alpha-helices or beta-sheets of proteins. This process, which is the main tool of Supramolecular Chemistry (i.e. the chemistry of the molecular assemblies and of the intermolecular bonds), starts to play a signi…

Supramolecular Self-Assembly in MaterialsDNA and Nucleic Acid ChemistrySurface Chemistry and Catalysis

Probing the Electronic Structure of Complex Systems by ARPES

A. Damascelli2004-01-01OpenAlex

Angle-resolved photoemission spectroscopy (ARPES) is one of the most direct methods of studying the electronic structure of solids. By measuring the kinetic energy and angular distribution of the electrons photoemitted from a sample illuminated with sufficiently high-energy radiation, one can gain information on both…

Advanced Chemical Physics StudiesElectron and X-Ray Spectroscopy TechniquesElectronic and Structural Properties of Oxides