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Determination of nucleation parameters and the solid liquid interfacial energy of the KCl‐ethanol‐water system

Waid Omar、Joachim Ulrich2007-04-04Crystal Research and Technology

Abstract The kinetic parameters of homogeneous nucleation of KCl in different ethanol‐water solvent mixtures were determined at 25°C from the experimental measurements of the width of the metastable zone at different cooling rates. The ethanol mass ratio in the ethanol water solvent mixture was varied from 0‐0.9 and t…

Crystallization and Solubility StudiesChemical and Physical Properties in Aqueous Solutionsnanoparticles nucleation surface interactions

Growth and characterization of semiorganic nonlinear optical tetrakis thiourea nickel chloride single crystals

A. Bhaskaran、C. M. Ragavan、R. Sankar 等 5 位作者2007-04-04Crystal Research and Technology

Abstract A new nonlinear optical material tetrakis thiourea nickel chloride (TTNC) was synthesized and single crystals were grown from mixed solvent of water and isopropanol by both slow evaporation and slow cooling methods. The grown crystals were characterized by powder X‐ray diffraction analyses to confirm the crys…

Nonlinear Optical Materials ResearchThermal and Kinetic AnalysisChemical Thermodynamics and Molecular Structure

Domain Size Control in Self-Assembling Rod−Coil Block Copolymer and Homopolymer Blends

Yuefei Tao、Bradley D. Olsen、Venkat Ganesan 等 4 位作者2007-04-04Macromolecules

The addition of homopolymers to a self-assembling rod−coil block copolymer is demonstrated to be a flexible route toward domain size control. Molecular weight matched rod-like homopolymers interdigitate with the rod-blocks within their respective lamellae. As a result of the interdigitation, the coil blocks must rearr…

Organic Electronics and PhotovoltaicsBlock Copolymer Self-AssemblyNanopore and Nanochannel Transport Studies

Modification of WO3thin films by MeV N+-ion beam irradiation

R. Sivakumar、C. Sanjeeviraja、M. Jayachandran 等 7 位作者2007-04-04Journal of Physics Condensed Matter

In this paper, we report on modification of the structural, optical, vibrational, and surface morphological properties of 2 MeV N(+)-ion irradiated WO(3) thin films at different fluences (up to 1 × 10(15) ions cm(-2)). Although we observe irradiation induced grain growth, no structural phase transition takes place in…

ZnO doping and propertiesGas Sensing Nanomaterials and SensorsTransition Metal Oxide Nanomaterials

Drastic Modification of the Dispersion State of Submicron Silica during Biaxial Deformation of Poly(ethylene terephthalate)

Stéphane Jeol、Françoise Fenouillot、Alain Rousseau 等 6 位作者2007-04-04Macromolecules

Deformation-induced modification of the dispersion state of silica nanoparticles in poly(ethylene terephthalate) (PET) has been characterized by means of transmission electron microscopy (TEM) and wide-angle X-ray diffraction (WAXD). We focused on the biaxial deformation applied at a temperature just above the glass t…

Polymer crystallization and propertiesPolymer Nanocomposites and Propertiesbiodegradable polymer synthesis and properties

The coupling vibration of fluid-filled carbon nanotubes

X Y Wang、X Wang、Guodong Sheng2007-04-04Journal of Physics D Applied Physics

Carbon nanotubes (CNTs) have substantial promise as nanocontainers filled with fluid in their hollow cavity in nanotechnology. This paper reports the result of an investigation into the influence of internal fluid on the coupling vibration of fluid-filled CNTs. The coupling vibrational behaviour of fluid-filled CNTs u…

Carbon Nanotubes in CompositesNonlocal and gradient elasticity in micro/nano structuresNanotechnology research and applications

Memory effect in the adsorption phenomena of neutral particles

Rafael S. Zola、E. K. Lenzi、L. R. Evangelista 等 4 位作者2007-04-04Physical Review E

The adsorption-desorption phenomenon of neutral particles dissolved in an isotropic fluid is investigated by using a nonsingular kernel in the kinetic equation at the limiting surfaces. To account for the relevance of a memory effect, three types of kernels in the kinetic equation are considered. Similar kernels have…

Liquid Crystal Research AdvancementsMaterial Dynamics and PropertiesSurfactants and Colloidal Systems

Charge transport in carbon nanotubes: quantum effects of electron–phonon coupling

Stephan Roche、Jie Jiang、Luis E. F. Foa Torres 等 4 位作者2007-04-04Journal of Physics Condensed Matter

This review deals with the role of electron-phonon (e-ph) coupling in quantum transport of carbon nanotubes. First, the case of low-energy phonons and weak localization phenomena is addressed, followed by a summary of inelastic scattering lengths within the Fermi golden rule. A second part outlines the contribution of…

Carbon Nanotubes in CompositesGraphene research and applicationsMechanical and Optical Resonators

Fractionated crystallization of polypropylene droplets produced by nanolayer breakup

Yuliang Jin、A. Hiltner、E. Baer2007-04-04Journal of Polymer Science Part B Polymer Physics

Abstract Layer‐multiplying coextrusion was used to fabricate assemblies of 257 layers, in which polypropylene (PP) nanolayers alternated with thicker polystyrene (PS) layers. The PP layer thickness was varied from 12 to 200 nm. When the assembly was heated into the melt, interfacial instability‐driven breakup of the t…

Polymer crystallization and propertiesBlock Copolymer Self-AssemblyNanomaterials and Printing Technologies

Synthesis, Structures and Optical Power Limiting of Some Transition Metal and Lanthanide Monoporphyrinate Complexes Containing Electron‐Rich Diphenylamino Substituents

Shitao Fu、Xunjin Zhu、Guijiang Zhou 等 7 位作者2007-04-04European Journal of Inorganic Chemistry

Abstract Transition metal and lanthanide monoporphyrinate complexes based on 5,10,15,20‐tetrakis[ p ‐(diphenylamino)phenyl]‐21 H ,23 H ‐porphine (H 2 tdpapp) have been synthesized and characterized and the X‐ray crystal structures of the palladium and platinum analogues [M(tdpapp)] (M = Pd, Pt) determined. Experimenta…

Porphyrin and Phthalocyanine ChemistryPhotochemistry and Electron Transfer StudiesNonlinear Optical Materials Studies

Hysteretic metal–ferroelectric– semiconductor capacitors based on PZT/ZnO heterostructures

E. Cagin、D Y Chen、J. J. Siddiqui 等 4 位作者2007-04-04Journal of Physics D Applied Physics

Interfacing of ferroelectric and semiconductor materials provides a means of coupling unique properties associated with ferroelectric materials to high performance semiconductor devices. In this work we report the electronic properties of ferroelectric/ZnO heterostructures, where (Pb,Zr)TiO3 (PZT) is used as a prototy…

Ferroelectric and Piezoelectric MaterialsAdvanced Sensor and Energy Harvesting MaterialsMultiferroics and related materials

Factors determining properties of multi-walled carbon nanotubes/fibres deposited by PECVD

Martin S. Bell、K. B. K. Teo、W. I. Milne2007-04-04Journal of Physics D Applied Physics

This paper presents a number of factors which have been found to be important to the growth of carbon nanotubes and nanofibres by plasma enhanced chemical vapour deposition. The effect of the electric field in a plasma discharge on nanotube growth is investigated and shown to be important in achieving nanotube alignme…

Carbon Nanotubes in CompositesGraphene research and applicationsNanotechnology research and applications

Plasma nanofabrications and antireflection applications

Jiann Shieh、Chia‐Hua Lin、Min-Hyeok Yang2007-04-04Journal of Physics D Applied Physics

Plasma fabrication provides an approach to create nanostructured materials. We summarize recent studies on the quantum dot, nanograss, porous film and nanocone that have been developed using plasma methods to date and investigate the antireflection properties of the nanograss by spectrophotometric measurements and rig…

Metal and Thin Film MechanicsAdvanced Surface Polishing TechniquesOptical Coatings and Gratings

High Thermal Conductive Si3N4 Particle Filled Epoxy Composites With a Novel Structure

Hong He、Renli Fu、Yanchun Han 等 5 位作者2007-04-04Journal of Electronic Packaging

Traditionally, large quantities of ceramic fillers are added to polymers in order to obtain high thermally conductive polymer composites, which are used for electronic encapsulants. However, that is not cost effective enough. In this study, Si3N4 particle filled epoxy composite with a novel structure was fabricated by…

Epoxy Resin Curing ProcessesThermal properties of materialsDielectric materials and actuators

A plasma process for the synthesis of cubic-shaped silicon nanocrystals for nanoelectronic devices

Ameya Bapat、Marco Gatti、Yong-Ping Ding 等 5 位作者2007-04-04Journal of Physics D Applied Physics

Low pressure silane plasmas are known for their ability to synthesize silicon nanoparticles via gas phase nucleation. While in the past this particle formation has often been considered from the viewpoint of a contamination problem in semiconductor processing, we here describe a silane low pressure plasma that enables…

Thin-Film Transistor TechnologiesSilicon Nanostructures and PhotoluminescenceNanowire Synthesis and Applications

Kinetic Improvement in the Mg(NH2)2−LiH Storage System by Product Seeding

Andrea Sudik、Jun Yang、Devin Halliday 等 4 位作者2007-04-04The Journal of Physical Chemistry C

Mg(NH 2 ) 2 −2LiH is considered a promising hydrogen storage composition because of its reversibility, moderate operating conditions, and favorable thermodynamics. Two barriers which remain for this system are reducing (eliminating) ammonia release which occurs in parallel with hydrogen desorption and further reducing…

Hydrogen Storage and MaterialsHybrid Renewable Energy SystemsAmmonia Synthesis and Nitrogen Reduction

Cell Adhesion Properties on Photochemically Functionalized Diamond

Kwok Feng Chong、Kian Ping Loh、Sri Ram Krishna Vedula 等 8 位作者2007-04-04Langmuir

The biocompatibility of diamond was investigated with a view toward correlating surface chemistry and topography with cellular adhesion and growth. The adhesion properties of normal human dermal fibroblast (NHDF) cells on microcrystalline and ultrananocrystalline diamond (UNCD) surfaces were measured using atomic forc…

Diamond and Carbon-based Materials ResearchForce Microscopy Techniques and ApplicationsLubricants and Their Additives

Growth and characterization of a novel organic NLO crystal: 4 – ethoxy benzaldehyde – n – methyl 4 – stilbazolium tosylate

K. Jagannathan、S. Kalainathan、T. Gnanasekaran 等 5 位作者2007-04-04Crystal Research and Technology

Abstract The organic material 4‐Ethoxybenzaldehyde‐N‐methyl 4‐Stilbazolium Tosylate (EBST) is a new NLO material and new derivative in Stilbazolium Tosylate family. In this work we synthesized the EBST, the derivative of DAST. By slow evaporation method, we have grown the EBST crystal. Powder XRD confirms the crystall…

Crystal structures of chemical compoundsNonlinear Optical Materials ResearchAcoustic Wave Resonator Technologies

“Living” Polymer Beads in Supercritical CO2

Kristofer J. Thurecht、Andrew M. Gregory、Wenxin Wang 等 4 位作者2007-04-04Macromolecules

ADVERTISEMENT RETURN TO ISSUECommunication to the...Communication to the EditorNEXT"Living" Polymer Beads in Supercritical CO2Kristofer J. Thurecht, Andrew M. Gregory, Wenxin Wang, and Steven M. HowdleView Author Information School of Chemistry, University of Nottingham, University Park, Nottingham, NG7 2RD, United Ki…

Advanced Polymer Synthesis and CharacterizationIonic liquids properties and applicationsLuminescence and Fluorescent Materials

Toward Self-Assembled Ferroelectric Random Access Memories: Hard-Wired Switching Capacitor Arrays with Almost Tb/in.2 Densities

P. R. Evans、XinHau Zhu、Paul N. W. Baxter 等 10 位作者2007-04-04Nano Letters

We report on the successful fabrication of arrays of switchable nanocapacitors made by harnessing the self-assembly of materials. The structures are composed of arrays of 20-40 nm diameter Pt nanowires, spaced 50-100 nm apart, electrodeposited through nanoporous alumina onto a thin film lower electrode on a silicon wa…

Ferroelectric and Piezoelectric MaterialsAdvanced Sensor and Energy Harvesting MaterialsAnodic Oxide Films and Nanostructures