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Wide‐band reflective polarizers from cholesteric liquid crystals with stable optical properties

Jiumei Xiao、Hui Cao、Wanli He 等 8 位作者2007-05-16Journal of Applied Polymer Science

Abstract A wide‐band reflective polarizer from glassy siloxane cyclic side‐chain liquid crystals with stable optical properties was developed. The pitch gradient that formed was first stored by rapid cooling, which, by preventing the crystallization of glassy materials, was a very easy way of keeping the molecular arr…

Liquid Crystal Research AdvancementsPhotonic Crystals and ApplicationsPhotochromic and Fluorescence Chemistry

Probing Surface Oxidation of Reduced Uranium Dioxide Thin Film Using Synchrotron Radiation

Sanjaya D. Senanayake、Geoffrey I. N. Waterhouse、A. S. Y. Chan 等 6 位作者2007-05-16The Journal of Physical Chemistry C

The work presents a study of the formation of defects created by argon ion sputtering of UO 2 thin film surfaces using high-resolution X-ray photoelectron spectroscopy with photon energy of 625 eV. Stable-defected surfaces of UO 2- x were monitored by the uranium core level lines found at the low-binding energy side o…

Radioactive element chemistry and processingNuclear Materials and PropertiesNuclear Physics and Applications

Double Perovskites with Ferromagnetism Above Room Temperature

David Serrate、J. M. De Teresa、M. R. Ibarra2007-05-16ChemInform

Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.

Perovskite Materials and ApplicationsMagnetic and transport properties of perovskites and related materialsThermal Expansion and Ionic Conductivity

Temperature Dependence of Optical Gain in CdSe/ZnS Quantum Rods

Miri Kazes、Dan Oron、Itzhak Shweky 等 4 位作者2007-05-16The Journal of Physical Chemistry C

We studied the optical gain characteristics of CdSe/ZnS core/shell colloidal quantum rods, investigated their temperature dependence, and compared the gain properties with quantum dots (QD). The gain was measured systematically for close-packed films of rods and dots under quasi-CW nanosecond optical pumping, using th…

Quantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin FilmsMolecular Junctions and Nanostructures

High-Purity Diamagnetic Single-Wall Carbon Nanotube Buckypaper

Younghyun Kim、O. N. Torrens、James M. Kikkawa 等 6 位作者2007-05-16Chemistry of Materials

We describe a novel purification process for single-wall carbon nanotube (SWNT) materials that removes non-nanotube carbon and reduces ferromagnetic impurities to levels at which native SWNT magnetic properties predominate. Ferromagnetism is reduced from 1.04 to less than 0.013 emu/g by magnetic gradient filtration. T…

Carbon Nanotubes in CompositesGraphene research and applicationsIon-surface interactions and analysis

Synthesis and characterization of hyperbranched polyesters and polyurethane coatings

Savita Kumari、Aswini K. Mishra、D. K. Chattopadhyay 等 4 位作者2007-05-16Journal of Polymer Science Part A Polymer Chemistry

Abstract Polyurethane (PU) coatings are widely used for variety of high‐performance applications in today's coating technology. The emerging hyperbranched polymers having three‐dimensional morphology have opened a new avenue to tailor the architecture of PU coatings. The methodology followed here is based on preparati…

Fuel Cells and Related MaterialsDendrimers and Hyperbranched PolymersSynthesis and properties of polymers

Diameter-Dependent Elastic Modulus Supports the Metastable-Catalyst Growth of Carbon Nanotubes

Kyumin Lee、Branimir Lukić、Arnaud Magrez 等 7 位作者2007-05-16Nano Letters

We measured the elastic modulus of individual multiwalled carbon nanotubes (MWCNTs) grown by catalytic chemical vapor deposition (CVD) over a broad diameter range (10-25 nm). Alternating current (ac) dielectrophoresis was used for efficient tube deposition, and atomic force microscope (AFM) force-displacement curve te…

Carbon Nanotubes in CompositesForce Microscopy Techniques and Applicationsnanoparticles nucleation surface interactions

Seasonal variations of epilithic diatoms on different hard substrates, in the northern Adriatic Sea

Cecilia Totti、Emellina Cucchiari、Mario De Stefano 等 6 位作者2007-05-16Journal of the Marine Biological Association of the United Kingdom

The colonization of epilithic diatoms on artificial hard substrates (marble, quartzite and slate) was investigated on a seasonal basis in a subtidal site of the northern Adriatic Sea to determine if substrate-dependent differences in colonization occurs and to define the seasonal variations of microepilithic communiti…

Marine and coastal ecosystemsMarine Biology and Ecology ResearchDiatoms and Algae Research

Solid Solubility and Thermal Expansion in a LaPO 4 –YPO 4 System

P. Mogilevsky、Emmanuel E. Boakye、Randall S. Hay2007-05-16Journal of the American Ceramic Society

The composition and lattice parameters of co‐precipitated (La 0.3 Y 0.7 ) orthophosphate were studied using X‐ray diffraction (XRD), transmission electron microscopy (TEM), and energy dispersive X‐ray spectroscopy (EDX). The results indicate that the as‐precipitated powder consists of single‐phase (La 0.3 Y 0.7 PO 4 ·…

Ferroelectric and Piezoelectric MaterialsMicrowave Dielectric Ceramics SynthesisNuclear materials and radiation effects

Properties of films from corn zein reacted with glutaraldehyde

David J. Sessa、Abdellatif A. Mohamed、Jeffrey A. Byars 等 5 位作者2007-05-16Journal of Applied Polymer Science

Abstract To improve the mechanical properties of zein films, a commercial white zein was reacted in glacial acetic acid (HAc) with glutaraldehyde (GDA) from 0.5 to 16% by weight based on the weight of zein. Amounts of 4% or higher GDA‐modified zein, when cured in a closed system, generated a gel. That gel was insolubl…

Nanocomposite Films for Food PackagingElectrospun Nanofibers in Biomedical ApplicationsAdditive Manufacturing and 3D Printing Technologies

Spontaneous Assembly of Magnetic Microspheres

Muhammet S. Toprak、Brandon J. McKenna、Maria Mikhaylova 等 5 位作者2007-05-16Advanced Materials

The first use of magnetic nanoparticles (MNPs) as assembling components in complex coacervation is presented. The single-step formation of MNP-based microspheres (see figure) can be considered as a NP self-assembly process induced by the presence of polyelectrolytes, in which solid microspheres are rapidly generated a…

Proteins in Food SystemsPolymer Surface Interaction StudiesPickering emulsions and particle stabilization

Magnetic properties of bulk Fe-doped indium oxide

David Bérardan、Emmanuel Guilmeau2007-05-16Journal of Physics Condensed Matter

This paper presents the influence of the iron fraction and of the sintering atmosphere on the magnetic properties of bulk iron-doped indium oxide In 2− x Fe x O 3 . The formation of a solid solution between β - Fe 2 O 3 and In 2 O 3 up to x ∼0.3 under argon atmosphere and x ∼0.55 under air has been evidenced. All sing…

ZnO doping and propertiesMultiferroics and related materialsTransition Metal Oxide Nanomaterials

LiNaSiB3O7(OH) – novel structure of the new borosilicate mineral jadarite determined from laboratory powder diffraction data

Pamela S. Whitfield、Y. Le Page、Joel D. Grice 等 10 位作者2007-05-16Acta Crystallographica Section B Structural Science

The structure of a new mineral jadarite, LiNaSiB(3)O(7)(OH) (IMA mineral 2006-36), has been determined by simulated annealing and Rietveld refinement of laboratory X-ray powder diffraction data. The structure contains a layer of corner-sharing, tetrahedrally coordinated Li, Si and B forming an unbranched vierer single…

Crystal Structures and PropertiesChemical Synthesis and CharacterizationX-ray Diffraction in Crystallography

Surface Enhanced Raman Scattering, in Situ Spectro-Electrochemical, and Electrochemical Impedance Spectroscopic Investigations of 2-Amino-5-mercapto-1,3,4-thiadiazole Monolayers at a Silver Electrode

Haifeng Yang、Xiaojing Sun、Junwu Zhu 等 6 位作者2007-05-16The Journal of Physical Chemistry C

At a silver surface, surface-enhanced Raman scattering (SERS) technique along with the self-assembled monolayers (SAMs) method was performed to observe the adsorption behavior of AMT as a protective reagent for metals from corrosion. For 20 h of self-assembling, the time-dependent SERS spectra show that a stable AMT m…

Gold and Silver Nanoparticles Synthesis and ApplicationsMolecular Junctions and NanostructuresElectrochemical Analysis and Applications

Surface and Interfacial Segregation in Blends of Polystyrene with Functional End Groups and Deuterated Polystyrene

Daisuke Kawaguchi、Keiji Tanaka、Naoya Torikai 等 5 位作者2007-05-16Langmuir

The effect of chain-end chemistry on surface and interfacial segregation in symmetric blends of polystyrene (hPS)/deuterated polystyrene (dPS) has been investigated by X-ray photoelectron and secondary ion mass spectroscopy in conjunction with neutron reflectivity measurements. Alpha,omega-fluoroalkyl- and alpha,omega…

Polymer crystallization and propertiesMaterial Dynamics and PropertiesMaterial Properties and Processing

Strongly renormalized quasi-two-dimensional electron gas in a heterostructure with correlation effects

Andreas Rüegg、S. Pilgram、Manfred Sigrist2007-05-16Physical Review B

We present aspects of strong electron correlation in a model of a $BI∕M∕BI$ heterostructure where $BI$ is a band insulator and $M$ can be tuned from a metal to a Mott insulator by varying the on-site repulsion. An effective one-dimensional Schr\"odinger equation for the low-energy part is derived in the framework of t…

Quantum and electron transport phenomenaMagnetic and transport properties of perovskites and related materialsElectronic and Structural Properties of Oxides

Influence of Phase Formation on Dielectric Properties of Si 3 N 4 Ceramics

Junqi Li、Fa Luo、Dongmei Zhu 等 4 位作者2007-05-16Journal of the American Ceramic Society

The influence of phase formation on the dielectric properties of silicon nitride (Si 3 N 4 ) ceramics, which were produced by pressureless sintering with additives in MgO–Al 2 O 3 –SiO 2 system, was investigated. It seems that the difference in the dielectric properties of Si 3 N 4 ceramics sintered at different tempe…

Advanced ceramic materials synthesisSemiconductor materials and devicesMXene and MAX Phase Materials

Nonlocal optical effects on the fluorescence and decay rates for admolecules at a metallic nanoparticle

Jason Vielma、Paul Leung2007-05-16The Journal of Chemical Physics

A phenomenological model is implemented to study the decay rates of fluorescing molecules in the vicinity of a metallic nanoparticle, wherein the nonlocal optical response of the particle is accounted for via the hydrodynamic model for the description of the free electrons in the metal. These nonlocal effects are exam…

Gold and Silver Nanoparticles Synthesis and ApplicationsPlasmonic and Surface Plasmon ResearchSpectroscopy and Quantum Chemical Studies

Temperature Sensitivity Control of Alkylamide-Terminated Poly(amidoamine) Dendrimers Induced by Guest Molecule Binding

Kenji Kono、Takuma MIYOSHI、Yasuhiro Haba 等 6 位作者2007-05-16Journal of the American Chemical Society

We examined the effect of binding of rose bengal (RB) to alkylamide-terminated PAMAM G5 dendrimers on their temperature-sensitive properties. The cloud point of aqueous solutions of the isobutyramide-terminated dendrimer decreased with increasing amount of RB molecules bound to the dendrimer. The propylamide-terminate…

Advanced Polymer Synthesis and CharacterizationFuel Cells and Related MaterialsDendrimers and Hyperbranched Polymers

Stability for Function Trade-Offs in the Enolase Superfamily “Catalytic Module”,

Ray A. Nagatani、Ana Gonzalez、Brian K. Shoichet 等 5 位作者2007-05-16Biochemistry

Enzyme catalysis reflects a dynamic interplay between charged and polar active site residues that facilitate function, stabilize transition states, and maintain overall protein stability. Previous studies show that substituting neutral for charged residues in the active site often significantly stabilizes a protein, s…

Protein Structure and DynamicsEnzyme Structure and FunctionBiochemical and Molecular Research