Materials Literature
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Organic-inorganic nanoporous silica sol-gel glasses constitute the ideal support for protein bio-encapsulation and to study the different factors influencing the protein folding process in a crowded environment. Due to the facile silica surface modifications with desired Si-substituted organic groups from organosilane…
Abstract The coalescence, continuity development, dynamic and static mechanical properties and interfacial interactions are studied for polycaprolactone/thermoplastic starch blends. These blends, prepared by a one‐step extrusion process, demonstrate the features of a highly interacting system and the tensile mechanica…
We utilize a vapor deposition setup and cross-diffusion of functionalized chlorosilanes under dynamic vacuum to generate a nearly linear gradient in surface energy and composition on a silicon substrate. The gradient can be tuned by manipulating chlorosilane reservoir sizes and positions, and the gradient profile is i…
Abstract Mg-based nanocomposites are promising candidates for hydrogen storage applications exhibiting fast H-sorption kinetics at reasonably low temperatures when processed by high-energy ball milling techniques. However, since compaction of the highly reactive nanometric powder is desirable before application, the s…
Au nanoparticles epitaxially grown on Fe3O4 in Au (6.7 nm)-Fe3O4 dumbbell nanoparticles exhibit excellent stability against sintering, but display negligible catalytic activity in CO oxidation. Starting from various supported Au (6.7 nm)-Fe3O4 catalysts prepared by the colloidal deposition method, we have unambiguousl…
A systematic study was carried out to understand the effect of ethanol chemistry (chloride, water, pHe, and oxygen level) as well as other controlling parameters on the stress corrosion cracking (SCC) behavior of X-65 carbon steel in simulated fuel-grade ethanol (SFGE). The SCC susceptibility of carbon steel was evalu…
In order to understand self-diffusion (D) of a charged, flexible, and porous nanoscopic molecule in water, we carry out very long, fully atomistic molecular dynamics simulation of PAMAM dendrimer up to eight generations in explicit salt water under varying pH. We find that while the radius of gyration (R(g)) varies as…
Gold is active in various hydrogenation reactions and often shows exceptional high chemoselectivity when multiple functional groups are present. All hydrogenation reactions have in common, that the hydrogen molecules have to adsorb and dissociate before they react. Recent insights in the interaction of gold with hydro…
The demand for environmental sustainability has resulted in a great interest in finding new materials that are biodegradable and environmentally friendly. Therefore, materials derived from natural resources are now being extensively studied. Preparation of novel biocomposites based on nanocelluloses has drawn specific…
High-frequency PIN-PMN-PT single crystal ultrasound transducers at center frequencies of 35 MHz and 60 MHz were successfully fabricated using lead indium niobate-lead magnesium niobate-lead titanate (0.23PIN- 0.5PMN-0.27PT) single crystal. The new PIN-PMN-PT single crystal has higher coercivity (6.0 kV/cm) and higher…
A near-infrared quantum cutting phosphor GdBO3:Tb3+,Yb3+ shows poor optical absorption in the ultraviolet-visible excitation spectral range and weak near-infrared luminescence in the 900–1100 nm range, which strongly limit its practical application in silicon-based solar cells, due to the inefficient excitation of the…
Much more work has been carried out on supported gold catalysts (also called “real” catalysts) than on gold single crystal surfaces. However, for fundamental understanding of catalysis by gold, well-defined gold surfaces and controlled conditions using the surface science approach may provide useful information concer…
Two new Zintl compounds Ba(2)Cd(2)As(3) and Ba(2)Cd(2)Sb(3) have been synthesized and structurally characterized. They crystallize in a novel monoclinic structure type with the space group C2/m (no. 12), featuring polyanionic layers made of CdPn(4) tetrahedra (Pn = As, Sb) and homoatomic Pn-Pn bonds. The topological r…
The present study describes the synthesis of monodispersed PbSe and PbS nanocrystals by a facile, less hazardous and inexpensive approach. In this study, Se and S powder are used as chalcogenide precursors instead of trioctylphosphine-selenium (TOPSe) and hexamethyldisilthiane (TMS), which are toxic and expensive. The…
The key element of a novel generation of protective coatings with feedback activity to the external and internal triggers is an embedding of smart nano- or microcontainers into the coating matrix. When implanted in various types of coating matrices, these containers with a sensitive polymeric shell and water or oil in…
Abstract Vor genau 70 Jahren wurde PVP von Prof. Dr. Walter Reppe in der BASF erfunden und zum Patent angemeldet. Polyvinylpyrrolidon wurde zunächst als Blutplasmaersatzstoff im Zweiten Weltkrieg eingesetzt. Nach und nach fand es dann Anwendung in den unterschiedlichsten Branchen: Pharma‐, Kosmetik‐, Waschmittelindust…
We report the covalent layer-by-layer construction of polyelectrolyte multilayer (PEM) films by using an efficient electrochemically triggered Sharpless click reaction. The click reaction is catalyzed by Cu(I) which is generated in situ from Cu(II) (originating from the dissolution of CuSO(4)) at the electrode constit…
Abstract Polymeric materials are used extensively, but their applications are limited because many of them are flammable. Therefore ways to make them flame retardant have received much attention. In this work, polypropylene (PP) was used as the matrix resin, aluminium hydroxide (Al(OH) 3 ) and magnesium hydroxide (Mg(…
This is the third part of a three-part series that investigates the rolling contact fatigue initiation and spall propagation characteristics of three bearing materials, namely, AISI 52100, VIM-VAR M50, and VIM-VAR M50 NiL steels. Though there is substantial prior work published on the rolling contact fatigue initiatio…
BACKGROUND: Silver has long been known to have antimicrobial activity. To incorporate this property into multiple applications, a silver-impregnated cellulose (SIC) with low cytotoxicity to human cells was developed. SIC differs from other silver treatment methods in that the leaching of silver particles is non-existe…