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Characterization of 1,5‐pentanediol dibenzoate as a potential “green” plasticizer for poly(vinyl chloride)

Nicolas Firlotte、David G. Cooper、Milan Marić 等 4 位作者2009-04-30Journal of Vinyl and Additive Technology

Abstract 1,5‐Pentanediol dibenzoate (PDDB) was evaluated as a potential “green” plasticizer for poly(vinyl chloride) (PVC) at concentrations ranging between 20 and 80 parts by weight per hundred parts of resin. The results of glass transition temperature ( T g ) and tensile tests of PDDB blends with PVC were compared…

biodegradable polymer synthesis and propertiesEffects and risks of endocrine disrupting chemicalsPolymer Science and PVC

Synthesis, Structure and Catalysis of Tetranuclear Copper(II) Open Cubane for Henry Reaction on Water

Suribabu Jammi、Tharmalingam Punniyamurthy2009-04-30European Journal of Inorganic Chemistry

Abstract The copper(II) open cubane 1 has been synthesized and its structure determined. It is insoluble in water and efficiently catalyzes the Henry reaction with high yield. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)

Magnetism in coordination complexesFluorine in Organic ChemistryMetalloenzymes and iron-sulfur proteins

The structure of hybrid radial superlattices

Christoph Deneke、Rudeesun Songmuang、N. Y. Jin-Phillipp 等 4 位作者2009-04-30Journal of Physics D Applied Physics

A new class of integrative radial crystals (Krause et al 2006 Phys. Rev. Lett. 96 165502) and radial superlattices (RSLs) (Deneke et al 2004 Appl. Phys. Lett. 84 4475) has been realized by the roll-up of semiconductor-based hybrid layer systems on a substrate surface (Prinz et al 2000 Physica E 6 828, Schmidt and Eber…

Semiconductor Quantum Structures and DevicesQuantum Dots Synthesis And Propertiesnanoparticles nucleation surface interactions

Effects of parameter changes on the structure and properties of low‐density polyethylene foam

Zunaida Zakaria、Zulkifli Mohamad Ariff、Coswald Stephen Sipaut2009-04-30Journal of Vinyl and Additive Technology

Abstract Several parameters, such as crosslinking agent concentration, blowing agent concentration, and temperature, were varied to evaluate their effects on the structure and mechanical properties of low‐density polyethylene (LDPE) foams. Dicumyl peroxide (DCP) was used as crosslinking agent, while azodicarbonamide (…

Cellular and Composite StructuresPolymer composites and self-healingPolymer Foaming and Composites

Size-Dependent Stability of Supported Gold Nanostructures onto Ceria: an HRTEM Study

Jérôme Majimel、M. Lamirand-Majimel、Iona Moog 等 5 位作者2009-04-30The Journal of Physical Chemistry C

Gold nanoparticles of various sizes, supported onto ceria, were synthesized using both deposition−precipitation and coprecipitation methods. Whatever the size, the study of the Au/CeO 2 interface confirms the existence of two preferential orientation relationships with a dislocation network which compensates the 25% i…

Gold and Silver Nanoparticles Synthesis and ApplicationsCatalytic Processes in Materials Sciencenanoparticles nucleation surface interactions

Downfolded Self-Energy of Many-Electron Systems

F. Aryasetiawan、Jan M. Tomczak、Takashi Miyake 等 4 位作者2009-04-30Physical Review Letters

Starting from the full many-body Hamiltonian of interacting electrons the effective self-energy acting on electrons residing in a subspace of the full Hilbert space is derived. This subspace may correspond to, for example, partially filled narrow bands, which often characterize strongly correlated materials. The forma…

Magnetic and transport properties of perovskites and related materialsOrganic and Molecular Conductors ResearchElectronic and Structural Properties of Oxides

Recent Developments in Temperature Responsive Shape Memory Polymers

Subrata Mondal2009-04-30Mini-Reviews in Organic Chemistry

Shape memory polymer is an important area of interest in the polymer science research because of its many applications in industry such as biomedical, smart textiles, actuations and so on. Among the shape memory polymers, temperature responsive shape memory polymers are gaining much attention to the scientist as their…

Polymer composites and self-healing

Dislocation density and strain distribution in SrTiO3film grown on (1 1 0) DyScO3substrate

Zhangyin Zhai、Xiaoshan Wu、Hong‐Ling Cai 等 10 位作者2009-04-30Journal of Physics D Applied Physics

High quality SrTiO 3 thin film on (1 1 0) DyScO 3 substrate is grown by laser molecular beam epitaxy. The lattice strain resulting from the lattice mismatch between the substrate and the film relaxes gradually with depth. A critical thickness of about 30 nm for sharp strain relaxation is observed. The dislocation dens…

Ferroelectric and Piezoelectric MaterialsMagnetic and transport properties of perovskites and related materialsElectronic and Structural Properties of Oxides

The Unusual Solid-State Structure of Mercury Oxide: Relativistic Density Functional Calculations for the Group 12 Oxides ZnO, CdO, and HgO

S. Biering、Andreas Hermann、J. Furthmüller 等 4 位作者2009-04-30The Journal of Physical Chemistry A

The solid-state structure of mercury oxide and its low-pressure modifications are known to significantly differ from those found for the corresponding zinc and cadmium compounds, that is, one changes from a simple hexagonal wurtzite or cubic rock salt structure found in zinc oxide and cadmium oxide to unusual chainlik…

ZnO doping and propertiesHigh-pressure geophysics and materialsnanoparticles nucleation surface interactions

Ultrafast Spatially Resolved Carrier Dynamics in Single CdSSe Nanobelts

Lars Gundlach、Piotr Piotrowiak2009-04-30The Journal of Physical Chemistry C

We present ultrafast microscopy measurements on CdSSe semiconductor nanobelts addressing the early luminescence dynamics, charge transport, and charge carrier localization in individual nanoparticles. The diffraction limited spatial resolution of our femtosecond Kerr-gated microscope allowed us to address single parti…

Quantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin FilmsNanowire Synthesis and Applications

Anomalous Odd–Even Effects in Columnar and Smectic Phases of Discotic Tetraphenylenes

Constanze Hägele、Eugen Wuckert、Sabine Laschat 等 4 位作者2009-04-30ChemPhysChem

Rather uncommon but pronounced odd-even effects in the clearing temperatures of liquid crystals are found for three new homologous series of discotic tetraphenylenes [figure: see text]. Detailed similarities to the well-known odd-even effects in calmitic mesogens point towards a more general understanding of odd-even…

Liquid Crystal Research AdvancementsMaterial Dynamics and PropertiesMolecular spectroscopy and chirality

Predicting from first principles the chemical evolution of crystalline compounds due to radioactive decay: The case of the transformation of CsCl to BaCl

Chao Jiang、Christopher R. Stanek、Nigel A. Marks 等 5 位作者2009-04-30Physical Review B

In this Brief Report, we use density functional theory to predict the existence of a heretofore unobserved crystalline compound, BaCl, and additionally predict it to be isostructural with NaCl (rocksalt). Due to the chemistry of Ba, which strongly prefers a $2+$ charge state, compounds where Ba nominally exhibits a $+…

Nuclear Materials and PropertiesNuclear materials and radiation effectsX-ray Diffraction in Crystallography

Time—frequency and time-scale analysis of Barkhausen noise signals

Linilson Rodrigues Padovese、Nadine Martin、Fabien Millioz2009-04-30Proceedings of the Institution of Mechanical Engineers Part G Journal of Aerospace Engineering

Carrying out information about the microstructure and stress behaviour of ferromagnetic steels, magnetic Barkhausen noise (MBN) has been used as a basis for effective non-destructive testing methods, opening new areas in industrial applications. One of the factors that determines the quality and reliability of the MBN…

Machine Fault Diagnosis TechniquesMagnetic Properties and ApplicationsNon-Destructive Testing Techniques

Inhibitive and adsorption properties of ethanol extract of Colocasia esculenta leaves for the corrosion of mild steel in H2SO4

N. Eddy2009-04-30International Journal of the Physical Sciences

Inhibitive and adsorption properties of ethanol extract of Colocasia esculenta for the corrosion of mild steel in H2SO4 were investigated using weight loss, hydrogen evolution and IR methods of monitoring corrosion. The results obtained indicates that ethanol extract of C. esculenta is a good inhibitor for the corrosi…

Corrosion Behavior and InhibitionCalcium Carbonate Crystallization and InhibitionDyeing and Modifying Textile Fibers

Tuning Microstructures in Organogels: Gelation and Spectroscopic Properties of Mono- and Bis-cholesterol-Linked Diphenylbutadiene Derivatives

Shibu Abraham、Ratheesh K. Vijayaraghavan、Suresh Das2009-04-30Langmuir

The gelation and photophysical properties of mono- and bis-cholesterol derivatives linked to diphenylbutadiene have been investigated. Scanning electron microscopy of xerogels of the monocholesterol derivatives indicated that these molecules self-assemble into 3D networks consisting of helically twisted fibers. In con…

Supramolecular Self-Assembly in MaterialsPhotochromic and Fluorescence ChemistryPolydiacetylene-based materials and applications

Optical nonlinearities in As_2Se_3 chalcogenide glasses doped with Cu and Ag for pulse durations on the order of nanoseconds

Kazuhiko Ogusu、Kenta Shinkawa2009-04-30Optics Express

We investigate the dependence of the nonlinear optical properties of Cu-doped and Ag-doped As(2)Se(3) glasses on the incident pulse-width at 1.064 microm using the Z-scan technique. In this work, 11.5-ns optical pulses from a Nd:YAG laser were compressed up to 1.6 ns by using stimulated Brillouin scattering in heavy f…

Glass properties and applicationsPhase-change materials and chalcogenidesNonlinear Optical Materials Studies

Fabrication and Electrocatalytic Properties of Chitosan and Keplerate-Type Polyoxometalate {Mo72Fe30} Hybrid Films

Dawei Fan、Jingcheng Hao2009-04-30The Journal of Physical Chemistry B

Hybrid films composed of chitosan and Keplerate-type polyoxometalate, {Mo72Fe30} (Mo72VIFe30IIIO252L102.ca.180H2O, L=H2O/CH3COO-/Mo2O8/9n-), were fabricated on quartz, silicon, and ITO substrates by layer-by-layer (LbL) method. The LbL films were characterized by UV-vis spectroscopy, X-ray photoelectron spectroscopy (…

Advanced Photocatalysis TechniquesPolyoxometalates: Synthesis and ApplicationsAdvanced Nanomaterials in Catalysis

Active Protein-Functionalized Poly(poly(ethylene glycol) monomethacrylate)-Si(100) Hybrids from Surface-Initiated Atom Transfer Radical Polymerization for Potential Biological Applications

Fu‐Jian Xu、L. Y. Liu、Wantai Yang 等 5 位作者2009-04-30Biomacromolecules

Protein-resistant poly(poly(ethylene glycol)monomethacrylate)-graft-Si(100), or Si-g-P(PEGMA) hybrids, were prepared via surface-initiated atom transfer radical polymerization (ATRP) of the poly(ethylene glycol)monomethacrylate (PEGMA) macromonomer from the hydrogen-terminated Si(100) surface (Si-H surface). The resul…

Polymer Surface Interaction StudiesNanofabrication and Lithography TechniquesAdvanced Biosensing Techniques and Applications

Preparation of Titania−Silica Mixed Oxides by a Sol−Gel Route in the Presence of Citric Acid

Gang Liu、Yan Liu、Guang Yang 等 7 位作者2009-04-30The Journal of Physical Chemistry C

Titania−silica mixed oxides (denoted as TiO 2 −SiO 2 ) with different Ti contents are prepared by a sol−gel route in the presence of citric acid (CA). Various characterization techniques, including XRD, FT-IR, N 2 -adsorption, TEM, solid-state CP-MAS NMR spectroscopy, UV−vis, and NH 3 -TPD, have been carried out to in…

Zeolite Catalysis and SynthesisMesoporous Materials and CatalysisCatalysis and Oxidation Reactions

Experimental Insight into the Radiation Resistance of Zirconia-Based Americium Ceramics

Renaud C. Belin、P. Martín、Philippe J. Valenza 等 4 位作者2009-04-30Inorganic Chemistry

Our works shows that the americium pyrochlore (241)Am(2)Zr(2)O(7) undergoes a phase transition to a defect-fluorite structure along with an unusual volume contraction when subjected to internal radiation from alpha-emitting actinides. Disorder relaxation proceeds through the simultaneous formation of cation antisites…

Nuclear Materials and PropertiesNuclear materials and radiation effects