Materials Literature
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Abstract Carbon nanotubes (CNTs) are thought to be perfect enhancive materials for composites. Multi‐wall carbon nanotubes were directly electrospun into polyacrylonitrile (PAN) nanofibers via both traditional electrospinning and vibration‐electrospinning. The fibers obtained were examined by scanning electron microsc…
"Hairy nano-objects" are hybrid nanostructures comprising a core surrounded by a "hairlike" corona of flexible polymer chains, the role of which is typically to improve the solubility of the core material or to improve its dispersability and adhesion in other polymer matrices. Both aspects could be particularly useful…
We report on the observation of weak localization in arrays of (Ga,Mn)As nanowires at millikelvin temperatures. The corresponding phase coherence length L phi is typically between 100 and 200 nm at 20 mK. Strong spin-orbit interaction in the material is manifested by a weak antilocalization correction around zero magn…
The influence of reaction parameters such as temperature, contact time, and O 2, CO, H 2, CO 2, and H 2 O partial pressures on the catalytic performances of 4 wt % CuO/CeO 2 in the CO-PROX process (the preferential oxidation of CO) has been investigated in a fixed-bed reactor. Catalyst appears very active (light-off a…
Small angle x-ray scattering is utilized to directly examine the formation of clusters in supersaturated solutions of glycine, in an attempt to understand their role in the nucleation process. The results suggest that the majority of glycine molecules exist as dimers in aqueous solutions, and monomers in 13% (upsilon/…
A new cyanide-bearing molecular precursor, mer-[Fe(pzcq)(CN)(3)]- (1), and a zigzag chain, [Fe(pzcq)(CN)(3)][Mn(salen)].4H(2)O (2), were prepared and characterized in terms of structure and magnetism. Magnetic data reveal that intrachain antiferromagnetic couplings via cyanide ligands in 2 are clearly operating, resul…
This work reports on the hydrogen interaction with a 3 wt % Au/Ce 0.62 Zr 0.38 O 2 (Au/CZ) catalyst prepared by deposition−precipitation. As deduced from X-ray powder diffraction, electron microscopy (scanning transmission electron microscopy−high-angle angular dark field and high-resolution electron microscopy), and…
The influence of different conditions on the mechanical properties of short coir fiber reinforced polymer composites as well as glass fiber reinforced polymer composites have been analyzed and compared. Fiber length of 20 mm was found to be optimum for the best result. It is observed that the filler loading of 30 phr…
Electrochemically deposited silver structures with nanowires 50-100 nm in diameter show high fluorescence amplification and strongly reduced fluorescence lifetimes. Both quantities depend on the structure thickness. With increasing thickness the fluorescence amplification proportionally increases and the fluorescence…
Numerous studies have shown that a surface can direct and regulate molecular assembly. In this study, the nanofiber growth of an ionic-complementary peptide, EAK16-II, on a mica surface was investigated under various solution conditions via in situ atomic force microscopy. In comparison to the assembly in bulk solutio…
The charge-transport behavior in one-dimensional (1D) poly (3,4-ethylenedioxythiophene) (PEDOT) nanomaterials of three different shapes is described. Both intrinsic and extrinsic factors are considered from the viewpoint of a single nanoparticle and nanoparticle assembly. Intrinsically, the oxidation level of the 1D P…
Abstract A brief review of mathematical models of electrospinning is given. The nano‐effect and electrospinning dilation are presented to explain how to prepare extremely high strength continuous nanofibers and nanoporous microspheres, respectively. According to the established models, vibration‐electrospinning is int…
The X-ray crystal structures, magnetic susceptibilities from 2 to 300 K, and theoretical analyses of the magnetism for 1D and trinuclear azido Cu(II) carboxylate complexes [Cu(1.5)(hnta)(N(3))(2)(H(2)O)](n) (1) and [Cu(3)(hnta)(4)(N(3))(2)(H(2)O)(3)] (2), respectively, where hnta is 6-hydroxynicotinate, are described.…
The interband and intraband spectra of colloidal II-VI CdS and CdSe quantum dot cores and CdSZnSe, CdSCdSe, CdSeCdS, and CdSeZnSe core/shell systems are reported. Infrared absorption peaks between 0.5 and 0.2 eV are observed. The slope of the intraband energy versus the first interband absorption feature is characteri…
A systematic multiscale coarse-graining (MS-CG) algorithm is applied to build coarse-grained models for monosaccharides in aqueous solution. The methodology is demonstrated for the example of alpha-D-glucopyranose. The nonbonded interactions are directly derived from the force-matching approach, whereas the bonded int…
Polymers exhibit a range of physical characteristics, from rubber-like elasticity to the glassy state. These particular properties are controlled at the molecular level by the mobility of the structural constituents. Remarkable changes in mobility can be witnessed with temperature, over narrow, well defined regions, t…
The focused ion beam (FIB) system is an important tool for understanding and manipulating the structure of materials at the nanoscale. Combining this system with an electron beam creates a DualBeam - a single system that can function as an imaging, analytical and sample modification tool. Presenting the principles, ca…
Nephrogenic systemic fibrosis is a new disorder reported almost exclusively in patients who have renal insufficiency and are exposed to contrast media formulated with gadolinium. High morbidity and mortality are associated with this severely disabling and painful condition. The acute phase begins upon exposure to gado…
Abstract BACKGROUND: The design of implants comprised of biodegradable electrospun nanofibers for the purpose of bridging injuries in damaged spinal cord is discussed. Electrospun nanofibers structurally mimic the extracellular matrix on which neurons and other cell types grow in vivo . This property has created great…
Oxydianiline-pyromellitic dianhydride poly(amic acid) (ODA-PMDA PAA) was polymerized with a catalyst support of triethyl amine for controlling molecular weight. This polymer was used for electrospinning in the preparation of PAA nanofibers, a precursor of carbon nanofibers. Here the amount of catalyst and concentratio…