Materials Literature
按标题、摘要、年份、主题和来源检索公开元数据。结果保留作者、摘要、分类与原始来源链接。
Highly dispersed ruthenium oxide clusters were synthesized on carbon nanotubes (CNTs) to form RuO 2 · x H 2 O/CNT catalyst by a homogeneous oxidation precipitation method. Methanol oxidation was carried out on RuO 2 · x H 2 O/CNT at low temperatures for the production of diverse oxygenous products, such as methyl form…
Abstract Poly(lactide) (PLA), poly(ε‐caprolactone) (PCL) and poly(trimethylene carbonate) (PTMC) homopolymers of high molecular weight were prepared using potassium‐based catalyst. Polymerizations were carried out in toluene at room temperature. The chemical structure of the polymers was investigated by 1 H and 13 C N…
Abstract The toughness of cycloaliphatic epoxy resin 3,4‐epoxycyclohexylmethyl‐3′,4′‐epoxycyclohexane carboxylate (ERL‐4221) has been improved by using multiwalled carbon nanotubes (MWCNTs) treated by mixed acids. The MWCNT/ERL‐4221 composites were characterized by Raman spectroscopy and their mechanical properties we…
Abstract Polypyrrole nanoparticles were prepared by emulsion polymerization, and the surface charge of PPy nanoparticles was controlled by the mixed surfactant system of dodecylbenzene sulfonic acid and isooctylphenyl ether. The shape and size of nanoparticles prepared could be controlled by changing concentration of…
Characterization of composition and structure is crucial to understanding the properties and performance of nanomaterials. For nanowires and nanotubes, determining radial compositional and structural modulations is particularly challenging. Here we use a focused ion beam (FIB) lift-out technique to show that Cu-Ni cor…
Abstract Chloramphenicol (CLM), originally derived from the bacterium Streptomyces venezuelae , is an inhibitor of bacterial ribosomal peptidyl transferase activity. The near infrared Fourier transform (NIR‐FT) Raman, surface‐enhanced Raman spectroscopy (SERS) and Fourier transform infrared (FT‐IR) spectral analyses o…
Nanocomposite polyHIPEs were synthesised by the polymerization of the continuous phase of high internal phase emulsions containing titania nanoparticles in the organic or oxidized CNTs in the aqueous phase. The resulting polymer foams possessed an interconnected pore structure characteristic of polyHIPEs. The incorpor…
We consider the equilibrium flotation of a thin, flexible cylinder at the interface between a liquid and a gas. In particular, we determine the maximum load that such a cylinder can support without sinking. We find that as the length of such a cylinder increases the maximum load at first increases. However, the maximu…
The ability to adhere onto surfaces is of very high importance for microorganisms, enabling them to stay in a favourable habitat for life. In the case of Bacteria cell surface organelles called fimbriae/pili have been shown to be used for adhesion; corresponding cell surface appendages of Archaea have not yet been def…
Abstract A series of polypropylene (PP)/polystyrene (PS) blends were prepared by solvent blending with PS‐grafted PP copolymers (PP‐ g ‐PS) having different PS graft chain length as compatibilizers. The interfacial compatibility was significantly improved with increasing PS graft chain length until the interface was s…
Three-dimensional nano-architectures with varying shape, morphology and size were fabricated by the phase separation of methyltrichlorosilane (CH(3)SiCl(3)) on commercially available glass and SiO(2) substrates. By changing the synthesis conditions, CH(3)SiCl(3) nanostructures evolved from discrete to quasi-network or…
Abstract A water‐soluble carboxymethyl chitosan was prepared with a view to develop a multifunctional finish on cotton. Carboxymethyl chitosan (CMCTS) was synthesized by chemical reaction of chitosan with monochloroacetic acid under alkaline condition. The water soluble CMCTS was applied to cationized cotton with diff…
Activating gold: High-resolution photoemission spectroscopy and DFT calculations were used to study the interaction of SO2 with Au/TiC(001) surfaces. Both revealed molecular adsorption of SO2 on TiC(001) but complete dissociation of the SO bonds on Au/TiC(001) (see picture). Au/TiC(001) cleaves SO bonds more efficie…
We report here a novel phenomenon: selective metal deposition on photoswitchable diarylethene (DAE) surfaces. Magnesium vapor was deposited by vacuum evaporation on the colored DAE but not on the uncolored surface. The selective deposition originates in the change of the glass transition temperature of the amorphous D…
Recent experiments report that the long-looked-for thermotropic biaxial nematic phase has been finally detected in some thermotropic liquid crystalline systems. Inspired by these experimental observations, we concentrate on some elementary theoretical issues concerned with the classical sixth-order Landau-de Gennes fr…
Abstract A series of waterborne polyurethane adhesives (WPUAs) were prepared from diphenylmethane‐4,4′‐diisocyanate (MDI), 1,6‐hexamethylene diisocyanate (HDI), poly(1,4‐butanediol adipate) diol (PBA), 1,4‐butanediol (BDO), and internal‐emulsifying agents by the prepolymer mixing method. The viscosity, mechanical prop…
Abstract This article reports crystallization behaviors of isotactic polypropylene (iPP) with an aryl amide derivative (TMB‐5) as β‐form nucleating agent. The effects of nucleating agent concentration, thermal history and assemble morphology of nucleating agent on the crystallization behaviors of iPP were studied by d…
The use of noble metals as catalysts for mercury oxidation in flue gas remains an area of active study. To date, field studies have focused on gold and palladium catalysts installed at pilot scale. In this article, we introduce bench-scale experimental results for gold, palladium and platinum catalysts tested in reali…
Using the density functional theory, we have demonstrated the chemical functionalization of semiconducting graphene nanoribbons (GNRs) with Stone-Wales (SW) defects by carboxyl (COOH) groups. It is found that the geometrical structures and electronic properties of the GNRs changed significantly, and the electrical con…
Apatite-type oxides of general formula La 9.33+ x (SiO 4 ) 6 O 2 + 3 x /2 have been attracting considerable interest recently because of their observed high oxide-ion conductivity and potential use in solid oxide fuel cells (SOFCs), oxygen sensors, and ceramic membranes. In this paper, computer modeling techniques are…