Materials Literature
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Dispersion of carbon nanotubes into solvents affects their surface chemistries, electronic structures, and subsequent functionalization. In this Communication, a water-soluble self-doped polyaniline nanocomposite was fabricated by in situ polymerization of the 3-aminophenylboronic acid monomers in the presence of sing…
Many transition metal oxide materials of high chemical purity are not necessarily monophasic. Thus, single crystals of chemically pure rare earth manganites and cobaltates of the general formula Ln(1-x)A(x)MO(3) (Ln=rare earth metal, A=alkaline earth metal, M=Mn, Co) exhibit the phenomenon of electronic phase separati…
We analyze photon statistics of blinking CdSe-ZnS nanocrystals interacting with a continuous wave laser field, showing that the process is described by a ballistic Lévy walk. In particular, we show that Mandel's Q parameter, describing the fluctuations of the photon counts, is increasing with time even in the limit of…
Thin silicate platelets in a dimension of approximately 80 x 80 x 1 nm(3) are isolated for the first time by a newly developed process involving one-step exfoliation of natural montmorillonite clay and toluene/aqueous NaOH extraction. The platelets are observed to be polygon shape by transmission electron microscopy (…
Abstract The resistivity of transparent conducting Al‐ and Ga‐doped ZnO (AZO and GZO) thin films prepared with a thickness in the range from 20 to 200 nm on glass substrates at a temperature below 200 °C was found to increase with exposure time when tested in a high humidity environment (air at 90% relative humidity a…
Systematic measurements of auto- and cross-correlations of photons emitted from individual $\mathrm{Cd}\mathrm{Te}∕\mathrm{Zn}\mathrm{Te}$ quantum dots under pulsed excitation were used to elucidate nonresonant excitation mechanisms in this self-assembled system. Memory effects extending over a few excitation pulses h…
The temperature dependence of magnetic susceptibility, χ( T ), of the P 2 1 / m crystal of a novel [Pd(dmit) 2 ] salt, (C 2 H 5 )(CH 3 ) 3 P[Pd(dmit) 2 ] 2 , has been measured. The observed χ( T ) above 30 K is reproduced by the model of a spin-1/2 Heisenberg antiferromagnet on a triangular lattice with the exchange c…
Porphyrins play a major role as active chromophores in artificial systems mimicking the natural photoinduced processes. The formation of coordination bonds between peripheral donor sites on the porphyrins and external metal fragments has proven to be an efficient alternative to covalent synthesis for the construction…
Northern Illinois University DeKalb,Institut fu¨r Anorganische Chemie & Southern Methodist University
Owing to short distances between the inner nitrogen atoms and, therefore, strong intramolecular hydrogen bonds, porphycenes display completely different tautomeric properties than porphyrins, their constitutional isomers. Tunneling splitting caused by delocalization of two inner hydrogen atoms is observed for porphyce…
In this study, we report on a simple two-step casting process designed to create a stable superhydrophobic surface. This method possesses the advantages of being both simple and inexpensive as well as utilizing non-fluorine-containing compounds. Most interestingly, we found that the as-prepared surface possesses super…
We report here the first observation of the low frequency Raman scattering from acoustic phonons in semiconducting zinc oxide (ZnO) nanoparticles without embedding in any solid matrix. ZnO nanoparticles (size 5-10 nm) with nearly spherical shape have been synthesized using a chemical route. A shift in the phonon peaks…
A method to functionalize single-walled carbon nanotubes (SWNTs) in a field-effect transistor (FET) device for the selective detection of heavy-metal ions is presented. In this method, peptide-modified polymers were electrochemically deposited onto SWNTs and the selective detection of metal ions was demonstrated by ch…
New fluorescent gelators containing pyrene moieties and dendritic oligopeptides have been developed. These molecules self-assemble into 1D helical columnar structures that lead to the formation of 3D fibrous random networks. The resulting gel materials show monomer emission of pyrenes because the hydrogen-bonded array…
Festgesetzt: Kaliumionen werden in Koordinationskäfigen aus Oberflächensechsecken und Wassermolekülen in einer Smektit-Zwischenschicht fixiert (siehe Bild). Diese Mikrostruktur führt zu einer überraschenden Stabilität des einschichtigen K-Smektit-Hydrats und verhindert ein weiteres Quellen des Tons.
We investigated the relationship between the tunnel magnetoresistance (TMR) ratio and the electrode structure in MgO-barrier magnetic tunnel junctions (MTJs). The TMR ratio in a MTJ with Co40Fe40B20 reference and free layers reached 355% at the post-deposition annealing temperature of Ta=400 degree C. When Co50Fe50 or…
Fast magnetization reversal of uniaxial Stoner particles by spin-transfer torque due to the spin-polarized electric current is investigated. It is found that a current with a properly designed time-dependent polarization direction can dramatically reduce the critical current density required to reverse a magnetization…
ADVERTISEMENT RETURN TO ISSUEPREVNoteNEXTSuppression of Skin−Core Structure in Injection-Molded Polymer Parts by in Situ Incorporation of a Microfibrillar NetworkGan-Ji Zhong, Liangbin Li, Eduardo Mendes, Dmytro Byelov, Qiang Fu, and Zhong-Ming LiView Author Information College of Polymer Science and Engineering, Stat…
We study interfacial phenomena in a colloidal dispersion of sterically stabilized gibbsite platelets, exhibiting coexisting isotropic and nematic phases separated by a sharp horizontal interface. The nematic phase wets a vertical glass wall and polarized light micrographs reveal homeotropic surface anchoring both at t…
We use an all-electron implementation of the GW approximation to analyze several possible sources of error in the theory and its implementation. Among these are convergence in the polarization and Green's functions, the dependence of QP levels on choice of basis sets, and differing approximations for dealing with core…