Materials Literature
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Unprecedented porphycene complexes, containing a [RuCp*] (Cp*: pentamethylcyclopentadienyl) fragment accommodated in the central N(4) core or directly bonded to the "pi-face" of the macrocycle have been prepared and fully characterized, including via single crystal X-ray diffraction analysis. The optical and electroch…
Hydrothermal reaction of CoCl(2) with trans-3-pyridylacrylic acid (3-pycaH) and Et(3)N results in the formation of a new three-dimensional network formulated as [{Co(4)(mu-H(2)O)(2)(3-pyca)(8)}(0.94){Co(5)(mu(3)-OH)(2)(3-pyca)(8)}(0.06)]. Magnetic measurements reveal that spin-canting and metamagnetic behavior coexist…
We report the synthesis of Mn-substituted titania nanosheets and the preparation of room-temperature ferromagnetic thin films via layer-by-layer assembly of these nanosheets. Ti (5.2−2 x )/6 Mn x /2 O 2 ( x = 0.0−0.4) nanosheets were synthesized by delaminating layered titanates [K 0.8 Ti (5.2−2 x )/3 Li (0.8− x )/3 M…
Ferroelectric (Na 1/2 Bi 1/2 )TiO 3 –BaTiO 3 (BNT–BT) single perovskite thin films have been prepared, for the first time, by chemical solution deposition onto Pt/TiO 2 /SiO 2 /(100)Si substrates. A solution process has been developed for the preparation of precursor solutions. The handling of all the chemical reagent…
Abstract Even for samples exhibiting excellent electronic properties in terms of carrier mobility, sample‐to‐sample variability remains considerable and dislocation density is still very high, the latter characteristic being often related to damages induced either by the substrate polishing step or by substrate bulk d…
Electrospinning offers an attractive opportunity for producing silk fibroin (SF) nano/micro fibrous scaffolds with potential for tissue regeneration and repair. Electrospun scaffolds of silk fibroin were fabricated as a biomimetic scaffold for tissue engineering. The morphology of the electrospun scaffolds was investi…
To test the molecular exciton theory for heterodimeric chromophores, various heterodimers and clusters, in which two different dyes were stacked alternately, were prepared by hybridizing two oligodeoxyribonucleotides (ODNs), each of which tethered a different dye on D-threoninol at the center of the strand. NMR analys…
The expression for hardness related to crystal orientation is proposed. Because all quantities in the equation are inherently coupled to the atomistic structure of matter, the anisotropy of hardness can be determined by first-principles methods. The calculations show the highest hardness is in ${\text{ReB}}_{2}$ and $…
Abstract A series of tetradentate dimeric salicylaldimine ligands (H 2 L n R m ) with terminal chains of variable length (R m ) and a central flexible (CH 2 ) n spacer (L n = 10 and 12) was synthesized. For all ligands, according to their rod‐like molecular shape, mesomorphism characteristic of calamitic systems (nema…
OBJECTIVE: The aim of this study was to evaluate histologically the bio-degradation of two layers of Bio-Gide((R)) (BG) membrane, as compared with that of a single layer. MATERIAL AND METHODS: Two circular calvarial bony defects, 5 mm in diameter, were made in 24 Wistar rats. BG membrane, labeled with biotin, was cut…
We use classical molecular-dynamics simulations to study the aggregation of various titanium dioxide (anatase) nanocrystals in vacuum. In all cases, we observe a strong tendency for the nanocrystals to aggregate with certain preferred orientations in a "hinge" mechanism. Although some of the nanocrystals possess signi…
BACKGROUND: Poly-beta-hydroxybutyrate (PHB) mobilization in bacteria has been proposed as a mechanism that can benefit their host for survival under stress conditions. Here we reported for the first time that a stress-induced system enabled E. coli, a non-PHB producer, to mobilize PHB in vivo by mimicking natural PHB…
A planar lens made of gradient index metamaterials can transform cylindrical waves to plane waves, and the beam direction of plane waves is controlled by adjusting the refractive-index distributions of the lens. Based on such properties, we present high-performance beam-scanning antennas experimentally using the gradi…
An interesting property of zigzag graphene nanoribbons is the presence of edge states, extended along its borders but localized in the transverse direction. Here we show that because of this property, electron transport through an externally induced potential well displays two-path-interference oscillations when subje…
A Ge/Si heterojunction light emitting diode with a p+-Ge/i-Ge/N+–Si structure was fabricated using the ultrahigh vacuum chemical vapor deposition technology on N+–Si substrate. The device had a good I-V rectifying behavior. Under forward bias voltage ranging from 1.1 to 2.5 V, electroluminescence around 1565 nm was ob…
Large-scale molecular dynamics simulations were performed to demonstrate the synergistic effects of twin boundaries and free surfaces on dislocation emission in gold nanowires under tensile loading. It is revealed that the addition of nanoscale twins to crystalline nanowires can act to either increase or decrease thei…
Exciton-exciton interaction in dot/rod CdSe/CdS nanocrystals has proved to be very sensitive to the shape of nanocrystals, due to the unique band alignment between CdSe and CdS. Repulsive exciton-exciton interaction is demonstrated, which makes CdSe/CdS dot/rods promising gain media for solution-processable lasers, wi…
The effect of magnetostrictive layer thickness on the magnetoelectric (ME) response and field sensitivity of Pb(Zr,Ti)O3-metglas based sandwiched ME heterostructures has been studied. Such structures hold promise for sensor applications. The increase in metglas thickness results in a significant increase in the ME res…
Titanium tough! Novel proline-derived C1-symmetric titanium(salan) complexes have been used to catalyze the epoxidation of styrene derivatives with aqueous hydrogen peroxide as the oxidant (see scheme). High enantiomeric excesses ranging from 96 to 98 % were obtained.
Complex cobalt oxides known as cobaltites are reviewed, including LnCoO3-based perovskite-structured rare-earth cobaltites (where Ln is lanthanum or a lanthanide), quasi-two-dimensional and quasi-one-dimensional cobaltites of the types LnCo2O5+?, La2CoO4, and Ca3Co2O8, and NaxCoO2 ? yH2O superconducting compounds. Key…