Materials Literature
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Hybrid polymer-metal nanospheres are potential nano-sized medical devices that can provide multi-functions such as medical imaging and drug/biomolecule delivery. Gold nanoparticle-based hybrid nanospheres are particularly attractive owing to the unique optical and electronic properties that they possess. The polymer i…
Abstract The plasmonic origin of surface‐enhanced Raman scattering (SERS) leads to the concept of hotspots and plasmon coupling that can be realized in the interstitial regions, or on specially engineered, silver and gold nanostructures. It is also possible to achieve spatial locations of high local field or hotspots…
Nanocomposites (NC)s of carboxyl functionalized multi-walled carbon nanotubes (f-MWCNTs) that reinforced poly(amide-imide) have been created via a simple solution casting technique. X-ray diffraction, FT-IR spectroscopy, transmission electron microscopy, and field emission scanning electron microscopy were carried out…
Two partly new [Fe(intz)6](BF4)2 complexes with n = 3 and 4 (i3tz = 1-isopropyl-1H-tetrazole, i4tz = 1-isobutyl-1H-tetrazole) were synthesized and characterised by X-ray powder diffraction, magnetic susceptibility measurements, vibrational, electronic and 57Fe–Mößbauer spectroscopy as well as DSC. The [Fe(i3tz)6](BF4)…
In this paper, a new analytical methodology is proposed to estimate core losses in line-start and inverter-fed induction motors under rotor broken bars. This methodology can be utilized for different supply and load conditions. Core losses are precisely calculated taking into account the effects of nonsinusoidal distr…
Ferrous disulfide (FeS 2 ) nanocrystals were synthesized via a simple hydrothermal reaction. The FeS 2 nanocrystals were then combined in intumescent flame-retardant ethylene–vinyl acetate (EVA/IFR) systems. Thermogravimetric analysis data indicate that the addition of FeS 2 into the EVA/IFR composite can improve the…
We report a highly sensitive method for rapid identification and quantification of rare-event cells carrying low-abundance surface biomarkers. The method applies lanthanide bioprobes and time-gated detection to effectively eliminate both nontarget organisms and background noise and utilizes the europium containing nan…
A broad nanoscopic study of a wide-range of dendritic organic nonlinear optical (NLO) self-assembly molecular glasses reveals an intermediate thermal phase regime responsible for both enhanced electric field poling properties and strong phase stabilization after poling. In this paper, the focus is on dendritic NLO mol…
Electroconductive poly(N-butylaniline)-lignosulfonate (PBA-LS) composite nanospheres were prepared in a facile way by in situ, unstirred polymerization of N-butylaniline with lignosulfonate (LS) as a dispersant and dopant. The LS content was used to optimize the size, structure, electroconductivity, solubility, and si…
This study demonstrates all optical switches between the four diffractive light levels of a body-centered tetragonal photonic crystal. The sample is based on holographic polymer-dispersed liquid crystals that are fabricated using a two-beam interference with multiple exposures. The switching mechanism bases on the eff…
Acid gel caries lesions were created in 3,100 human and bovine enamel specimens and studied with transverse microradiography. Small, significant differences were found. Human enamel lesions were found to be less demineralized, shallower, had a higher ratio of integrated mineral loss (ΔZ) to lesion depth (L), a lower d…
Various carbonate apatite formulae contribute to discrete cuticle structures participating in protective functions of the American lobster, Homarus americanus, integument. Canal walls use their lowest Calcium : Phosphate (Ca : P) ratios to protect exposed surfaces of gland and neuronal canals. The linings insulate mor…
It is established by means of chemical nuclear polarization that the photointeraction of quinones with porphyrin leads to the transfer of an electron with the formation of ion-radical pairs, and then to the transfer of a proton with the reversible reduction of quinone.
A detailed study of the reaction between [Ni(6)(CO)(12)](2-) and [AuCl(4)](-) afforded the isolation of the new Ni-Au cluster [Ni(12)Au(CO)(24)](3-) as well as identifying an improved synthesis for the previously reported [Ni(32)Au(6)(CO)(44)](6-). The new [Ni(12)Au(CO)(24)](3-) cluster is composed by two [Ni(6)(CO)(1…
Abstract We present the study on optical quality of nanocrystalline diamond (NCD) films with submicron grain size grown from H 2 /CH 4 /CO 2 gas mixture on alkali‐free borosilicate glass substrates using the commercially available large area linear antenna pulsed microwave plasma chemical vapor deposition (CVD) system…
Glutathionylspermidine synthetase/amidase (Gss) and the encoding gene (gss) have only been studied in Escherichia coli and several members of the Kinetoplastida phyla. In the present article, we have studied the phylogenetic distribution of Gss and have found that Gss sequences are largely limited to certain bacteria…
The stabilization of inorganic nanostructures is a key challenge in developing label-free optical biosensors using inorganic nanoporous films. In the present study, a polyelectrolyte multilayer film (PMF) composed of poly(acrylic acid) and poly(allylamine hydrochloride) was deposited on porous anodic alumina (PAA) fil…
The structure and optical properties of several polynuclear gold(I) species, namely, diselenophosphate [Au{μ-Se(2)P(OR)(2)}](2) complexes (R = (i)Pr, Et, (n)Pr) respectively numbered 1, 2, and 3 and number 4 [Au{μ-Se(2)P(CH(2))(2)Ph)(2)}](2), exhibiting interesting structural, absorption, and emission properties have…
A novel hyperbranched polysiloxane containing epoxy and phosphaphenanthrene groups (EP-HPSi) was synthesized through a ring-open reaction between P-H bond of 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide (DOPO) and epoxy group of a hyperbranched polysiloxane. EP-HPSi was used to modify cyanate ester (CE) resin. T…
The ability to control the state of individual atoms is a new challenge for science and technology in the 21st century. Currently, experiments on individual quantum systems such as trapped ions, single molecules, quantum dots, superconducting qubits and photons are crucial for the rapidly growing field of quantum info…