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Preparation of Silica Coatings Heavily Doped with Spiropyran Using Perhydropolysilazane as the Silica Source and Their Photochromic Properties

Akihiro Yamano、Hiromitsu Kozuka2009-04-06The Journal of Physical Chemistry B

Silica coatings doped with spiropyran (SP) were prepared using xylene solutions of perhydropolysilazane (PHPS) as the silica source, where the SP-doped PHPS coatings were prepared by spin-coating and the PHPS-to-silica conversion was achieved by exposing the coatings to the vapor from aqueous ammonia at room temperatu…

Photochromic and Fluorescence ChemistryPhotoreceptor and optogenetics researchPolydiacetylene-based materials and applications

Invisibility cloaks for toroids

Yu You、George W. Kattawar、Ping Yang2009-04-06Optics Express

The material properties of toroidal invisibility cloaks are derived based on the coordinate transformation method. The permittivity and permeability tensors for toroidal cloaks are substantially different from those for spherical cloaks, but quite similar to those for 2D cylindrical cloaks because a singularity is inv…

Metamaterials and Metasurfaces ApplicationsElectromagnetic Scattering and AnalysisAdvanced Antenna and Metasurface Technologies

Nanocomposites of Size‐Tunable ZnO‐Nanoparticles and Amphiphilic Hyperbranched Polymers

Thomas V. Richter、Fabian Schüler、Ralf Thomann 等 5 位作者2009-04-06Macromolecular Rapid Communications

Highly dispersed ZnO nanoparticles with variable particle sizes were successfully prepared within an amphiphilic hyperbranched polyetherpolyol matrix via decomposition of an organometallic precursor in the presence of air leading to stable nanocomposites. The high degree of stabilization during and after the synthesis…

Organic Light-Emitting Diodes ResearchConducting polymers and applicationsDendrimers and Hyperbranched Polymers

Solubility of 3,5-Dimethoxybenzoic Acid, 4-Cyanobenzoic Acid, 4-Acetoxybenzoic Acid, 3,5-Diaminobenzoic Acid, and 2,4-Dichlorobenzoic Acid in Ethanol

Hui Wang、Weijiang Zhang2009-04-06Journal of Chemical & Engineering Data

The solubility of 3,5-dimethoxybenzoic acid, 4-cyanobenzoic acid, 4-acetoxybenzoic acid, 3,5-diaminobenzoic acid, and 2,4-dichlorobenzoic acid in ethanol was measured by both static method and dynamic method over the temperature range from (298.15 to 318.15) K under atmospheric pressure. The experimental data were cor…

Analytical Chemistry and ChromatographyCrystallization and Solubility StudiesChemical and Physical Properties in Aqueous Solutions

Effective coordination as a predictor of adsorption energies: A model study of NO on Rh(100) and Rh/MgO(100) surfaces

Raghani Pushpa、Prasenjit Ghosh、Shobhana Narasimhan 等 4 位作者2009-04-06Physical Review B

We have studied the adsorption of NO, and the coadsorption of N and O, on four physical and hypothetical systems: unstrained and strained Rh(100) surfaces and monolayers of Rh atoms on strained and unstrained MgO(100) surfaces. We find that as we go from Rh(100) to Rh/Mg0(100), via the other two hypothetical systems,…

Advanced Chemical Physics StudiesCatalytic Processes in Materials ScienceAmmonia Synthesis and Nitrogen Reduction

Extended x-ray absorption fine structure studies of the atomic structure of nanoparticles in different metallic matrices

S.H. Baker、M. Roy、S. J. Gurman 等 4 位作者2009-04-06Journal of Physics Condensed Matter

It has been appreciated for some time that the novel properties of particles in the size range 1-10 nm are potentially exploitable in a range of applications. In order to ultimately produce commercial devices containing nanosized particles, it is necessary to develop controllable means of incorporating them into macro…

Magnetic properties of thin filmsMagnetic Properties and Synthesis of FerritesIron oxide chemistry and applications

A simplified model for natural-gas vehicle catalysts with honeycomb and foam substrates

Dimitrios N. Tsinoglou、Panayotis Dimopoulos Eggenschwiler、T. Thurnheer 等 4 位作者2009-04-06Proceedings of the Institution of Mechanical Engineers Part D Journal of Automobile Engineering

A mathematical model is developed for the simulation of the chemical and transport phenomena in three-way catalysts for natural-gas vehicles, with honeycomb and foam substrates. The chemical phenomena are modelled on the basis of a simplified approach, which assumes that pollutant conversion is governed by oxygen stor…

Advanced Combustion Engine TechnologiesCatalytic Processes in Materials ScienceCatalysis and Oxidation Reactions

Autoradiographic observations on developing and growing claws of reptiles

Lorenzo Alibardi2009-04-06Acta Zoologica

Abstract Alibardi, L. 2010. Autoradiographic observations on developing and growing claws of reptiles. — Acta Zoologica (Stockholm) 91 : 233–241 The present qualitative autoradiographic analysis aims to present the main features of morphogenesis and growth of claws in reptiles. Lizard embryos treated with tritiated th…

Tendon Structure and TreatmentGenetic and Clinical Aspects of Sex Determination and Chromosomal AbnormalitiesSilk-based biomaterials and applications

Effect of the Y 2 O 3 Concentration in YSZ on the Thermophysical Property as a Thermal Shielding Material

Kazuya Sasaki、Takayuki Terai、Akihiro Suzuki 等 4 位作者2009-04-06International Journal of Applied Ceramic Technology

The effect of the Y 2 O 3 concentration in yttria‐stabilized zirconia (YSZ) on the thermophysical property of porous YSZ was studied. The specific heat capacities ( C p ), the thermal diffusivity (α), the apparent density (ρ) of a 3 mol% Y 2 O 3 /97 mol% ZrO 2 (3YSZ), and an 8 mol% Y 2 O 3 /97 mol% ZrO 2 (8YSZ) were m…

High-Temperature Coating BehaviorsNuclear Materials and PropertiesThermal and Kinetic Analysis

Influence of ageing conditions on the mechanical properties of Te–As–Se fibres

Gaëlle Delaizir、Jean‐Christophe Sanglebœuf、Ellyn A. King 等 8 位作者2009-04-06Journal of Physics D Applied Physics

Influence of ageing conditions on the mechanical properties of Te–As–Se fibres, Delaizir, Gaelle, Sangleboeuf, Jean-Christophe, King, Ellyn A, Gueguen, Yann, Zhang, Xiang-Hua, Boussard-Pledel, Catherine, Bureau, Bruno, Lucas, Pierre

Glass properties and applicationsChalcogenide Semiconductor Thin FilmsPhase-change materials and chalcogenides

Adsorption of glycerol from biodiesel washwaters

Shetian Liu、Sanjana Reddy Musuku、Sushil Adhikari 等 4 位作者2009-04-06Environmental Technology

The removal of glycerol by adsorption from biodiesel washwaters has been studied at room temperature using various adsorbent materials, including activated carbons, clay minerals, and natural and synthetic zeolites. Activated carbon exhibited the best adsorption for glycerol among the examined materials. Glycerol adso…

Supercapacitor Materials and FabricationCatalysis for Biomass ConversionMembrane Separation and Gas Transport

Converging biconcave metallic lens by double-negative extraordinary transmission metamaterial

Miguel Navarro‐Cía、Miguel Beruete、M. Sorolla 等 4 位作者2009-04-06Applied Physics Letters

In this letter we present simulation and experimental results of a left-handed converging biconcave metallic lens made of stacked subwavelength hole arrays (SSHAs) working in the millimeter wave range with additional features of polarizer and frequency filter. The converging behavior of the biconcave metallic lens, in…

Metamaterials and Metasurfaces ApplicationsPlasmonic and Surface Plasmon ResearchAdvanced Antenna and Metasurface Technologies

Hydrothermal Synthesis: A Suitable Route to Elaborate Nanomanganites

Ana Querejeta‐Fernández、Áurea Varela、M. Parras 等 6 位作者2009-04-06Chemistry of Materials

A tunable hydrothermal synthesis of single-crystalline BaMnO 3 nanoparticles is reported. The parameters governing the synthesis pathway are carefully evaluated, assessing their influence on both the morphology and size of the as-prepared products. The reactor filling volume is found to have a main influence on the pa…

Magnetic and transport properties of perovskites and related materialsMultiferroics and related materialsAdvanced Condensed Matter Physics

Theoretical Investigation of the Excited States of 2‐Nitrobenzyl and 4,5‐Methylendioxy‐2‐nitrobenzyl Caging Groups†

Klaus Schaper、Mihajlo Etinski、Timo Fleig2009-04-06Photochemistry and Photobiology

The photochemistry of caged compounds of the o-nitrobenzyl type has been investigated thoroughly in the past. However, even recently new side reactions have been discovered. Earlier, we reported [Bley, F., K. Schaper, and H. Görner (2008), Photochem. Photobiol.84 162-171] that we found long-lived triplet states which…

Photochromic and Fluorescence ChemistryPhotoreceptor and optogenetics researchbioluminescence and chemiluminescence research

Critical slowing down of relaxation dynamics near the Curie temperature in the relaxor Pb(Sc0.5Nb0.5)O3

Muhtar Ahart、Anwar Hushur、Yonghong Bing 等 6 位作者2009-04-06Applied Physics Letters

Brillouin spectroscopy of Pb(Sc0.5Nb0.5)O3 single crystals reveals an order-disorder ferroelectric phase transition occurs at 110 °C upon cooling. A softening of the longitudinal acoustic (LA) mode is observed that can be attributed to the coupling between polar nanoregions and acoustic modes. A critical slowing down…

Ferroelectric and Piezoelectric MaterialsMultiferroics and related materialsAcoustic Wave Resonator Technologies

Influence of phenolic hydroxyl groups on second-order optical nonlinearity at an example of 2,4- and 3,4-dihydroxyl hydrazone isomorphic crystals

O‐Pil Kwon、Mojca Jazbinšek、Jung‐In Seo 等 8 位作者2009-04-06The Journal of Chemical Physics

We investigate the crystal structure and physical properties of 2,4- and 3,4-dihydroxybenzaldehyde-4-nitrophenylhydrazone (DHNPH) isomer crystals to understand the relation between molecular ordering with noncovalent interactions based on phenolic OH groups. The microscopic and macroscopic optical nonlinearities of 2,…

Crystal structures of chemical compoundsCrystallography and molecular interactionsNonlinear Optical Materials Research

Morphology induced magnetoresistance enhancement of tunneling junctions with the Heusler electrode Co2Cr0.6Fe0.4Al

Christian Herbort、Elena Arbelo Jorge、Martin Jourdan2009-04-06Applied Physics Letters

A large magnetoresistance is expected when half-metallic ferromagnets are used in magnetic tunneling junctions with polycrystalline AlOx barrier. We demonstrate by in situ tunneling microscopy how the atomically smooth morphology of Co2Cr0.6Fe0.4Al Heusler thin films results in unfavorable wetting properties of the Al…

Magnetic properties of thin filmsMXene and MAX Phase MaterialsHeusler alloys: electronic and magnetic properties

Potential for C−H Activation in CH4Utilizing a CuMFI-Type Zeolite as a Catalyst

Atsushi Itadani、Hiroyuki Sugiyama、Masashi Tanaka 等 7 位作者2009-04-06The Journal of Physical Chemistry C

We have found that a copper ion-exchanged MFI (Mobil Five)-type zeolite, having an ion exchange capacity of 112% (CuMFI-112), exhibits a specific interaction with CH 4, even at room temperature. The observed properties are very remarkable compared with those found in the adsorbed amount of sodium ion-exchanged MFI and…

Metal-Organic Frameworks: Synthesis and ApplicationsCatalytic Processes in Materials ScienceCatalysis and Oxidation Reactions

Characteristic switching and dielectric parameters of ferro- and anti-ferroelectric phases of (S)-(+)-(1-methylheptyloxycarbonyl) phenyl 4′-(6-perfluoropentanoyloxyhex-1-oxy) biphenyl-4-carboxylate

Aanchal Dwivedi、Ravindra Dhar、R. Dąbrowski 等 4 位作者2009-04-06Journal of Physics D Applied Physics

We have studied spontaneous polarization, switching time and dielectric parameters (namely dielectric strength, relaxation frequency, distribution parameter) of a 5 µm thick planar oriented sample of a highly tilted anti-ferroelectric liquid crystal material (S)-(+)-(1-methylheptyloxycarbonyl) phenyl 4'-(6-perfluorope…

Liquid Crystal Research AdvancementsNonlinear Optical Materials ResearchSynthesis of Organic Compounds

A Novel Narrow Band Red‐Emitting Phosphor for White Light Emitting Diodes

Sivakumar Vaidyanathan、Duk Young Jeon2009-04-06International Journal of Applied Ceramic Technology

Research on down conversion phosphor materials is the key for the development of solid‐state lighting (SSL). Especially finding alternative red phosphor for white light emitting diodes (LEDs) based on blue or near ultraviolet (NUV) LEDs is important research task. In this view, we have synthesized a series of Eu 3+ ‐s…

Luminescence Properties of Advanced MaterialsGas Sensing Nanomaterials and SensorsAmmonia Synthesis and Nitrogen Reduction