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Effects of magnetic fields on crystal growth

Andrew Kao、K. Pericleous、Mayur Patel 等 4 位作者2009-07-22International Journal of Cast Metals Research

The effects of a constant uniform magnetic field on thermoelectric currents during dendritic solidification were investigated using a two-dimensional enthalpy based numerical model. Using an approximation for three-dimensional unconstricted growth, the resulting Lorentz forces generate a circulating flow influencing t…

Aluminum Alloy Microstructure PropertiesSolidification and crystal growth phenomenananoparticles nucleation surface interactions

Luminescence Study of ZnS Quantum Dots Prepared by Chemical Method

S. Nath、D. Chakdar、Gautam Gope 等 5 位作者2009-07-22Journal of Dispersion Science and Technology

We report synthesis of ZnS quantum dots by chemical method at room temperature. In this technique, ZnS quantum dots are produced by simple chemical reactions where zeolite, acts as matrix, plays the key role in controlling particle growth during synthesis. Quantum dots exhibit luminescence properties such as Zn2+ rela…

Quantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin FilmsCarbon and Quantum Dots Applications

Effect of melt flow on dendritic growth in AlSi7-based alloys during directional solidification

G. Zimmermann、László Sturz、Mark Walterfang 等 4 位作者2009-07-22International Journal of Cast Metals Research

High-strength automotive components are often made of AlSi7-based alloys. A very challenging problem with aluminium casting is the influence of melt flow during solidification, because it affects the microstructure formation and therefore the material properties. The scope of this paper is to investigate the effect of…

Aluminum Alloy Microstructure PropertiesSolidification and crystal growth phenomenaMetallurgy and Material Forming

Analysis of the transport properties of iron pnictides: Spin-fluctuation scenario

P. Prelovšek、I. Sega、Takami Tohyama2009-07-22Physical Review B

We present a phenomenological theory of quasiparticle scattering and transport relaxation in the normal state of iron pnictides based on the simplified two-band model coupled via spin fluctuations. In analogy with anomalous properties of cuprates it is shown that a large and anomalous normal-state resistivity and ther…

Physics of Superconductivity and MagnetismIron-based superconductors research

Modeling of the migration of glycerol monoester plasticizers in highly plasticized poly(vinyl chloride)

Rasmus Lundsgaard、Georgios M. Kontogeorgis、Jørgen K. Kristiansen 等 4 位作者2009-07-22Journal of Vinyl and Additive Technology

Abstract Different migration models were evaluated on the basis of data from migration experiments carried out by Danisco in 2005. The migration experiments were set up to investigate the behavior of the three plasticizers GRINDSTED®SOFT‐N‐SAFE (SNS), GRINDSTED®ACETEM 95 CO (Acetem), and epoxidized soybean oil (ESBO)…

biodegradable polymer synthesis and propertiesPolymer Science and PVC

Optimization of Arrays of Gold Nanodisks for Plasmon-Mediated Brillouin Light Scattering

Ward L. Johnson、S. A. Kim、Zhandos Utegulov 等 5 位作者2009-07-22The Journal of Physical Chemistry C

Distributions of electric fields in two-dimensional arrays of gold nanodisks on a Si 3 N 4 membrane, with light incident through the membrane, are modeled with the aim of determining array geometries for effective plasmon-mediated Brillouin light scattering (“surface-enhanced Brillouin scattering”) from phonons or mag…

Gold and Silver Nanoparticles Synthesis and ApplicationsPlasmonic and Surface Plasmon ResearchNear-Field Optical Microscopy

Free-carrier contribution to the optical response of N-rich Cu3N thin films

N. Gordillo、R. González-Arrabal、A. Álvarez‐Herrero 等 4 位作者2009-07-22Journal of Physics D Applied Physics

The influence of nitrogen excess on the optical response of N-rich Cu 3 N films is reported. The optical spectra measured in the wavelength range from 0.30 to 20.00 µm have been correlated with the elemental film composition which can be adjusted in the nitrogen atomic percentage (at%) range from 27 ± 2 up to 33 ± 2.…

ZnO doping and propertiesSemiconductor materials and devicesCopper-based nanomaterials and applications

Mesoporous Silica: A Suitable Adsorbent for Amines

Cyrus Zamani、Xavi Illa、Sara Abdollahzadeh‐Ghom 等 5 位作者2009-07-22Nanoscale Research Letters

Mesoporous silica with KIT-6 structure was investigated as a preconcentrating material in chromatographic systems for ammonia and trimethylamine. Its adsorption capacity was compared to that of existing commercial materials, showing its increased adsorption power. In addition, KIT-6 mesoporous silica efficiently adsor…

Catalytic Processes in Materials ScienceZeolite Catalysis and SynthesisMesoporous Materials and Catalysis

In vitro Anti-Leishmanial and Anti-Tumour Activities of a Pentacyclic Triterpenoid Compound Isolated from the Fruits of Dregea volubilis Benth Asclepiadaceae

B Moulisha、MN Bikash、P Partha 等 6 位作者2009-07-22Tropical Journal of Pharmaceutical Research

Purpose: Dregea volubilis Benth, commonly known as Jukti in Bengal, is used in the treatment of boils and abscesses from ancient times. The purpose of this study is to elucidate the active compounds and as well as their anti-leishmanial and anti-tumour activities. Methods: Dried and crushed fruits of Dregea volubilis…

Natural product bioactivities and synthesisPhytochemical compounds biological activitiesPhytochemistry and Bioactive Compounds

Synthesis and Characterization of Chloropentaaryloxycyclotriphosphazene Derivatives

Zhiyu Ju、Yong Ye、Le Wang 等 5 位作者2009-07-22Phosphorus, sulfur, and silicon and the related elements

Five chloropentaaryloxycyclotriphosphazene derivatives were synthesized by the reaction of hexachlorocyclotriphosphazene with potassium phenoxide in tetrahydrofuran. A satisfactory yield could be obtained when a 5.1 : 1(KOC 6 H 4 R : P 3 N 3 Cl 6 ) molar ratio was used. The new compounds were characterized by IR, 1H N…

Flame retardant materials and propertiesOrganophosphorus compounds synthesisSynthesis of Organic Compounds

An idea to treat the dendritic morphology in mixed columnar–equiaxed solidification

Menghuai Wu、Andreas Ludwig2009-07-22International Journal of Cast Metals Research

To treat mixed columnar–equiaxed solidification with dendritic morphology, five phase regions have been distinguished: extradendritic melt, interdendritic melt and solid dendrites in equiaxed grains, interdendritic melt and solid dendrites in columnar arrays of dendrites. These five phases are quantified by their volu…

Aluminum Alloy Microstructure PropertiesSolidification and crystal growth phenomenaMetallurgical Processes and Thermodynamics

Effect of the Catalyst Load on Syngas Production in Short Contact Time Catalytic Partial Oxidation Reactors

Stefania Specchia、Luigi Domenico Vella、Barbara Lorenzut 等 6 位作者2009-07-22Industrial & Engineering Chemistry Research

Short contact time catalytic partial oxidation (SCT-CPO) of natural gas is a promising technology for syngas production, representing an appealing alternative to existing processes. This process is likely to become more important in the future due to its advantages in thermodynamics, mildly exothermic overall reaction…

Catalytic Processes in Materials ScienceCatalysts for Methane ReformingCatalysis and Oxidation Reactions

Engineering responsive mechanisms to control the assembly of peptide-based nanostructures

Steven N. Dublin、Yuri Zimenkov、Vincent P. Conticello2009-07-22Biochemical Society Transactions

Complex biological machines arise from self-assembly on the basis of structural features programmed into sequence-specific macromolecules (i.e. polypeptides and polynucleotides) at the molecular level. As a consequence of the near-absolute control of macromolecular architecture that results from such sequence specific…

Supramolecular Chemistry and ComplexesSupramolecular Self-Assembly in MaterialsPolydiacetylene-based materials and applications

Upconverted fluorescence in Er-doped ZBLAN glasses for high efficiency solar cells

Bastian Henke、B. Ahrens、Jacqueline A. Johnson 等 5 位作者2009-07-22Proceedings of SPIE, the International Society for Optical Engineering/Proceedings of SPIE

Transparent erbium-doped fluorozirconate (FZ) glasses are attractive systems for upconversion-based solar cells. Upconverted fluorescence intensity vs. excitation power dependence was investigated for a series of erbium-doped FZ glasses. It was found that the ratio of the 2-photon upconverted emission in the near infr…

Glass properties and applicationsThin-Film Transistor TechnologiesPhotochemistry and Electron Transfer Studies

Electrically active defects in silica-filled epoxy as revealed by light emission analysis

Eddy Aubert、G. Teyssèdre、C. Laurent 等 5 位作者2009-07-22Journal of Physics D Applied Physics

Epoxy resins have long been used as the insulation of electrical systems. They are generally formulated with a dispersion of micro-fillers to improve thermal and mechanical properties. However, there are concerns about the possible influence of these fillers on the electric behaviour, especially on the long term agein…

Advanced Sensor and Energy Harvesting MaterialsHigh voltage insulation and dielectric phenomenaSmart Materials for Construction

Formation of polymer brushes inside cylindrical pores: A computer simulation study

Alexandros Koutsioubas、Nikolaos Spiliopoulos、Dimitris L. Anastassopoulos 等 5 位作者2009-07-22The Journal of Chemical Physics

The formation process of polymer brushes, formed by the adsorption of flexible end-functionalized chains from dilute solutions on the inner surface of cylindrical pores is studied by bond fluctuation Monte Carlo simulations. Various properties as the grafting density, monomer, and free-end distribution are monitored a…

Surface Modification and SuperhydrophobicityPolymer Surface Interaction StudiesForce Microscopy Techniques and Applications

Functionalized nanoparticles for bioanalysis by SERRS

Duncan Graham、Karen Faulds、David Thompson 等 10 位作者2009-07-22Biochemical Society Transactions

Metallic nanoparticles can be used as basic materials for a wide variety of purposes including building blocks for nanoassemblies, substrates for enhanced spectroscopies such as fluorescence and Raman and as labels for biomolecules. In the present paper, we report how silver and gold nanoparticles can be functionalize…

Gold and Silver Nanoparticles Synthesis and ApplicationsAdvanced biosensing and bioanalysis techniquesBiosensors and Analytical Detection

Improvement of aqueous solubility of fenretinide and other hydrophobic anti-tumor drugs by complexation with amphiphilic dextrins

Isabella Orienti、Guendalina Zuccari、Roberta Carosio 等 4 位作者2009-07-22Drug Delivery

This study relates to the preparation of a series of amphiphilic dextrins and their evaluation as complexing agents for anti-tumor hydrophobic drugs such as fenretinide, paclitaxel, etoposide, and camptothecin. The amphiphilic dextrins were obtained by conjugation of low molecular weight dextrin (average molecular wei…

Nanoparticle-Based Drug DeliveryDrug Transport and Resistance MechanismsProtein Interaction Studies and Fluorescence Analysis

Preparation and characterization of cellulose and konjac glucomannan blend film from ionic liquid

Zhaoju Yu、Yuanqin Jiang、Weiwei Zou 等 5 位作者2009-07-22Journal of Polymer Science Part B Polymer Physics

Abstract Blend films from cellulose and konjac glucomannan (KGM) in room temperature ionic liquid 1‐allyl‐3‐methylimidazolium chloride were satisfactorily prepared by coagulating with water. The composition of the blend films was gravimetrically analyzed, and the compatibility of the two natural polymers was character…

Advanced Cellulose Research StudiesLignin and Wood ChemistryPolysaccharides Composition and Applications

Dendritic Superstructures and Structure Transitions of Asymmetric Poly(l-lactide-b-ethylene oxide) Diblock Copolymer Thin Films

Shaoyong Huang、Shichun Jiang、Xuesi Chen 等 4 位作者2009-07-22Langmuir

The evolution of morphologies of isothermally crystallized thin films with different thicknesses of poly(L-lactide-b-ethylene oxide) diblock copolymer was observed by optical microscopy (OM) and atomic force microscopy (AFM). Dendritic superstructures stacked with lamellae were investigated in thin films with approxim…

Polymer crystallization and propertiesbiodegradable polymer synthesis and propertiesBlock Copolymer Self-Assembly