Materials Literature
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CO 2 reforming of methane over Ir loaded Ce 0.9 Gd 0.1 O 2− x (Ir/CGO) has been studied between 600 and 800 °C and for CH 4 /CO 2 ratios between 2 and 0.66 in order to evaluate its potential use as an anode material for direct conversion of biogas at moderate temperatures in solid oxide fuel cells. The catalyst exhibi…
Photoinduced primary charge-separation and charge-recombination are characterized by a combination of time-resolved optical and EPR measurements of a fullerene-porphyrin-linked triad that undergoes fast, stepwise charge-separation processes. The electronic coupling for the energy-wasting charge recombination is evalua…
In a previous paper (Michel, M.; Vautier, D.; Voegel, J.-C.; Schaaf, P.; Ball, V. Langmuir 2004, 20, 4835), we showed that phospholipid vesicles can be incorporated into poly(glutamic-acid)/poly(allylamine) (PGA/PAH) multilayered polyelectrolyte films built by the alternated dipping of a surface in polyanion and polyc…
Uniform CePO(4)@LaPO(4) and CePO(4):Tb(3+)@LaPO(4) one-dimensional single-crystalline nanocable heterostructures with highly enhanced photoluminescent emission have been synthesized via a mild and simple hydrothermal approach. The resulting one-dimensional single-crystalline nanocable heterostructures have smooth and…
Abstract Due to increased awareness on the part of end users and pressure from legislators, the composite industry has begun investigating the possibility of increasing the proportion of recycled or biodegradable composite materials. Accordingly, efforts are being deployed to find alternative reinforcement and resin s…
We investigate the effect of defects on the low temperature thermal conductance in nanowire structure by using the scattering-matrix method. It is found the behavior of the thermal conductance versus temperature is qualitatively different for different types of defects. When the defect is void, the universal quantum t…
To clarify the feasibility of using novel chitosan-based hyaluronan hybrid polymer fibers as a scaffold in ligament tissue engineering, their mechanical properties and ability to promote cellular adhesion, proliferation, and extracellular matrix production were studied in vitro. Chitosan fibers and chitosan-based 0.05…
This work demonstrated a facile route for the synthesis of poly(3,5-dimethyl aniline) nanofibers by polymerization of 3,5-dimethyl aniline using Pd-acetate as the oxidant. The reduction of Pd ion is accompanied by oxidative polymerization of 3,5-dimethyl aniline, leading to a metal-polymer composite material. Palladiu…
Two carboxylate-substituted, fluorescent (Phi = 0.08), water-soluble poly(p-phenyleneethynylene)s (PPE) and a water-soluble model compound were exposed to a series of proteins and bovine serum. While the anionic PPEs do not have any specific binding sites, they form stable complexes with histone, lysozyme, myoglobin,…
Recently, genetic studies have revealed the entire amino acid sequence of Bombyx mori silk fibroin. It is known from X-ray diffraction studies that the beta-sheet crystalline structure (silk II) of fibroin is composed of hexaamino acid sequences of GAGAGS. However, in the heavy chain of B. mori silk fibroin, there are…
ADVERTISEMENT RETURN TO ISSUEPREVCommunicationNEXTCarbon Nanotube-Adsorbed Polystyrene and Poly(methyl methacrylate) MicrospheresHyoung-Joon Jin, Hyoung Jin Choi, Seok Ho Yoon, Seung Jun Myung, and Sang Eun ShimView Author Information Department of Polymer Science and Engineering and Department of Chemical Engineering…
The magnetic arrangement in the vicinity of the interface between a ferromagnet and an antiferromagnet is investigated, in particular its dependence on the exchange couplings and the temperature. Applying a Heisenberg model, both sc(001) and fcc(001) lattices are considered and solved by a mean field approximation. De…
Evanescent wave amplification has been predicted under the ideal condition that the index of refraction, n=−1+i0 precisely, but is difficult to observe in practice because current metamaterials suffer from high losses. We present experimental results on a metamaterial that employs superconducting Nb metals and low-los…
Abstract In this paper we consider and compare special classes of static theories of gradient elasticity, nonlocal elasticity, gradient micropolar elasticity and nonlocal micropolar elasticity with only one gradient coefficient. Equilibrium equations are presented but higher‐order boundary conditions are not of concer…
We develop a theory for two-dimensional diluted magnetic semiconductor systems (e.g., Ga(1-x)Mn(x)As layers) where the itinerant carriers mediating the ferromagnetic interaction between the impurity local moments, as well as the local moments themselves, are confined in a two-dimensional layer. The theory includes exa…
Two-dimensional electron and hole gas systems, enabled through band structure design and epitaxial growth on planar substrates, have served as key platforms for fundamental condensed matter research and high performance devices. The analogous development of one-dimensional (1D) electron or hole gas systems through con…
Precise arrays of sub-100 nm diameter nanodots are fabricated from magnetic oxide perovskites with the total coverage area up to 5 mm2. Epitaxial single crystal structure of the nanodots is demonstrated by cross-sectional TEM. Low temperature MFM study confirmed the ferromagnetism of the produced particles.
Extending our earlier observations of the deviations from Summerfield scaling in a crystalline ferroelectric system of SBCT, we have studied the scaling of conductivity in another ferro/piezoelectric perovskite crystalline oxide, PZT. The deviations from Summerfield scaling are found at T greater than TC. Correction t…
We have studied the bound states of the extra electron in a molecular wire, corresponding to the physical situation of the electron tunneling through the wire. Based on formalism of the scattering operator that accounts for many-electron interactions we have shown that the energy spectrum of the bound states of the ex…
The use of single-walled carbon nanotube (SWNT) networks as templates for the electrodeposition of metal (Ag and Pt) nanostructures is described. Pristine SWNTs, grown on insulating SiO2 surfaces using catalyzed chemical vapor deposition, served as the working electrode. In the simplest case, electrical contact was ma…