Materials Literature
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Chitosan/poly(methacrylic acid) complexes, CS/PMAA, were prepared via dropwise addition of a solution of PMAA to a solution of chitosan in acetic acid 2 wt %. The increase in molecular weight of PMAA inhibited the formation of insoluble complexes, while the increase in ionic strength first favored the formation of the…
Two-dimensional (2-D) compact photonic crystal reflectors on suspended InP membranes were studied under normal incidence. We report the first experimental demonstration of 2-D broadband reflectors (experimental stopband superior to 200 nm, theoretical stopband of 350 nm). They are based on the coupling of free space w…
We study magnetization reversal processes of in-plane magnetized (Ga,Mn)As epilayers with different hole concentrations in out-of-plane magnetic fields using magnetotransport measurements. A clear difference in the magnetization process is found in two separate samples with hole concentrations of 10^20 cm^-3 and 10^21…
The decomposition of ozone in water at different solution pHs in the absence or presence of activated carbons with different surface chemistries and textural properties was investigated. Activated carbon acts as a catalyst in the decomposition of ozone into radical species, significantly accelerating this process. Hom…
Abstract Summary: The effects of various additives: poly( D ‐lactic acid) (PDLA), talc, fullerene C 60 , montmorillonite, and various polysaccharides, on the non‐isothermal crystallization behavior of poly( L ‐lactic acid) (PLLA), during both the heating of melt‐quenched films from room temperature, and the cooling of…
We present a study of the magnetic order and the structural stability of two-dimensional quantum spin systems in the presence of spin-lattice coupling. For a square lattice it is shown that the plaquette formation is the most favourable form of static two-dimensional dimerization. We also demonstrate that such distort…
Highly ordered mesoporous titania films consisting of crystalline nanopillars with open-spaced, perpendicular, and continuous porosity have been prepared via structural transformation from a 3D hexagonal mesostructure during the thermal treatment. The mechanism of the structural transformation is explained by the crys…
Abstract This paper presents a review of the principle and technologies in reactive extrusion and their application in starch modification and preparation of starch derivatives, such as starch graft copolymers, glycosides, cationic starch, or oxidized starch. The applications of reactive extrusion in producing other b…
First-principles simulations have been performed for [001]-ordered Mn/Ge and Mn/GaAs "digital alloys", focusing on the effects of i) a larger band-gap and ii) a different semiconducting host on the electronic structure of the magnetic semiconductors of interest. Our results for the exchange constants in Mn/Ge, evaluat…
The scattering determinant for the scattering of waves from several obstacles is considered in the case of elastic solids with voids. The multi-scattering determinant displays contributions from periodic ray-splitting orbits. A discussion of the weights of such orbits is presented.
Traumatic injury to the central nervous system (CNS) triggers cell death and deafferentation, which may activate a cascade of cellular and network disturbances. These events often result in the formation of irregularly shaped lesions comprised of necrotic tissue and/or a fluid-filled cavity. Tissue engineering represe…
We herein present the preparation, crystal structure, magnetic properties, and theoretical study of new heterobimetallic chains of formula {[Fe(III)(bpym)(CN4)]2M(II)(H2O)2}.6H2O [bpym = 2,2'-bipyrimidine; M = Zn (2), Co (3), Cu (4), and Mn (5)] which are obtained by using the building block PPh4[Fe(bpym)(CN)4].H2O (1…
A hydrothermal carbonization route has been designed for the syntheses of uniform core−shell Te@carbon-rich composite nanocables with ultrathin and ultralong Te nanowires as the core component and carbonaceous matter with remarkable reactivity as the shell, using ultralong Te nanowires of several nanometers in diamete…
Polyaniline (PANI)/Au composite hollow spheres were successfully synthesized using polystyrene/sulfonated polystyrene core/shell gel particle templates. The PANI shell thickness and the number of Au nanoparticles decorating the PANI could be controlled effectively by adjusting the experimental conditions. The morpholo…
A method for homogenizing heterogeneous catalyst is described. The method is based on growing polyaminoamido (PAMAM) dendrons on silica-coated magnetic nanoparticles. After the dendronizing process, the silica-coated magnetic nanoparticles are more stable and more soluble in organic solvents. The dendronized particles…
Nanoparticles (1-100 nm) comprise the latest technological advances designed to do everything from absorb environmental toxins to deliver drugs to a target organ. Recently, however, they have come under scrutiny for the potential to cause environmental damage. Because compounds in this miniature size range have chemic…
A near-field electrospinning (NFES) process has been developed to deposit solid nanofibers in a direct, continuous, and controllable manner. A tungsten electrode with tip diameter of 25 microm is used to construct nanofibers of 50-500 nm line width on silicon-based collectors while the liquid polymer solution is suppl…
Abstract Two different test apparatuses are used at BAM to evaluate the safety of oxygen components: First, the “promoted ignition combustion test” according to ASTM G 124 [1] and to EIGA IGC Doc 13/02/E [2], and second, the new “metallic disk ignition test” that has not been standardized yet. The standard test method…
Abstract It is shown that the heat conductivity of carbon fiber (CF)‐reinforced aromatic polyamide on the basis of phenylone can be described within the framework of a fractal model. Depending on the dimension of filler fibers network (system), such description can be obtained by the application of two limiting cases:…
Accurate measurements of the temperature dependence of spontaneous polarization and dielectric constant in the vicinity of the phase transition from the paraelectric to the ferroelectric phase in ${\mathrm{SrTi}}^{18}{\mathrm{O}}_{3}$ were performed. Dielectric constant and soft mode frequency can be well described [M…