Materials Literature
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We present a review of experimental, theoretical, and molecular simulation studies of confinement effects on freezing and melting. We consider both simple and more complex adsorbates that are confined in various environments (slit or cylindrical pores and also disordered porous materials). The most commonly used molec…
A lithographically patterned inductive-capacitive resonator is described that has a strong electric response. This resonator can be used to construct metamaterials with desired positive or negative permittivity. Such materials provide an alternative to wire media, and have the benefit of not requiring continuous curre…
Nephrogenic fibrosing dermopathy (NFD) is an acquired, idiopathic disorder that is observed in patients with renal disease. Most patients with NFD have undergone dialysis for renal failure [1,2]. It tends to affect mostly the middle-aged. An association of NFD with coagulation abnormalities, recent vascular surgery or…
Single crystals of a new complex phosphate, calcium sodium vanadium phosphate, Ca8.42Na1.16V(PO4)7, have been grown from a melt under an inert atmosphere. The crystal structure has rhombohedral (R3c) symmetry and belongs to the whitlockite structure type. Vanadium(III) ions occupy nearly regular octahedral sites (M5…
Abstract CsxH3−xPW12O40 salts prepared by a simple solid-synthesis method show good catalytic activity in n-butane isomerization as those analogues prepared by traditional liquid-preparation method.
Poly(3,4-ethylenedithiathiophene) (PEDTT) is a polythiophene-like conjugated polymer in which each thiophene ring is functionalized with an ethylenedithia bridge. As such, PEDTT is the sulfur analogue of the well-known poly(3,4-ethylenedioxythiophene) (PEDOT). Substituent effects, namely the presence of sulfur atoms i…
Miscibility of homogeneous propylene/ethylene (P/E) copolymers of relatively narrow molecular weight distribution was studied as a function of constituent comonomer content. Polymers with up to 31 mol % ethylene were blended in pairs in order to vary the comonomer content difference. Binary blends were rapidly quenche…
The systematic behavior of the charge-transfer (CT) energies in mixed 2,2'-bipyridyl (bipy), N,N-diethyldithiocarbamate (Et2dtc-) complexes of the trivalent lanthanides, Ln(Et2dtc)3(bipy), is investigated to understand the electronic structure of f-element complexes containing soft donor ligands. The energies of ligan…
Silver bis(3,5,5-trimethyl-1-hexyl) sulfosuccinate, Ag-AOT-TMH, exhibits 1.2 wt % solubility in dense CO 2 at 40 °C and 52 MPa. This is a remarkably high CO 2 solubility value for a nonfluorous organometallic compound. Silver nanoparticles were produced by reducing the supercritical CO 2 solution containing 0.06 wt %…
Heating hausmanite ZnMn 2 O 4 in a reducing atmosphere results in the formation of rock salt MnO with significant Zn substitution. Further heating at elevated temperatures under reducing conditions results in Zn being reduced and expelled in the vapor phase, leaving behind nearly pure rock salt MnO. Used judiciously,…
The edges of channels etched into topographically patterned substrates impart orientational order to monolayers of poly(styrene- b -2-vinylpyridine) cylinders. Quantitative measures of orientational order as well as defect densities are presented for cylinder arrays confined in channels of width varying between 1 and…
A novel inherently conducting polymer, high-quality polyfluoranthene (PFA) film with electrical conductivity of 10(-2) S cm(-1), was first synthesized electrochemically by direct anodic oxidation of fluoranthene in a middle strong Lewis acid-boron trifluoride diethyl etherate. The oxidation potential onset of fluorant…
In this article, we report the synthesis of methylene-bridged periodic mesoporous organosilicas (PMOs) of the SBA-15 type. The materials were characterized by SAXS, BET, NMR, FESEM, and TEM. It was found that the synthesis of methylene-bridged SBA-15 PMOs requires more rigorous conditions than that of SBA-15 PMOs bear…
NaAlH(4) with TiCl(3) and Al were mixed by ball-milling and cycled three times. The hydrogen storage properties were monitored during cycling, and the products were characterized by synchrotron X-ray diffraction. Because of the previously described formation of Al(1)(-)(y)Ti(y) with y approximately 0.15 during cycling…
Using rheological techniques, we investigate the evolution of the microstructure evolution during the early stages of quiescent crystallization of poly(1-butene). In performing the measurements, use is made of an innovative experimental protocol, called “inverse quenching”, which allows stopping the crystallization pr…
A chiral thioether-substituted phthalocyanine ((2,3,9,10,16,17,23,24-octakis-1-phenylethylthiophthalocyaninato)magnesium(II) [MgPc(SEtPh)8]) has been synthesized, which can be bound by soft-metal ions such as palladium(II) ion. Aggregates formed from MgPc(SEtPh)8 and Pd(II) in toluene and at the toluene/water interfac…
Fast switching of a photochromic dye in a rigid host matrix has been achieved without any modification of electronic nature of the photochromic entity. The method utilizes living radical polymerization (atom transfer radical polymerization (ATRP)) to grow a low glass transition temperature ( T g ) poly( n -butyl acryl…
We present a novel route to assemble perpendicular cylinders by converting an asymmetric diblock copolymer from poly(styrene-b-tert-butyl acrylate) (PS-b-PtBA) to poly(styrene-b-acrylic acid) (PS-b-PAA) using an autocatalytic reaction. Upon exposure of the films of PS-b-PAA to water, PAA cylinders constrained by the c…
Twenty years after their invention, sol-gel organically modified silicates (ORMOSIL) are finding a number of impressive applications that range from efficient deliver of genes into mouse brains to self-ordered helices of interest to fields as diverse as optics, catalysis, molecular recognition, and chromatography. The…
In this work, we describe the synthesis and electropolymerization of conjugated substituted polyacetylenes, poly( N -alkoxy-( p -ethynylphenyl)carbazole) or PPA-Cz-Cn with electropolymerizable carbazole side groups to form conjugated polymer network (CPN) films. The phenylacetylene monomer was functionalized with a ca…