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Why gold nanoparticles are more precious than pretty gold: Noble metal surface plasmon resonance and its enhancement of the radiative and nonradiative properties of nanocrystals of different shapes

Susie Eustis、Mostafa A. El‐Sayed2005-12-16OpenAlex

This tutorial review presents an introduction to the field of noble metal nanoparticles and their current applications. The origin of the surface plasmon resonance and synthesis procedures are described. A number of applications are presented that take advantage of the electromagnetic field enhancement of the radiativ…

Nanoparticles: synthesis and applicationsGold and Silver Nanoparticles Synthesis and ApplicationsNanocluster Synthesis and Applications

Materials aspects of laser-ablation-deposited cuprate∕manganate bilayers for spin-polarized injection devices

R. A. Chakalov、G. Passerieux、I.P. Jones 等 8 位作者2005-12-15Journal of Applied Physics

We report studies of cuprate∕manganate bilayers deposited onto SrTiO3 substrates by laser ablation. A significant difference in the properties of the individual layers is observed depending on the material deposition sequence. The material which is on the bottom of the multilayer shows worse properties, e.g., a critic…

Physics of Superconductivity and MagnetismMagnetic and transport properties of perovskites and related materialsElectronic and Structural Properties of Oxides

The structure of Omeprazole in the solid state: a 13C and 15N NMR/CPMAS study

Rosa M. Claramunt、Concepción López、José Elguero2005-12-15ARKIVOC

The 13 C and 15 N CPMAS spectra of a solid sample of Omeprazole have been recorded and all the signals assigned. The sample consists uniquely of the 6-methoxy tautomer. For analytical purposes, the signals of the other tautomer, the 5-methoxy one, were estimated from the data in solution (Magn.

Crystal structures of chemical compoundsSolid-state spectroscopy and crystallographyX-ray Diffraction in Crystallography

Synthesis and characterization of poly(phenylacetylene)s carrying oligo(ethylene oxide) pendants

Junwu Chen、Kevin Ka‐Leung Cheuk、Ben Zhong Tang2005-12-15Journal of Polymer Science Part A Polymer Chemistry

Abstract A group of new amphiphilic poly(phenylacetylene)s bearing polar oligo(ethylene oxide) pendants, poly{4‐[2‐(2‐hydroxyethoxy)ethoxy]phenylacetylene} ( 1 ), poly(4‐{2‐[2‐(2‐hydroxyethoxy)‐ethoxy]ethoxy}phenylacetylene) ( 2p ), poly(3‐{2‐[2‐(2‐hydroxyethoxy)ethoxy]ethoxy}phenylacetylene) ( 2m ), poly(4‐{2‐[2‐(2‐m…

Advanced Battery Materials and TechnologiesConducting polymers and applicationsSynthesis and Properties of Aromatic Compounds

Negative refraction and partial focusing in an anisotropic metamaterial realized by a loaded transmission line network

Xiaohua Teng、Junming Zhao、Tian Jiang 等 4 位作者2005-12-15Journal of Physics D Applied Physics

We have studied the electromagnetic wave propagation in a two-dimensional anisotropic metamaterial (AMM) realized by a periodic structure composed of an anisotropically loaded transmission line (TL) network. The dispersion relation of the TL metamaterial is analysed by rigorous periodic TL theory, which shows hyperbol…

Antenna Design and AnalysisMetamaterials and Metasurfaces ApplicationsAdvanced Antenna and Metasurface Technologies

Zein Dynamic Adsorption to Carboxylic and Alkyl Coated Surfaces

Qin Wang、Qian Wang、Xuejun Wang 等 4 位作者2005-12-15Journal of Agricultural and Food Chemistry

The adsorption of a commercial zein sample on carboxylic (COOH) and alkyl (CH(3)) surfaces was monitored by high time resolution surface plasmon resonance. Zein showed higher affinity and higher mass adsorption on carboxylic than alkyl surfaces. A zein layer specific for each surface was obtained after flushing off lo…

Analytical chemistry methods developmentPolymer Surface Interaction StudiesDiatoms and Algae Research

Nonionic fluorescent oligomeric surfactant for ordered mesoporous silica structure

Fu‐Yu Tsai、Hsiung‐Lin Tu、Chung‐Yuan Mou2005-12-15Journal of Materials Chemistry

A fluorescent oligomeric surfactant prepared by multi-step synthesis was used as a template to obtain ordered mesostructured silica, the fluorescent surfactant completely fills the nano-channels and the emission spectrum shows that the composite is red-shifted 32 nm when compared with the surfactant in aqueous solutio…

Mesoporous Materials and CatalysisPorphyrin and Phthalocyanine ChemistryDiatoms and Algae Research

Electronic structure and magnetism in sodium nickelate: Density-functional and model studies

Hakim Meskine、S. Satpathy2005-12-15Physical Review B

The electronic structure and magnetism in $\mathrm{Na}\mathrm{Ni}{\mathrm{O}}_{2}$ are studied from density-functional calculations and by solving model Hamiltonians, suggested from the density-functional results, to understand the magnetic exchange. The density-functional calculations within the LSDA approximation yi…

Magnetic and transport properties of perovskites and related materialsRare-earth and actinide compoundsAdvanced Condensed Matter Physics

Low potential electrosyntheses of free‐standing poly(dibenzofuran) films in mixed electrolytes of boron trifluoride diethyl etherate and trifluoroacetic acid

Jingkun Xu、Weiqiang Zhou、Bing Chen 等 6 位作者2005-12-15Journal of Polymer Science Part A Polymer Chemistry

Abstract Free‐standing poly(dibenzofuran) (PDBF) films were synthesized electrochemically by direct anodic oxidation of dibenzofuran in mixed electrolytes of boron trifluoride diethyl etherate (BFEE) containing certain amount of trifluoroacetic acid (TFA). The oxidation potential of dibenzofuran in pure BFEE was measu…

Organic Electronics and PhotovoltaicsConducting polymers and applicationsAnalytical Chemistry and Sensors

Characterization of nanoporous Si thin films obtained by Al–Si phase separation

Kazuhiko Fukutani、Youhei Ishida、Toshiaki Aiba 等 5 位作者2005-12-15Applied Physics Letters

Nanoporous silicon films of ultrahigh pore densities and large surface areas have been fabricated by sputtering an Al–Si target and subsequent removal of the deposited film’s Al regions by etching in a sulfuric acid solution. The resulting nanoporous films are mainly composed of amorphous silicon and have cylindrical…

Semiconductor materials and devicesSilicon Nanostructures and PhotoluminescenceAnodic Oxide Films and Nanostructures

Natural Polymer-Based Compositions Designed for Use in Conformance Gel Systems

B. R. Reddy、Larry Eoff、E. Dwyann Dalrymple 等 4 位作者2005-12-15SPE Journal

Summary This article describes a crosslinking material derived from natural sources that can be used with a variety of polymers over a broad temperature range to produce gels for conformance applications. Delayed crosslinked polymer systems have been used for many years in conformance applications. For the past decade…

biodegradable polymer synthesis and properties

Cloning and characterization of a gene encoding a cold-shock protein inLactobacillus casei

Nicolas Sauvageot、Sophie Beaufils、Alain Mazé 等 5 位作者2005-12-15FEMS Microbiology Letters

One csp-like gene, called cspA, from the lactic acid bacterium Lactobacillus casei was identified by an inverse polymerase chain reaction approach based on degenerate primers. cspA encodes a protein of 66 amino acid residues, which displays at least 74% identity with Csp proteins of Lactobacillus genera. Northern blot…

Protein Structure and DynamicsProbiotics and Fermented FoodsEnzyme Structure and Function

Miscibility study of solution cast blends of poly(lactic acid) and poly(vinyl butyral)

Jagjit R. Khurma、David Rohindra、Rajlakshmi Devi2005-12-15South Pacific journal of natural and applied sciences

Poly(lactic acid) (PLA) was blended with poly(viny1 butyral) (PVB) through solution casting method using chloroform as the common solvent. The films obtained were characterized for miscibility using Differential Scanning Calorimetry (DSC), tensile testing and FTIR spectroscopy. The DSC results showed that the glass-tr…

biodegradable polymer synthesis and propertiesMicroplastics and Plastic PollutionCarbon dioxide utilization in catalysis

Isotropic Knight shift of metallic carbon nanotubes

Oleg V. Yazyev、Lothar Helm2005-12-15Physical Review B

We study the isotropic $^{13}\mathrm{C}$ Knight shifts of conducting carbon nanotubes from first principles. We find that the values of the shifts provide information about the chirality indices of nanotubes. For carbon nanotubes wider than $0.5\phantom{\rule{0.3em}{0ex}}\mathrm{nm}$ the dominating spin-polarization e…

Carbon Nanotubes in CompositesTopological Materials and PhenomenaMechanical and Optical Resonators

[13C,15N]2-Acetamido-2-deoxy-d-aldohexoses and Their Methyl Glycosides: Synthesis and NMR Investigations of J-Couplings Involving 1H, 13C, and 15N

Yuping Zhu、Qingfeng Pan、Christophe Thibaudeau 等 6 位作者2005-12-15The Journal of Organic Chemistry

[reaction: see text] A series of 2-amino-2-deoxy-D-[1-13C]aldohexoses and their methyl glycosides was prepared with use of a simplified cyanohydrin reduction route. Four d-aldopentosylamines (arabino, lyxo, ribo, xylo) were prepared from the corresponding D-aldopentoses by reaction with NH3(g) in MeOH solvent, isolate…

DNA and Nucleic Acid ChemistryEnzyme Structure and FunctionAdvanced NMR Techniques and Applications

Effects of heat treatment and magnetoannealing on nanocrystalline Co-ferrite powders

Y. C. Wang、Jun Ding、Jianhua Yin 等 6 位作者2005-12-15Journal of Applied Physics

This work consists of three parts: the effects of heat treatment (slow cooling and quenching), magnetoannealing, and postannealing of samples with induced anisotropy. It has been found that noncomplete inverse spinel structure was the result after annealing at higher temperature and quenching. Our Mössbauer spectrosco…

Magnetic properties of thin filmsMagnetic Properties and Synthesis of FerritesIron oxide chemistry and applications

A Small-Angle X-ray Scattering Study of the Interactions in Concentrated Silica Colloidal Dispersions

Dong Qiu、Terence Cosgrove、Andrew M. Howe 等 4 位作者2005-12-15Langmuir

The structure factors of colloidal silica dispersions at rather high volume fractions (from 0.055 to 0.22) were measured by small-angle X-ray scattering and fitted with both the equivalent hard-sphere potential model (EHS) and the Hayter-Penfold/Yukawa potential model (HPY). Both of these models described the interact…

Material Dynamics and PropertiesSoil and Unsaturated FlowElectrostatics and Colloid Interactions

Refractive index gradients in TiO2thin films grown by atomic layer deposition

Aarne Kasikov、Jaan Aarik、Hugo Mändar 等 6 位作者2005-12-15Journal of Physics D Applied Physics

Transmission spectra of TiO2 films grown by atomic layer deposition on fused silica have been analysed by using Lorentz dispersion and a model consisting of two sublayers inside a film. It has been shown that the deposition process parameters significantly influenced the refractive index gradient in the film growth di…

Semiconductor materials and devicesCopper Interconnects and ReliabilityOptical Coatings and Gratings

Manipulation of single-wall carbon nanotubes into dispersively aligned arrays between metal electrodes

Changxin Chen、Yafei Zhang2005-12-15Journal of Physics D Applied Physics

A dispersively aligned carbon nanotube array has been achieved between metal electrodes by electric-field assisted manipulation of surface modified single-wall carbon nanotubes (SWCNTs). Surface modification of SWCNTs with octadecylamine (ODA) molecules creates well-dispersed SWCNT solutions and effectively obviates t…

Carbon Nanotubes in CompositesGraphene research and applicationsNanotechnology research and applications

Effects of reversible and irreversible ferroelectric switchings on the piezoelectric large-signal response of lead zirconate titanate thin films

Peter Arne Gerber、C. Kügeler、U. Böttger 等 4 位作者2005-12-15Journal of Applied Physics

The effects of reversible and irreversible switching processes on the electromechanical large-signal strain S of tetragonal Pb(Zrx,Ti1−x)O3 thin films are investigated and discussed. Starting from electric small- and large-signal measurements, the percentage of switched unit cells cesw is calculated. The result is the…

Ferroelectric and Piezoelectric MaterialsUltrasonics and Acoustic Wave PropagationAcoustic Wave Resonator Technologies