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In vitro degradation of poly(L‐ lactic acid) fibers in phosphate buffered saline

Xiaoyan Yuan、Arthur F. T. Mak、Kangde Yao2002-05-21Journal of Applied Polymer Science

Abstract In vitro degradation of poly( L ‐lactic acid) (PLLA) fibers was studied by incubating the fibers in phosphate buffered saline (pH 7.4) at 37°C for 35–45 weeks. Three kinds of PLLA fibers with different diameters and different initial viscosity‐average molecular weights were tested. The viscosity‐average molec…

biodegradable polymer synthesis and propertiesMicroplastics and Plastic PollutionAdditive Manufacturing and 3D Printing Technologies

Synthetic hydrocerussite, 2PbCO3·Pb(OH)2, by X-ray powder diffraction

Pauline Martinetto、Michel Anne、E. Dooryhée 等 5 位作者2002-05-21Acta Crystallographica Section C Crystal Structure Communications

Synthetic hydrocerussite [trilead dihydroxide dicarbonate, Pb(3)(CO(3))(2)(OH)(2)] can be easily obtained, as a white powder, by the action of carbon dioxide and water on either lead or litharge at pH 4-5. This compound is also found in lead corrosion technological products as a fine-grained phase. Ab initio crystal s…

Crystal Structures and PropertiesChemical Synthesis and CharacterizationX-ray Diffraction in Crystallography

Electrochemical Synthesis and Characterization of Magnetic Nanoparticles on Carbon Nanowall Templates

Bingjun Yang、Yihong Wu、B. Y. Zong 等 4 位作者2002-05-21Nano Letters

Magnetic nanoparticles (Ni, CoNiFe) with diameters ranging from 30 to 200 nm were synthesized by electrodeposition using carbon nanowalls as templates. A series of experiments have been carried out to study the formation mechanism of nanoparticles. It was found that the formation of nanoparticles instead of continuous…

Advancements in Battery MaterialsElectrocatalysts for Energy ConversionSupercapacitor Materials and Fabrication

Growth pulsations in symmetric dendritic crystallization in thin polymer blend films

Vincent Ferreiro、Jack F. Douglas、James A. Warren 等 4 位作者2002-05-21Physical review. E, Statistical physics, plasmas, fluids, and related interdisciplinary topics

The crystallization of polymeric and metallic materials normally occurs under conditions far from equilibrium, leading to patterns that grow as propagating waves into the surrounding unstable fluid medium. The Mullins-Sekerka instability causes these wave fronts to break up into dendritic arms, and we anticipate that…

Solidification and crystal growth phenomenaRheology and Fluid Dynamics StudiesFluid Dynamics and Thin Films

An Indication of Magnetic-Field-Induced Superconductivity in a Bifunctional Layered Organic Conductor, κ-(BETS)2FeBr4

Hideki Fujiwara、Hayao Kobayashi、Emiko Fujiwara 等 4 位作者2002-05-21Journal of the American Chemical Society

Hybrid systems consisting of the conducting layers of organic donor molecules and the magnetic layers of inorganic anions have been focused on as possible bifunctional materials, whose conducting properties can be tuned by controlling the magnetic state of the anion layers on an application of magnetic field. Here we…

Perovskite Materials and ApplicationsOrganic and Molecular Conductors ResearchSolid-state spectroscopy and crystallography

Intermediate length scale dynamics of polyisobutylene

B. Farago、Arantxa Arbe、Juan Colmenero 等 6 位作者2002-05-21Physical review. E, Statistical physics, plasmas, fluids, and related interdisciplinary topics

We report on a neutron spin echo investigation of the intermediate scale dynamics of polyisobutylene studying both the self-motion and the collective motion. The momentum transfer (Q) dependences of the self-correlation times are found to follow a Q(-2/beta) law in agreement with the picture of Gaussian dynamics. In t…

Material Dynamics and PropertiesQuantum, superfluid, helium dynamicsNMR spectroscopy and applications

Site-Selective EXAFS in Mixed-Valence Compounds Using High-Resolution Fluorescence Detection: A Study of Iron in Prussian Blue

Pieter Glatzel、Lilian Jacquamet、Uwe Bergmann 等 5 位作者2002-05-21Inorganic Chemistry

A quantitative analysis is presented for the site-selective Fe K-edge absorption spectra of Prussian Blue: Fe(4)[Fe(CN)(6)](3) x xH(2)O (x = 14-16). The site-selective spectra were recorded using high-resolution fluorescence detection of the K beta emission from a polycrystalline sample. The K beta fluorescence lines…

Magnetism in coordination complexesLanthanide and Transition Metal ComplexesX-ray Spectroscopy and Fluorescence Analysis

Internal Structure of Silver−Poly(amidoamine) Dendrimer Complexes and Nanocomposites

M. Francesca Ottaviani、Regina Valluzzi、Lajos Balogh2002-05-21Macromolecules

Poly(amidoamine) PAMAM dendrimers of various generations (generation 2 to generation 6) with different surfaces (amine, Tris, and pivalate) were used as organic templates to form complexes and nanocomposites of silver. Starting from silver salts and PAMAM dendrimers, first a silver−dendrimer complex and then a nanocom…

Conducting polymers and applicationsDendrimers and Hyperbranched PolymersFerrocene Chemistry and Applications

Evidence for an unusual dynamical-arrest scenario in short-ranged colloidal systems

Giuseppe Foffi、Kenneth A. Dawson、Sergey V. Buldyrev 等 6 位作者2002-05-21Physical review. E, Statistical physics, plasmas, fluids, and related interdisciplinary topics

Extensive molecular dynamics simulation studies of particles interacting via a short-ranged attractive square-well potential are reported. The calculated loci of constant diffusion coefficient D in the temperature-packing fraction plane show a reentrant behavior, i.e., an increase of diffusivity on cooling, confirming…

Phase Equilibria and ThermodynamicsMaterial Dynamics and PropertiesSpectroscopy and Quantum Chemical Studies

DFT Calculation of NMR JFF Spin−Spin Coupling Constants in Fluorinated Pyridines

Verónica Barone、Juan E. Peralta、Rubén H. Contreras 等 4 位作者2002-05-21The Journal of Physical Chemistry A

All four isotropic contributions to the NMR fluorine−fluorine coupling constants (Fermi contact, FC, spin-dipolar, SD, paramagnetic spin−orbit, PSO, and diamagnetic spin−orbit, DSO) have been calculated for 2,6-difluoropyridine, 2,4,6-trifluoropyridine, perfluoropyridine, and 2-Br-3,4,5,6,7,8-hexafluoroquinoline by me…

Magnetism in coordination complexesAdvanced NMR Techniques and ApplicationsElectron Spin Resonance Studies

Enthalpic Stabilization of Brush-Coated Particles in a Polymer Melt

Itamar Borukhov、Ludwik Leibler2002-05-21Macromolecules

The interaction between spherical particles covered with end-grafted polymers (brushes) immersed in a polymer melt is studied theoretically. It has been known for some time that two densely grafted brushes may attract each other in the presence of a chemically identical polymer melt. In this study we show that this at…

Polymer Surface Interaction StudiesForce Microscopy Techniques and ApplicationsAdhesion, Friction, and Surface Interactions

Electron self-energy and effective mass in a single heterostructure

Xiu-Kun Hua、Yin-Zhong Wu、Zhen-Ya Li2002-05-21arXiv

In this paper, we investigate the electron self-energy and effective mass in a single heterostructure using Green-function method. Numerical calculations of the electron self-energy and effective mass for GaAs/AlAs heterostructure are performed. The results show that the self energy (effective mass) of electron, which…

Materials Science

Anisotropic magnetoresistance inGa1−xMnxAs

David V. Baxter、Dmitry Ruzmetov、Julia Scherschligt 等 7 位作者2002-05-21Physical review. B, Condensed matter

We have measured the magnetoresistance in a series of ${\mathrm{Ga}}_{1\ensuremath{-}x}{\mathrm{Mn}}_{x}\mathrm{As}$ samples with $0.033<~x<~0.053$ for three mutually orthogonal orientations of the applied magnetic field. The spontaneous resistivity anisotropy (SRA) in these materials is negative (i.e., the samp…

ZnO doping and propertiesMagnetic and transport properties of perovskites and related materialsElectronic and Structural Properties of Oxides

Local texture and fatigue crack initiation in a Ti‐6Al‐4V titanium alloy

K. Le Biavant、Sylvie Pommier、C. Prioul2002-05-21Fatigue & Fracture of Engineering Materials & Structures

ABSTRACT Fatigue crack initiation was studied in a bimodal TA6V titanium alloy. A ghost structure inherited from the forging process, the scale of which is roughly 100 times the apparent grain size, was found to govern the initiation process. In these macrograins, that we have labelled macrozones, most of the primary…

Fatigue and fracture mechanicsHydrogen embrittlement and corrosion behaviors in metalsTitanium Alloys Microstructure and Properties

Comment on ``Anisotropic s-wave superconductivity: comparison with experiments on MgB_2 [A. I. Posazhennikova, T. Dahm and K. Maki, cond-mat/0204272; submitted to Europhys. Lett.]

T. M. Mishonov、E. S. Penev、J. O. Indekeu2002-05-21arXiv

An analytical result for the renormalization of the jump of the heat capacity Delta C/C_N by the anisotropy of the order parameter is derived within the framework of the very recent model proposed by Posazhennikova, Dahm and Maki [cond-mat/0204272, submitted to Europhys. Lett.], for both oblate and prolate anisotropy.…

Materials ScienceSuperconductivity

Bi-continuum modelling of layered structures and crystalline interfaces

M. Sztyren2002-05-21arXiv

The bi-continuum model composed of two interpenetrating and dynamically coupled material continua is analysed as a simplified but relatively accurate way to describe some physical phenomena in crystalline solids. The essential novelty of our approach consists in treating a crystalline medium as bi-continuum, even if t…

Materials Science

Charge-density-wave phase transition in1T−TiSe2: Excitonic insulator versus band-type Jahn-Teller mechanism

Kai Roßnagel、L. Kipp、M. Skibowski2002-05-21Physical review. B, Condensed matter

The influence of the charge-density-wave phase transition on the electronic structure of $1T\ensuremath{-}{\mathrm{TiSe}}_{2}$ is studied by means of high-resolution angle-resolved photoemission spectroscopy with synchrotron radiation. We find that both the Se $4p$-type valence band maximum at $\ensuremath{\Gamma}$ an…

2D Materials and ApplicationsOrganic and Molecular Conductors ResearchIron-based superconductors research

A novel precursor for synthesis of pure boron nitride nanotubesElectronic supplementary information (ESI) available: (a) experimental apparatus and details; (b) Fig. S2, XRD pattern of BN nanotubes; (c) XRD pattern of the product formed by dispersive Mg at the surface of the graphite susceptor; (d) Fig. S4, EELS spectrum of BN nanotubes; (e) Fig. S5, selected-area electron diffraction; (f) Fig. S6, EDS analysis of open tip. See http://www.rsc.org/suppdata/cc/b2/b202177c/

Chengchun Tang、Yoshio Bando、Tadao Sato 等 4 位作者2002-05-21OpenAlex

A novel precursor, a mixture of B2O2 and Mg which is generated in situ by reacting B and MgO at 1300 degrees C, can be used to effectively synthesize bulk amounts of pure BN nanotubes with Mg evaporated from the final product; transmission electron microscope observation for the synthesized BN nanotubes indicates that…

Graphene research and applicationsBoron and Carbon Nanomaterials ResearchMXene and MAX Phase Materials

Size Tunable Visible Luminescence from Individual Organic Monolayer Stabilized Silicon Nanocrystal Quantum Dots

Douglas S. English、Lindsay E. Pell、Zhonghua Yu 等 5 位作者2002-05-21OpenAlex

Quantum confinement in nanostructured silicon can lead to efficient light emission. However, the photoluminescence (PL) lifetimes in nanostructured silicon are typically very long−approximately 3 orders of magnitude longer than those of direct band gap semiconductors. Herein, we show that organic monolayer coated sili…

Quantum Dots Synthesis And PropertiesSilicon Nanostructures and PhotoluminescenceCarbon and Quantum Dots Applications