Materials Literature
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Ultraviolet laser excited surface-enhanced Raman scattering (UV−SERS) was obtained on platinum and palladium surfaces using adenine and SCN − as the probe molecules. Diverse Pt and Pd nanoparticles, i.e., Pt nanospheres, Pt nanocubes, and Au core Pt or Pd shell nanoparticles with different shell thicknesses, were synt…
Miscibility and intermolecular interactions of novel blends of poly(N-vinyl-2-pyrrolidone) (PVP) and acid functional polyester resins (APE) were studied by use of Differential Scanning Calorimetry (DSC), Attenuated Total Reflectance Fourier Transform Infrared (ATR-FTIR), Cross-Polarization Magic Angle Spinning (CPMAS)…
The crystal structures of KMn(4)(PO(4))(3) and KCo(4)(PO(4))(3) have been determined by neutron diffraction at room temperature. Both compounds are orthorhombic with similar cell parameters, but they crystallize in different space groups, Pnam for the Mn phosphate and Pnnm for the Co analogue. On the basis of the meta…
This Test Guideline describes a method to assess bioaccumulation of sediment-associated chemicals in endobenthic oligochaetes worms. It applies to stable, neutral organic chemicals having log Kow values between 3.0 and 6.0, superlipophilic substances that show a log Kow of more than 6.0, or stable metallo-organic comp…
Abstract In atomized spray quenching, the spraying water is atomized into fine droplets of the size of about 20 μm by compressed air and sprayed onto a hot surface. Only single droplets touch the surface, become deformed, and transfer heat. The drops partially evaporate and then move away from the superposed airflow.…
Internally alkynylated or cyanated N-confused porphyrins have been prepared, and these have been characterized by NMR, UV/Vis/NIR absorption, and X-ray analysis. The desired porphyrins have been synthesized by interconversion between an N-confused porphyrin and an N-fused porphyrin. In the case of terminal alkyne deri…
Bio-inspired chemistry based on photoresponsive molecules is a rapidly developing new strategy to mimic the function of various biological systems. The interaction of electromagnetic radiation with molecular systems is ideally suited for the control and powering of dynamic processes at the speed of light. Besides typi…
We consider the capillary absorption of liquid metal droplets by carbon nanotubes using molecular dynamics simulations and the steady-state flow model due to Marmur [A. Marmur, J. Colloid Interface Sci. 122, 209 (1988)]. We find an exact solution to Marmur's evolution equation for the height of the absorbed liquid col…
The steady propagation of an air finger into a fluid-filled tube of uniform rectangular cross-section is investigated. This paper is primarily focused on the influence of the aspect ratio, α, on the flow properties, but the effects of a transverse gravitational field are also considered. The three-dimensional interfac…
Energy dispersive X-ray diffraction and X-ray absorption spectra of two CoFe Prussian blue analogues were collected under variable pressure at room temperature: one of them is essentially composed of Co II and Fe III ions and undergoes a Co II −Fe III → Co III −Fe II pressure-induced electron transfer, whereas the oth…
Abstract In step‐growth polymerizations, the molar concentration of reactive linear species (oligomers and polymers) decreases with higher conversions and finally reaches zero at 100% conversion. This self‐dilution favors cyclization at the expense of chain‐growth. Cyclization reduces the average lengths of the linear…
The use of short chain block copolymer melts as nanostructured templates with sub-10 nm domains is often limited by their low segregation strength (χ N ). Since increasing molar mass to strengthen segregation also increases the interdomain spacing of block copolymer melts, it is more desirable to increase the Flory−Hu…
We study the infrared conductivity of graphene at finite chemical potential and temperature taking into account the effect of phonons and disorder due to charged impurities and unitary scatterers, that is, considering all possible single-particle scattering mechanisms. The screening of the long-range Coulomb potential…
A remarkably bent diiron(III) mu-oxobisporphyrin containing a highly flexible ethane linker is reported that authenticates, for the first time, the unprecedented ability of this platform to "open" and "close" its binding pockets, leading to facile syn-anti conformational switching with very high vertical flexibility o…
In contrast to LLA, DLA is converted in toluene solution under mild reaction conditions (50-70 degrees C) using Novozyme 435 (immobilized CALB) to form the corresponding polymer. The influence of several parameters, such as enzyme concentration, temperature and monomer concentration, on the polymerization rate and the…
In this work, we provide theoretical evidence on the existence of energetically stable chiral structures for bare gold clusters. Density functional theory calculations within the generalized-gradient approximation were performed to systematically study structural, vibrational, electronic, and optical properties of the…
A comprehensive first-principles theoretical study of the electronic properties and half-metallic nature of finite zigzag carbon nanotubes is presented. Unlike previous reports, we find that all nanotubes studied present a spin-polarized ground state, where opposite spins are localized at the two zigzag edges in a lon…
Abstract Poly(glycidyl methacrylate) (PGMA) was synthesized by the RAFT method in the presence of 2‐cyanoprop‐2‐yl dithiobenzoate (CPDB) chain transfer agent using different [GMA]/[CPDB] molar ratios. The living radical polymerization resulted in controlled molecular weights and narrow polydispersity indices ( PDI ) o…
No place like kagome: A quaternary amphiphile displays a novel complex liquid-crystalline phase formed by a periodic array combining triangular and hexagonal cylinders, filled with hydrocarbon and fluorinated chains, respectively. This leads to a fluid nanoscale multicompartment structure with kagome geometry. The thi…
The synthesis and evaluation of new dopamine-based catechol anchors coupled to poly(ethylene glycol) (PEG) for surface modification of TiO(2) are reported. Dopamine is modified by dimethylamine-methylene (7) or trimethylammonium-methylene (8) groups, and the preparation of mPEG-Glu didopamine polymer 11 is presented.…