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Optical studies of CdS:Mn nanoparticles

R. K. Sharma2011-12-27Luminescence

Cadmium sulphide nanoparticles were grown using a wet chemical method, by dissolving the reactants, cadmium chloride and sodium sulphide in water, in the presence of mercaptoethanol (ME), which was used as a capping agent. Manganese chloride was used to dope the nanoparticles. It was found that the particle size varie…

Quantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin FilmsNanowire Synthesis and Applications

The effect of expansion conditions on the batch foaming dynamics of St–MMA copolymer

Hamid Reza Azimi、Mostafa Rezaei、Farhang Abbasi2011-12-27Journal of Cellular Plastics

In this study, we synthesized styrene–methyl methacrylate copolymer particles by suspension polymerization process to study the foaming dynamics via visual batch foaming apparatus. The weight ratio of styrene–methyl methacrylate was 53–47. The foaming system consisted of a self-sealing observation cell equipped with t…

Advanced Polymer Synthesis and CharacterizationPolymer composites and self-healingPolymer Foaming and Composites

Porous exfoliated poly(ε‐caprolactone)/clay nanocomposites: Preparation, structure, and properties

Oana M. Istrate、Biqiong Chen2011-12-27Journal of Applied Polymer Science

Abstract Porous biodegradable poly(ε‐caprolactone) (PCL)/clay nanocomposites were prepared by incorporating a blowing agent into the galleries of an organoclay, followed by mixing the pretreated organoclay and PCL to give partially intercalated and exfoliated nanocomposites and subsequently degrading the blowing agent…

biodegradable polymer synthesis and propertiesElectrospun Nanofibers in Biomedical ApplicationsPolymer Foaming and Composites

Correlation between spinning temperature, membrane morphology, and performance of Psf/PVP/NMP/Water hollow fiber membrane forming system

Ganpat J. Dahe、Rohit Teotia、Jayesh Bellare2011-12-27Journal of Applied Polymer Science

Abstract Asymmetric polysulfone (Psf)/polyvinylpyrrolidone (PVP) hollow fiber membranes were fabricated via dry‐wet spinning process in a custom made apparatus with controlled spinneret and spinning lines temperature. This study investigated the effect of isothermal spinning temperatures on morphology, performance, an…

Membrane Separation TechnologiesSurface Modification and SuperhydrophobicityElectrospun Nanofibers in Biomedical Applications

CO2 Separation From Combined Cycles Using Molten Carbonate Fuel Cells

Giampaolo Manzolini、Stefano Campanari、Paolo Chiesa 等 6 位作者2011-12-27Journal of Electrochemical Energy Conversion and Storage

This paper presents an analysis of advanced cycles with limited CO2 emissions based onthe integration of molten carbonate fuel cells (MCFCs) in natural gas fired combined cycles (NGCC) in order to efficiently capture CO2 from the exhaust of the gas turbine. In the proposed cycles, the gas turbine flue gases are used a…

Advancements in Solid Oxide Fuel CellsCarbon Dioxide Capture TechnologiesCO2 Reduction Techniques and Catalysts

Effects of plasticization conditions on the structures and properties of cellulose packaging films from ionic liquid [BMIM]Cl

Zhengwei Jin、Shuo Wang、Jianqing Wang 等 4 位作者2011-12-27Journal of Applied Polymer Science

Abstract By using natural softwood pulp with higher degree of polymerization (DP = 1460) as cellulose source, 1‐butyl‐3‐methylimidazolium chloride ([BMIM]Cl) ionic liquid as solvent and glycerol as plasticizer, a novel cellulose packaging film was prepared. The effects of plasticization conditions on the structures, m…

Nanocomposite Films for Food PackagingAdvanced Cellulose Research StudiesLignin and Wood Chemistry

Relating fracture behavior to spherulite size in conrolled‐rheology polypropylenes

A. Salazar、A. Rico、S. Rodríguez 等 5 位作者2011-12-27Polymer Engineering and Science

Abstract The influence of the spherulite size and distribution on the fracture toughness and Izod impact strength at different temperatures of controlled‐rheology polypropylenes with 0, 154, 402, and 546 ppm of peroxide has been evaluated. As the peroxide content increased, the average spherulite size was enhanced and…

Polymer crystallization and propertiesPolymer Nanocomposites and Propertiesbiodegradable polymer synthesis and properties

Development of the scratch resistance on acrylic sheet with basic colloidal silica (SiO2)—methyltrimethoxysilane (MTMS) nanocomposite films by sol–gel technique

Rojcharin Chantarachindawong、W. Luangtip、Pongpan Chindaudom 等 5 位作者2011-12-27The Canadian Journal of Chemical Engineering

Abstract The formation of scratch‐resistant coating film prepared from colloidal silica and a polysiloxane matrix was investigated. Methyltrimethoxysilane (MTMS) was hydrolysed and mixed with silica sol (SiO 2 ) at various compositions to form the hybrid hard‐coating nanocomposite film. The hydrolysed MTMS (polysiloxa…

Metal and Thin Film MechanicsPolymer Nanocomposites and PropertiesSilicone and Siloxane Chemistry

Functionalization of SiC(110) Surfaces via Porphyrin Adsorption: Ab Initio Results

Alessandra Catellani、Arrigo Calzolari2011-12-27The Journal of Physical Chemistry C

We investigate molecular sensitization of the nonpolar SiC(110) surface by means of density functional simulations. We focus on aromatic fragments up to a full porphyrin molecule, in view of potential application in biosensors and devices. Our results reveal a relatively low affinity between aromatic rings and the sur…

Graphene research and applicationsSilicon Carbide Semiconductor TechnologiesNanowire Synthesis and Applications

Charge-parity symmetry observed through Friedel oscillations in chiral charge-density waves

Junya Ishioka、T. Fujii、K. Katono 等 7 位作者2011-12-27Physical Review B

We discovered a chiral behavior of Friedel oscillations (FOs), which have both triangular symmetry and inverse chirality from chiral charge-density waves (CDWs) in 1T-TiSe${}_{2}$ by using scanning tunneling microscopy (STM). Surprisingly, the existence of FOs with the opposite chirality to the underlying CDWs suggest…

Physics of Superconductivity and Magnetism2D Materials and ApplicationsTopological Materials and Phenomena

Potential of Oil Palm Trunk Sap as a Novel Inexpensive Renewable Carbon Feedstock for Polyhydroxyalkanoate Biosynthesis and as a Bacterial Growth Medium

Bhadravathi Eswara Lokesh、Zubaidah Aimi Abdul Hamid、Takamitsu Arai 等 9 位作者2011-12-27CLEAN - Soil Air Water

Abstract Utilization of cheap renewable carbon feedstock for polyhydroxyalkanoate (PHA) production not only brings down its production cost but also ensures sustainability. The scope of this study was to evaluate the potential of sap extracted from felled oil palm trunk (OPT) as a novel inexpensive renewable carbon so…

biodegradable polymer synthesis and propertiesElectrospun Nanofibers in Biomedical ApplicationsMicroplastics and Plastic Pollution

Galvanostatic Anodic Polarization Curves and Galvanic Corrosion of AZ31B in 0.01 M Na2SO4 Saturated with Mg(OH)2

Zhiming Shi、Jimmy Xueshan Jia、Andrej Atrens2011-12-27Advanced Engineering Materials

Abstract Measured polarization curves were used in a BEM model of the galvanic corrosion of the Mg alloy AZ31B. The AZ31B galvanostatic anodic polarization curves indicated: (i) the existence of the uni‐positive Mg + ion, (ii) some hydrogen dissolved in the AZ31B metal, and (iii) self corrosion was more important than…

Corrosion Behavior and InhibitionMagnesium Alloys: Properties and ApplicationsAluminum Alloy Microstructure Properties

Ionic Crystals [M3O(OOCC6H5)6(H2O)3]4[α-SiW12O40] (M = Cr, Fe) as Heterogeneous Catalysts for Pinacol Rearrangement

Sayaka Uchida、Aldes Lesbani、Yoshiyuki Ogasawara 等 4 位作者2011-12-27Inorganic Chemistry

Complexation of trinuclear oxo-centered carboxylates with a silicododecatungstate resulted in the formation of ionic crystals of [M(3)O(OOCC(6)H(5))(6)(H(2)O)(3)](4)[α-SiW(12)O(40)]·nH(2)O·mCH(3)COCH(3) [M = Cr (Ia), Fe (IIa)]. Treatments of Ia and IIa at 373 K in vacuo formed guest-free phases Ib and IIb, respectivel…

Metal-Organic Frameworks: Synthesis and ApplicationsPolyoxometalates: Synthesis and ApplicationsVanadium and Halogenation Chemistry

Polymer-Nanocrystal Hybrid Materials for Light Conversion Applications

Ying Yuan、Michael Krüger2011-12-27Polymers

In this mini-review we report on current developments of hybrid materials based on semiconductor nanocrystals integrated into polymer matrices for direct light conversion, their present limitations, as well as their high potential for future applications.

Perovskite Materials and ApplicationsQuantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin Films

Supercritical CO 2 in injection molding can produce open porous polyurethane scaffolds – a parameter study

Hongbin Wu、Håvard Jostein Haugen、Erich Wintermantel2011-12-27Journal of Cellular Plastics

There are several methods of producing open porous polymer structures for medical use. However, very few are applicable to industries and are therefore limited to both number of samples and batch variations. This study presents an industrial microcellular injection molding process, known as MuCell® technology, which w…

Polymer composites and self-healingCarbon dioxide utilization in catalysisPolymer Foaming and Composites

A‐site magnetism in A‐site‐ordered perovskite‐structure oxides

Yuichi Shimakawa、Takashi Saito2011-12-27physica status solidi (b)

Abstract A‐site‐ordered perovskite‐structure oxides AA′ 3 B 4 O 12 with Cu 2+ ions at the A′ site are highlighted. Some new compounds were synthesized under high‐pressure and high‐temperature conditions. With nonmagnetic ions at the B site, only the Cu 2+ spins at the A′ site contribute to the magnetic properties, pro…

Ferroelectric and Piezoelectric MaterialsMultiferroics and related materialsDielectric properties of ceramics

ANALYSES AND SOLUTIONS ON TECHNICAL AND ECONOMICAL ASPECTS OF RAPID PROTOTYPING TECHNOLOGY

Jozef Novák-Marcinčin、Jozef Barna、Ľudmila Nováková-Marcinčínová 等 4 位作者2011-12-27Tehnicki vjesnik - Technical Gazette

This article deals with basic characteristics and problems in the area of technology of Rapid Prototyping using layered manufacturing technology. It belongs to progressive methods of model creation based on geometry obtained from CAD environment with application possibilities in different industrial spheres. Chapters…

Additive Manufacturing and 3D Printing TechnologiesManufacturing Process and OptimizationMaterial Selection and Properties

Synthesis and Anisotropic Properties of Novel Asymmetric Diones Fused With 1,3-Oxazepine and Oxazepane Rings

Guan‐Yeow Yeap、AbdulKarim‐Talaq Mohammad、Hasnah Osman2011-12-27Molecular Crystals and Liquid Crystals

Novel synthesis of heterocyclic liquid crystal compounds containing seven-membered 1,3-oxazepine-4,7-diones, 5,6-dihydro-1,3-oxazepane-4,7-diones, and 5,6-benzo[e] [Citation1, Citation3]oxazepine-4,7-diones rings at para position has been carried out from the reaction of maleic, succinic, and phthalic anhydrides with…

Liquid Crystal Research AdvancementsSynthesis of Organic CompoundsSynthesis and pharmacology of benzodiazepine derivatives

Free energy of alternating two-component polymer brushes on cylindrical templates

William L. Miller、Behnaz Bozorgui、Katherine Klymko 等 4 位作者2011-12-27The Journal of Chemical Physics

We use computer simulations to investigate the stability of a two-component polymer brush de-mixing on a curved template into phases of different morphological properties. It has been previously shown via molecular dynamics simulations that immiscible chains having different length and anchored to a cylindrical templa…

Polymer Surface Interaction StudiesForce Microscopy Techniques and ApplicationsAdhesion, Friction, and Surface Interactions

Memory effect in composites of liquid crystal and silica aerosil

Sabrina Relaix、Robert L. Leheny、Linda Reven 等 4 位作者2011-12-27Physical Review E

Aerosil silica nanoparticles dispersed in a liquid crystal (LC) possess the interesting property of keeping memory of an electric- or magnetic-field-induced orientation. Two types of memory have been identified: thermally erasable memory arising from the pinning of defect lines versus a "permanent" memory where the or…

Liquid Crystal Research AdvancementsPhotonic Crystals and Applications