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Radiation Hazard of Coal-Slags as Building Material in Tatabanya Town (Hungary)

J. Somlai、Mária Horváth、B. Kanyár 等 5 位作者1998-12-01Health Physics

High concentrations of 226Ra (865-2,383 Bq kg(1)) were measured in the coal-slags, originated from the region of the settlement Tatabánya, Transdanubian Middle Mountains, Hungary. These slags are commonly used as building materials in this district. The external gamma dose rate was measured in 188 rooms at different h…

Graphite, nuclear technology, radiation studiesNuclear and radioactivity studies

High‐Strength Alumina/Alumina:Calcium‐Hexaluminate Layer Composites

Linan An、Hyoung‐Chan Ha、Helen M. Chan1998-12-01Journal of the American Ceramic Society

The strength degradation of alumina/alumina:calcium‐hexaluminate/alumina trilayers, after damage from Hertzian contacts, is evaluated. Relative to the monolithic alumina and alumina:calcium‐hexaluminate constituent layer materials, the trilayers show markedly improved strength retention in the damaged state at high co…

Advanced ceramic materials synthesisMetal and Thin Film MechanicsAdvanced materials and composites

Calmodulin Binding to Myosin Light Chain Kinase Begins at Substoichiometric Ca2+ Concentrations: A Small-Angle Scattering Study of Binding and Conformational Transitions

Joanna K. Krueger、Nicholas A. Bishop、Donald Blumenthal 等 7 位作者1998-12-01Biochemistry

We have used small-angle scattering to study the calcium dependence of the interactions between calmodulin (CaM) and skeletal muscle myosin light chain kinase (MLCK), as well as the conformations of the complexes that form. Scattering data were measured from equimolar mixtures of a functional MLCK and CaM or a mutated…

Protein Structure and DynamicsCardiomyopathy and Myosin StudiesEnzyme Structure and Function

Polymer-polymer rectifying heterojunction based on poly(3,4-dicyanothiophene) and MEH-PPV

Y. Greenwald、Xiaoyan Xu、Marc Fourmigu 等 7 位作者1998-12-01Journal of Polymer Science Part A Polymer Chemistry

Thin, homogeneous films of a high electron affinity (n-dopable) polymer, poly(3,4-dicyanothiophene) (PDCTh), were prepared by in-situ thermal polymerization of 2,5-diiodo-3,4-dicyanothiophene on substrates. As a result of the presence of two cyano substituents on the thiophene backbone, PDCTh is an electronegative pol…

Organic Electronics and PhotovoltaicsConducting polymers and applicationsAnalytical Chemistry and Sensors

Coordination Chemistry ofN-Alkylbenzamide-2,3-dithiolates as an Approach to Poly(dithiolate) Ligands: 1,4-Bis[(2,3-dimercaptobenzamido)methyl]benzene and Its Chelate Complex with the (C5H5)Ti Fragment

Wolfram W. Seidel、F. Ekkehardt Hahn、Thomas Lügger1998-12-01Inorganic Chemistry

The bidentate dithiolate ligands N,N-diethyl-2,3-dimercaptobenzamide (H(2)-1), bis(N,N-diethyl-2,3-dimercaptoterephthalamide (H(2)-2), and 1,4-bis(hydroxymethyl)-2,3-dimercaptobenzene (H(4)-3) were synthesized from 2,3-dimercaptobenzoic acid or 2,3-dimercaptoterephthalic acid. The air-sensitive ligands form metallocen…

Organometallic Complex Synthesis and CatalysisMagnetism in coordination complexesOrganic and Molecular Conductors Research

First-principles calculation of the conformation and electronic structure of polyparaphenylene

Maosheng Miao、P. E. Van Camp、V. E. Van Doren 等 5 位作者1998-12-01The Journal of Chemical Physics

In this article, an all-electron first-principles total energy calculation with Gaussian-type functions for the wave functions, for the exchange correlation potential, and for the charge density has been applied for single chains of polyparaphenylene (PPP). A local-density approximation within a helical band structure…

Carbon Nanotubes in CompositesSpectroscopy and Quantum Chemical StudiesAdvanced Physical and Chemical Molecular Interactions

Model block-graft copolymer via anionic living polymerization: Preparation and characterization of polystyrene-block-[poly(p-hydroxystyrene)-graft-poly(ethylene oxide)]-block-polystyrene

Kazunori Se、Kazushige Miyawaki、Kazuhiro Hirahara 等 5 位作者1998-12-01Journal of Polymer Science Part A Polymer Chemistry

A model graft copolymer in which position of graft points was set to the center of a backbone molecule was prepared via anionic living polymerization. Polystyrene-block-poly(p-tert-butoxystyrene)-block-polystyrene (PSt-b-PBSt-b-PSt) was prepared by three-stage sequential addition. The tert-butyl group was removed from…

Advanced Polymer Synthesis and CharacterizationFuel Cells and Related Materialsbiodegradable polymer synthesis and properties

Influence of defects on electron emission from diamond films

Yoshiyuki Show、F. Matsuoka、Masaharu Hayashi 等 6 位作者1998-12-01Journal of Applied Physics

The correlation between paramagnetic defects and the electron emission in diamond films, which were deposited by the chemical vapor deposition method, has been studied using electron-spin-resonance (ESR) and field-emission measurements. The paramagnetic defects, which are a carbon dangling bond in the diamond layer (P…

Semiconductor materials and devicesDiamond and Carbon-based Materials ResearchIon-surface interactions and analysis

Radiation effects on the thermal degradation of poly(vinyl chloride) and poly(vinyl alcohol)

Wenwei Zhao、Yukio Yamamoto、Seiichi Tagawa1998-12-01Journal of Polymer Science Part A Polymer Chemistry

Radiation effects on the formation of conjugated double bonds in the thermal degradation of poly(vinyl chloride) (PVC) and poly(vinyl alcohol) (PVA) were investigated. Thin films of PVC and PVA were either irradiated with γ-rays at ambient temperature (pre-irradiation) and then subjected to thermal treatment, or irrad…

Advancements in Photolithography TechniquesPolymer Nanocomposite Synthesis and IrradiationPolymer Science and PVC

Ultrathin Coatings by Multiple Polyelectrolyte Adsorption/Surface Activation (CoMPAS)

M. M. Koetse、André Laschewsky、Bernd Mayer 等 5 位作者1998-12-01Macromolecules

A new versatile method for the preparation of thin polymer coatings is presented. It is based on the adsorption of reactive polyelectrolytes by electrostatic interactions. In a following activation step, the adsorbed polymers are modified by reacting with low molar mass reagents carrying the complementary charge, in o…

Polymer Surface Interaction StudiesMolecular Junctions and NanostructuresForce Microscopy Techniques and Applications

A biosensor approach to probe the structure and function of the adsorbed proteins: fibrinogen at the gold surface

Б. А. Снопок、K. V. Kostyukevych、O.V. Rengevych 等 7 位作者1998-12-01Semiconductor Physics Quantum Electronics & Optoelectronics

The kinetics of adsorption and surface structure of adsorbed layers of the human fibrinogen on the gold surface, determined by Surface Plasmon Resonance (SPR) and Atomic Force Microscopy (AFM) analysis, was employed to probe the lateral distribution and preferred orientation of protein molecules within the monolayer.…

Polymer Surface Interaction StudiesForce Microscopy Techniques and ApplicationsAdvanced Biosensing Techniques and Applications

Metal−Metal Bonding in d1d1 and d2d2 Bioctahedral Dimer Systems: A Density Functional Study of Face-Shared M2X93- (M = Ti, Zr, Hf, V, Nb, Ta) Complexes

Robert Stranger、John E. McGrady、Timothy Lovell1998-12-01Inorganic Chemistry

Density functional theory is used to investigate the electronic and geometric structures and periodic trends in metal-metal bonding of d(1)d(1) and d(2)d(2) face-shared M(2)X(9)(3)(-) dimers of Ti, Zr, Hf (d(1)d(1)) and V, Nb, Ta (d(2)d(2)). For these systems three distinct coupling modes can be recognized, depending…

Organometallic Complex Synthesis and CatalysisMetal complexes synthesis and propertiesMagnetism in coordination complexes

3‐D modeling of SCR of NOx by NH3 on vanadia honeycomb catalysts

B. Roduit、Alfons Baiker、Flavio Bettoni 等 5 位作者1998-12-01AIChE Journal

Abstract A novel scheme for simulating the selective catalytic reduction of NO with NH 3 on a honeycomb‐type catalyst was developed based on a 3‐D model. New insight was gained by considering such modeling aspects as: correct geometry (square ducts); hydrodynamic entrance effects; occurrence of adsorption phenomena an…

Catalytic Processes in Materials ScienceCatalysis and Oxidation ReactionsIndustrial Gas Emission Control

Study of dosimetry consistency for kilovoltage x‐ray beams

C.‐M. Charlie、X. A. Li、Jan Seuntjens1998-12-01Medical Physics

In this paper, the consistency of kilovoltage (tube potentials between 40 and 300 kV) x-ray beam dosimetry using the "in-air" method and the in-phantom measurement has been studied. The procedures for the measurement of the central-axis depth-dose curve, which serve as a link between the dose at the reference depth to…

Advanced Radiotherapy TechniquesRadiation Dose and ImagingRadiation Shielding Materials Analysis

Theoretical Analysis of Metal Hydride Electrodes: Studies on Equilibrium Potential and Exchange Current Density

Bala S. Haran、Branko N. Popov、Ralph E. White1998-12-01Journal of The Electrochemical Society

A theoretical model for the metal hydride electrode has been developed assuming that hydrogen diffusion in the alloy and charge‐transfer at the surface control the discharge process. Theoretical equations for the dependence of equilibrium potential and exchange current density on the surface hydrogen concentration hav…

Advanced Chemical Physics StudiesHydrogen Storage and MaterialsAmmonia Synthesis and Nitrogen Reduction

Organic reagent interaction with hair spatially characterized by infrared microspectroscopy using synchrotron radiation

J‐L. Bantignies、G. Fuchs、G. L. Carr 等 6 位作者1998-12-01International Journal of Cosmetic Science

Synopsis The penetration of chemical reagents through human hair after bleaching has been spatially characterized using infrared microspectroscopy (IMS) with a synchrotron source. Chemical imaging of hair cross sections before and after bleaching was achieved with high contrast, using the peptide and lipid mid‐infrare…

Silk-based biomaterials and applications

Chemical/Physical Retting of Flax Using Detergent and Oxalic Acid at High pH

Gunnar Henriksson、Karl–Erik L. Eriksson、Linda B. Kimmel 等 4 位作者1998-12-01Textile Research Journal

An oxalic acid-based system for chemically retting flax is tested and compared with enzymatic retting. The retting effect is substantially higher at pH 10 and 11 than at lower pH levels, and the optimal oxalic acid concentration is 50 mmol. The presence of the strong detergent sodium dodecyl sulfate (SDS) further enha…

Food composition and propertiesTextile materials and evaluationsEnzyme Production and Characterization

Anomalous low-temperature specific heat of charge-orderedLa0.5Ca0.5MnO3

V. N. Smolyaninova、K. Ghosh、R. L. Greene1998-12-01Physical review. B, Condensed matter

We report a study of the specific heat, resistivity, and magnetization of ${\mathrm{La}}_{1\ensuremath{-}x}{\mathrm{Ca}}_{x}{\mathrm{MnO}}_{x}$ for $x=0.47,$ 0.5, 0.53 with and without an applied magnetic field. In zero (earth) field we find that the charge-ordered materials $(x=0.5,0.53)$ have extra entropy of nonmag…

Advanced Thermoelectric Materials and DevicesMagnetic and transport properties of perovskites and related materialsAdvanced Condensed Matter Physics

Complete substitution of Si for Ti in titanite Ca(Ti (sub 1-x) Si x ) vi Si iv O 5

Ruth Knoche、R. J. Angel、F. Seifert 等 4 位作者1998-12-01American Mineralogist

Other| December 01, 1998 Complete substitution of Si for Ti in titanite Ca(Ti (sub 1-x) Si x ) vi Si iv O 5 R. Knoche; R. Knoche Universitaet Bayreuth, Bayerisches Geoinstitut, Bayreuth, Federal Republic of Germany Search for other works by this author on: GSW Google Scholar Ross J. Angel; Ross J. Angel Search for oth…

Advanced ceramic materials synthesisIntermetallics and Advanced Alloy PropertiesNuclear materials and radiation effects

Spin-Polarized Low Energy Electron Microscopy

Th. Duden、E. Bauer1998-12-01Surface Review and Letters

We present the concept and recent developments of spin-polarized low energy electron microscopy. A detailed discussion addresses the questions of magnetic resolution and the image acquisition rate. Examples of recent experiments illustrating the possibilities of the present instrumental setup are given.

Advanced Electron Microscopy Techniques and ApplicationsElectron and X-Ray Spectroscopy TechniquesPhotocathodes and Microchannel Plates