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Toward clinical application of prompt gamma spectroscopy for in vivo monitoring of boron uptake in boron neutron capture therapy

Per Munck af Rosenschöld、Wilko F.A.R. Verbakel、Crister Ceberg 等 5 位作者2001-05-01Medical Physics

In boron neutron capture therapy (BNCT) the absorbed dose to the tumor cells and healthy tissues depends critically on the boron uptake. Pronounced individual variations in the uptake patterns have been observed for two boron compounds currently used in clinical trials. This implies a high uncertainty in the determina…

Nuclear Physics and ApplicationsBoron Compounds in ChemistryRadiation Shielding Materials Analysis

Improvement of Processability of PCL and PBS Blend by Irradiation and its Biodegradability

Pramono Nugroho、Hiroshi Mitomo、Fumio Yoshii 等 5 位作者2001-05-01Macromolecular Materials and Engineering

Poly(ε-caprolactone) (PCL) was blended with poly(butylene succinate) (PBS), (PCL/PBS = 30/70) to improve the heat stability of PCL. The processability of the blended samples (PHB02) was improved due to enhancing of melt strength by γ-rays irradiation in the dose range between 10 and 50 kGy. High speed production of a…

biodegradable polymer synthesis and propertiesElectrospun Nanofibers in Biomedical ApplicationsMicroplastics and Plastic Pollution

Achromatic phase retarder by slanted illumination of a dielectric grating with period comparable with the wavelength

Nándor Bokor、Revital Shechter、Nir Davidson 等 5 位作者2001-05-01Applied Optics

We discuss some properties of dielectric gratings with period comparable with the illuminating wavelength for slanted illumination (this illumination geometry is often referred to as concical mounting). We demonstrate the usefulness of such an illuminating geometry. We show that the threshold period (under which only…

Photonic and Optical DevicesAdvanced optical system designOptical Coatings and Gratings

Soft and hard shells in metallic nanocrystals

D. Y. Sun、X. G. Gong、Xiaoqian Wang2001-05-01Physical review. B, Condensed matter

The inhomogeneous elastic properties of metallic nanocrystals are studied using semiempirical potentials for Au, Pb, Ag, and Cu. The enhanced low- and high-frequency modes are found to be spatially localized in two shells, a soft surface shell and a hard transition shell. Our analysis shows that the linear frequency d…

Microstructure and mechanical propertiesForce Microscopy Techniques and Applicationsnanoparticles nucleation surface interactions

Allosteric Binding of K+ to Crown Ether Macrocycles Appended to a Lanthanum Double Decker System

Andrew Robertson、Masato Ikeda、Masayuki Takeuchi 等 4 位作者2001-05-01Bulletin of the Chemical Society of Japan

Abstract A benzocrown-appended lanthanum(III) porphyrin double decker has been synthesized which is capable of binding simple K+ in a cooperative, allosteric fashion to form a 1 : 4 complex. Analysis of this system by means of the Hill equation gave an overall binding constant (Kb) of 1.0 × 1014 (mol dm−3)−4 and a Hil…

Molecular Sensors and Ion DetectionSupramolecular Chemistry and ComplexesPorphyrin and Phthalocyanine Chemistry

Behavior of Paramagnetic Iron during the Thermal Transformations of Kaolinite

Amédée Djemai、Etienne Balan、Guillaume Morin 等 6 位作者2001-05-01Journal of the American Ceramic Society

Kaolinites with various degrees of structural order and iron content were heated and subsequently analyzed via electron paramagnetic resonance. Iron was present in two different states in the heated materials, either as dilute structural Fe 3+ ions or in concentrated Fe 3+ phases. During metakaolinization, the environ…

Geological and Geochemical AnalysisClay minerals and soil interactionsIron oxide chemistry and applications

Sensitization to Silk and Childhood Asthma in Rural China

Juan C. Celedón、Lyle J. Palmer、Xiping Xu 等 6 位作者2001-05-01PEDIATRICS

OBJECTIVE: Sensitization to perennial aeroallergens is associated with asthma in industrialized countries with a Western lifestyle. Because silk products are commonly used in Chinese society, we were interested in examining the relation between sensitization to silk and asthma. DESIGN: Cross-sectional study of 871 chi…

Mast cells and histamineSilk-based biomaterials and applicationsAntioxidants, Aging, Portulaca oleracea

Ruscogenin glycoside (Lm-3) isolated from Liriope muscari improves liver injury by dysfunctioning liver-infiltrating lymphocytes

Feihua Wu、Jingsong Cao、Jieyun Jiang 等 5 位作者2001-05-01Journal of Pharmacy and Pharmacology

The effects of ruscogenin 1-O-[beta-D-glucopyranosyl(1 --> 2)] [beta-D-xylopyranosyl(1 --> 3)]-beta-D-fucopyranoside (Lm-3) and its aglycone, ruscogenin, on liver injury induced in mice by delayed-type hypersensitivity to picryl chloride have been investigated. Lm-3 and ruscogenin significantly decreased liver injury…

Sphingolipid Metabolism and SignalingPhytochemical Studies and BioactivitiesPhytochemistry and Bioactive Compounds

On the 1,4-cis-Polymerization of Butadiene with the Highly Active Catalyst Systems Nd(C3H5)2Cl·1.5 THF/Hexaisobutylaluminoxane (HIBAO), Nd(C3H5)Cl2· 2 THF/HIBAO and Nd(C3H5)Cl2·2 THF/Methyl-aluminoxane (MAO) – Degree of Polymerization, Polydispersity, Kinetics and Catalyst Formation

Steffen Maiwald、Christian Sommer、Gert Müller 等 4 位作者2001-05-01Macromolecular Chemistry and Physics

The allylneodymium chloride complexes Nd(C3H5)2Cl·1.5 THF and Nd(C3H5)Cl2·2 THF can be activated by adding hexaisobutylaluminoxane (HIBAO) or methylaluminoxane (MAO) in a ratio of Al/Nd = 30 for the catalysis of butadiene 1,4-cis-polymerization. A turnover frequency (TOF) of about 20 000 mol butadiene/(mol Nd·h) and c…

Organometallic Complex Synthesis and CatalysisThermal and Kinetic AnalysisChemical Thermodynamics and Molecular Structure

Role of Enzyme−Ribofuranosyl Contacts in the Ground State and Transition State for Orotidine 5‘-Phosphate Decarboxylase: A Role for Substrate Destabilization?

Brian G. Miller、Glenn L. Butterfoss、Steven A. Short 等 4 位作者2001-05-01Biochemistry

The crystal structure of yeast orotidine 5'-monophosphate decarboxylase (ODCase) complexed with the inhibitor 6-hydroxyuridine 5'-phosphate (BMP) reveals the presence of a series of strong interactions between enzyme residues and functional groups of this ligand. Enzyme contacts with the phosphoribofuranosyl moiety of…

Genetic Neurodegenerative DiseasesEnzyme Structure and FunctionBiochemical and biochemical processes

Manufacture of Powder Coatings by Spraying of Gas-Enriched Melts

E. Weidner、Marcus Petermann、K. Blatter 等 4 位作者2001-05-01Chemical Engineering & Technology

An alternative process for the manufacture of powder coatings was developed. The continuously operated process is applicable to new (low-melting and fast-reacting) and conventional powder coating systems and allows to produce coatings with improved properties. The process uses the solubility of compressed gases in mel…

Additive Manufacturing and 3D Printing TechnologiesInjection Molding Process and PropertiesPolymer Foaming and Composites

Temperature rise due to fast-moving dislocations

J. Th. M. De Hosson、Arjen Roos、E.D.F. Metselaar2001-05-01Philosophical magazine. A/Philosophical magazine. A. Physics of condensed matter. Structure, defects and mechanical properties

In this paper, the method of discrete dislocation plasticity (DDP) is extended to include explicitly the thermal effects of moving dislocations. In this manner, localization of heat during fast deformation can be calculated exactly. The thermal effects included are the thermal dissipation due to dislocation drag, the…

Microstructure and mechanical propertiesMetal and Thin Film MechanicsHigh-Velocity Impact and Material Behavior

Phenomenological Theory of Solid Oxide Fuel Cell Anode

A. S. Ioselevich、A. A. Kornyshev2001-05-01Fuel Cells

We develop a phenomenological theory of oxygen-ion-conducting porous cermet anode for solid oxide fuel cells utilizing hydrogen, based on a simple picture of macro- and microkinetics of charge and gas transport in the cermet. Its basic equations account for the transport of hydrogen molecules and oxygen anions to the…

Electrocatalysts for Energy ConversionAdvancements in Solid Oxide Fuel CellsFuel Cells and Related Materials

Magnetic Properties of Carboxylate-Bridged Ferromagnetic Copper(II) Chains Coupled by Cation−π Interactions

Antonio J. Costa‐Filho、Otaciro R. Nascimento、L. Ghivelder 等 4 位作者2001-05-01The Journal of Physical Chemistry B

The exchange interactions between copper ions in ( l -tryptophyl-glycinato)copper(II), C 13 H 13 CuN 3 O 3 (named Cu(II)Trp-Gly) are determined by ac magnetic susceptibility and dc magnetization measurements in powder samples, and by EPR measurements in single-crystal samples. The copper ions in this compound are arra…

Magnetism in coordination complexesLanthanide and Transition Metal ComplexesElectron Spin Resonance Studies

Surface‐Induced Nickel Hydroxide Precipitation in the Presence of Citrate and Salicylate

Noriko Yamaguchi、Andreas C. Scheinost、Donald L. Sparks2001-05-01Soil Science Society of America Journal

Formation of surface‐induced precipitates may play an important role in the immobilization of Ni and other metals in nonacidic soils. To investigate the influence of commonly present organic ligands on precipitate formation, we monitored the uptake of Ni by gibbsite and pyrophyllite in the presence of citrate and sali…

Clay minerals and soil interactionsIron oxide chemistry and applicationsPhosphorus and nutrient management

Ultrasonic Devulcanization Reactors for Recycling of GRT: Comparative Study

Jushik Yun、Jeonq Seok Oh、А. I. Isayev2001-05-01Rubber Chemistry and Technology

Abstract The present paper describes the comparative study of a continuous ultrasonic devulcanization of ground tire rubber (GRT) using two reactors. The devulcanization zone in the first reactor (coaxial reactor) is located at the exit from an extruder without imposition of additional shearing. In the second reactor…

Polymer crystallization and propertiesPolymer Nanocomposites and Propertiesbiodegradable polymer synthesis and properties

Thermodynamic modeling of crystal deposition in humans

Erich Königsberger、Lan-Chi Königsberger2001-05-01Pure and Applied Chemistry

Abstract The prevention and treatment of crystal deposition in the human body are based on the understanding of the physicochemical properties underlying the precipitation of the substances involved. Among these properties, the solubilities of the crystals are very important. Recently, experimentally determined solubi…

Gout, Hyperuricemia, Uric AcidCrystallization and Solubility StudiesChemical and Physical Properties in Aqueous Solutions

Raman Study of Hi‐Nicalon‐Fiber‐Reinforced Celsian Composites: II, Residual Stress in Fibers

Gwénaël Gouadec、Philippe Colomban、Narottam P. Bansal2001-05-01Journal of the American Ceramic Society

Band shifts in Raman spectra were used to assess, on a microscopic scale, the residual strain existing in Hi‐Nicalon silicon carbide fibers reinforcing celsian‐matrix composites. Uncoated as well as p‐BN/SiC‐coated and p‐B(Si)N/SiC‐coated Hi‐Nicalon fibers were used as the reinforcements. We unambiguously conclude tha…

Advanced ceramic materials synthesisMetal and Thin Film MechanicsDiamond and Carbon-based Materials Research

Photocontrolled Alignment of Chiral Nematic Liquid Crystals

Christian Ruslim、K. Ichimura2001-05-01Advanced Materials

The first successful alignment of helix axes of chiral nematic liquid crystals (LCs) by the photoalignment technique is reported here. The helix axis aligns perpendicularly to the propagation direction of the incident non-polarized light. Dark and bright images (see Figure) of the aligned helix axis of a chiral nemati…

Liquid Crystal Research AdvancementsOrbital Angular Momentum in OpticsAdvanced Optical Imaging Technologies

THE MARINE, PLANKTONIC DIATOM FAMILY THALASSIONEMATACEAE: MORPHOLOGY, TAXONOMY AND DISTRIBUTION

Grethe Rytter Hasle2001-05-01Diatom Research

The morphology, taxonomy and distribution of Thalassionema (six species), Thalassiothrix (five species), Trichotoxon (one species) and Lioloma (three species) are examined. They are needle-shaped diatoms ranging in size from a few μm to several millimetres. Colony formation is represented in all genera but apparently…

Aquatic Ecosystems and Phytoplankton DynamicsMarine Biology and Ecology ResearchDiatoms and Algae Research