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Octahedral cation site disorder effects on magnetization in double-perovskite Sr2FeMoO6: Monte Carlo simulation study

Abhijit S. Ogale、S. B. Ogale、R. Ramesh 等 4 位作者1999-07-26Applied Physics Letters

Monte Carlo simulation studies are performed to examine the implications of octahedral cation (Fe, Mo) site disorder for magnetization in the double-perovskite Sr2FeMoO6. Correlations between the near-neighbor cation distributions and the spin distributions are identified to gain insight into the spin arrangement with…

Magnetic and transport properties of perovskites and related materialsMultiferroics and related materialsAdvanced Condensed Matter Physics

Coexistence of ferroelectricity and ferromagnetism in BiFeO3–BaTiO3 thin films at room temperature

K. Ueda、Hitoshi Tabata、Tomoji Kawai1999-07-26Applied Physics Letters

( Bi 0.7 Ba 0.3 ) ( Fe 0.7 Ti 0.3 )O 3 films have been constructed on Nb-doped SrTiO3 (100) by the pulsed-laser deposition technique, and their physical properties have been examined. The films exhibit both ferroelectricity and ferromagnetism (weak ferromagnetism) with Pr=2.5 μC/cm2 and Mr=0.2 emu/g at room temperatur…

Ferroelectric and Piezoelectric MaterialsMultiferroics and related materialsDielectric properties of ceramics

Single Particle and Collective Excitations in the One-Dimensional Charge Density Wave SolidK0.3MoO3Probed in Real Time by Femtosecond Spectroscopy

J. Demšar、K. Biljaković、D. Mihailović1999-07-26Physical Review Letters

Ultrafast transient reflectivity changes caused by collective and single particle excitations in the quasi-one-dimensional charge-density wave (CDW) semiconductor ${\mathrm{K}}_{0.3}{\mathrm{MoO}}_{3}$ are investigated with optical pump-probe spectroscopy. The temperature dependence of nonequilibrium single particle e…

Perovskite Materials and ApplicationsOrganic and Molecular Conductors ResearchSolid-state spectroscopy and crystallography

Synthesis and characterization of phenolic resole resins for composite applications

J. E. Shafizadeh、S. Guionnet、Matthew S. Tillman 等 4 位作者1999-07-25Journal of Applied Polymer Science

In this study, phenol–formaldehyde resins catalyzed with sodium hydroxide, triethylamine, and ammonium hydroxide were investigated and characterized in terms of their degradation behavior, flammability, mechanical properties, and chemical structure. All three resins displayed similar degradative mechanisms, and their…

Epoxy Resin Curing ProcessesSilicone and Siloxane ChemistryEngineering and Material Science Research

Gas permeability and permselectivity of photochemically crosslinked copolyimides

Ye Liu、Cai‐Yuan Pan、Mengxiang Ding 等 4 位作者1999-07-25Journal of Applied Polymer Science

A series of copolyimides were prepared from 2,4,6-trimethyl-1,3-phenylenediamines (3MPDA), 3,3′,4,4′-benzophenone tetracarboxyl dianhydride (BTDA), and pyromellitic dianhydride (PMDA). Modification of the copolyimides by ultraviolet irradiation were carried out. Gas permeabilities of H2, O2, and N2 through the copolyi…

Membrane Separation and Gas TransportSynthesis and properties of polymersSilicone and Siloxane Chemistry

Flow-induced morphological instability of a mushy layer

D. L. Feltham、M. Grae Worster1999-07-25Journal of Fluid Mechanics

A morphological instability of a mushy layer due to a forced flow in the melt is analysed. The instability is caused by flow induced in the mushy layer by Bernoulli suction at the crests of a sinusoidally perturbed mush–melt interface. The flow in the mushy layer advects heat away from crests which promotes solidifica…

Solidification and crystal growth phenomenananoparticles nucleation surface interactionsFreezing and Crystallization Processes

Water transport properties in poly(3-hydroxybutyrate) and poly(3-hydroxybutyrate-co-3-hydroxyvalerate) biopolymers

Óscar Miguel、J. J. Iruin1999-07-25Journal of Applied Polymer Science

Water sorption and diffusion have been investigated in poly(3-hydroxybutyrate) (PHB) and three poly(3-hydroxybutyrate-co-3-hydroxyvalerate) copolymers [P(HB-HV)] by means of a Cahn electromicrobalance. Permeability of these samples have been determined using a gravimetric permeation cell. Two experimental setups were…

Polymer crystallization and propertiesbiodegradable polymer synthesis and propertiesRecycling and Waste Management Techniques

Effect of filler treatment on temperature dependence of resistivity of carbon-black-filled polymer blends

Gang Yu、Ming Qiu Zhang、Han Min Zeng 等 5 位作者1999-07-25Journal of Applied Polymer Science

Polyblends prove to be able to provide more possibilities for tailoring conductive polymer composites in comparison with individual polymer systems. Accordingly, ethylene–vinyl acetate—low-density polyethylene (EVA–LDPE) filled with carbon black (CB) was prepared in this study as a candidate for positive temperature c…

Carbon Nanotubes in CompositesPolymer crystallization and propertiesPolymer Nanocomposites and Properties

Comparison of dynamic shear properties of styrene-butadiene vulcanizates filled with carbon black or polymeric fillers

Springer Vieweg、R. Unger、Gert Heinrich 等 4 位作者1999-07-25Journal of Applied Polymer Science

The dynamic shear behavior of SBR 1500 vulcanizates filled with polymeric fillers of 24.6, 40.2, and 74.7 nm diameter and various filler loading up to 100 phr (parts per 100 parts of rubber), and its dependence of strain amplitude up to 14%, have been investigated. The results are compared with carbon-black-filled vul…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesTribology and Wear Analysis

On the stability of liquid ridges

R. V. Roy、Leonard W. Schwartz1999-07-25Journal of Fluid Mechanics

We consider the stability of a rectilinear liquid region whose boundary is composed of a solid cylindrical substrate of arbitrary shape and a free surface whose cross-section, in the absence of gravity, is a circular arc. The liquid–solid contact angle is a prescribed material property. A variational technique, using…

Surface Modification and SuperhydrophobicityAdhesion, Friction, and Surface InteractionsFluid Dynamics and Thin Films

Cusping, capture, and breakup of interacting drops by a curvatureless boundary-integral algorithm

Alexander Z. Zinchenko、Michael Rother、Robert H. Davis1999-07-25Journal of Fluid Mechanics

A three-dimensional boundary-integral algorithm for interacting deformable drops in Stokes flow is developed. The algorithm is applicable to very large deformations and extreme cases, including cusped interfaces and drops closely approaching breakup. A new, curvatureless boundary-integral formulation is used, containi…

Fluid Dynamics and Heat TransferMicro and Nano RoboticsPickering emulsions and particle stabilization

Biocomposites based on sea algae fibers and biodegradable thermoplastic matrices

Salvatore Iannace、G. Nocilla、L. Nicolais1999-07-25Journal of Applied Polymer Science

Composites were prepared by mixing thermoplastic biodegradable polymers with sea algae fibers. Tensile mechanical properties were analyzed as a function of fiber concentration. The effect of processing, such as compression molding and calendering, on the mechanical properties of the materials was investigated. Composi…

Natural Fiber Reinforced Compositesbiodegradable polymer synthesis and propertiesFiber-reinforced polymer composites

Quantitative in Situ Measurement of Ion Transport in Polypyrrole/Poly(styrenesulfonate) Films Using Rotating Ring−Disk Voltammetry

Corey A. Salzer、C. Michael Elliott、Susan M. Hendrickson1999-07-24Analytical Chemistry

An approach based on rotating ring-disk electrode (RRDE) voltammetry is described for the quantitative, in situ measurement of ion transport between solution and conducting polymer films. The specific composite film studied in this report is polypyrrole/poly(styrenesulfonate) (pPy(+)/pSS(-)). Cation flux in and out of…

Fuel Cells and Related MaterialsConducting polymers and applicationsAnalytical Chemistry and Sensors

The First Anionic Ring-Opening Polymerization of Cyclic Monothiocarbonate via Selective Ring-Opening with C−S Bond Cleavage

Fumio Sanda、Jun Kamatani、Takeshi Endo1999-07-24Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVCommunication to the...Communication to the EditorNEXTThe First Anionic Ring-Opening Polymerization of Cyclic Monothiocarbonate via Selective Ring-Opening with C−S Bond CleavageFumio Sanda, Jun Kamatani, and Takeshi EndoView Author Information Research Laboratory of Resources Utilizati…

Advanced Polymer Synthesis and Characterizationbiodegradable polymer synthesis and propertiesSynthesis and properties of polymers

Ex Situ X-ray Photoelectron Spectroscopy Study of the Interface between a Ag(111) Electrode and an Alkaline Electrolyte. 2. Structure of the Double Layer

Elena R. Savinova、Dmitry Zemlyanov、A. Scheybal 等 5 位作者1999-07-24Langmuir

A Ag(111) single-crystal electrode emersed from an alkaline NaF + NaOH electrolyte under various potentials has been studied ex situ by means of X-ray photoelectron spectroscopy. Superequivalent specific adsorption of negatively charged hydroxide and oxide species has been observed at the potentials positive to the po…

Iron oxide chemistry and applicationsElectron and X-Ray Spectroscopy TechniquesSurface and Thin Film Phenomena

Robust Triplet Molecule: Cationic Diradical of 3,4‘-Bis(diphenylamino)stilbene

Tsuyoshi Michinobu、Masahiro Takahashi、Eishun Tsuchida 等 4 位作者1999-07-24Chemistry of Materials

ADVERTISEMENT RETURN TO ISSUEPREVCommunicationNEXTRobust Triplet Molecule: Cationic Diradical of 3,4'-Bis(diphenylamino)stilbeneTsuyoshi Michinobu, Masahiro Takahashi, Eishun Tsuchida, and Hiroyuki NishideView Author Information Department of Polymer Chemistry, Waseda University, Tokyo 169-8555, Japan Cite this: Chem.…

Organic Light-Emitting Diodes ResearchLanthanide and Transition Metal ComplexesChemical Reactions and Mechanisms

Highly Ordered Nanotopographies on Electropolished Aluminum Single Crystals

Valery V. Konovalov、Giovanni Zangari、Robert M. Metzger1999-07-24Chemistry of Materials

Electropolishing of single-crystal aluminum faces yield different patterns from (111), (110), and (100) faces at different potentials. The stripes that dominate the (110) face extend throughout a 1 cm2 sample in the same direction.

Semiconductor materials and devicesSemiconductor materials and interfacesAnodic Oxide Films and Nanostructures

Förster Energy Transfer Studies of Polyelectrolyte Heterostructures Containing Conjugated Polymers: A Means To Estimate Layer Interpenetration

Jeffery W. Baur、Michael F. Rubner、John R. Reynolds 等 4 位作者1999-07-24Langmuir

Using a sequential adsorption process, thin film multilayer assemblies of polymers which photophysically interact via the Förster energy transfer mechanism have been fabricated and characterized in order to determine the level of interpenetration between layers. The assemblies consisted of layers of poly(phenylene vin…

Surface Modification and SuperhydrophobicityPolymer Surface Interaction StudiesMolecular Junctions and Nanostructures

Non-linear electrical conduction and broadband noise in charge-ordered rare earth manganate Nd_0.5Ca_0.5MnO_3

Ayan Guha、Arindam Ghosh、A. K. Raychaudhuri 等 6 位作者1999-07-24arXiv

Measurements of the dc transport properties and the low-frequency conductivity noise in films of charge ordered Nd_0.5Ca_0.5MnO_3 grown on Si subtrate reveal the existence of a threshold field in the charge ordered regime beyond which strong non linear conduction sets in along with a large broad band conductivity nois…

Materials ScienceStrongly Correlated Electrons

Plane-Stress Deformation in Strain Gradient Plasticity

Jikai Chen、Y. Huang、Kyu-Mok Hwang 等 4 位作者1999-07-23Journal of Applied Mechanics

A systematic approach is proposed to derive the governing equations and boundary conditions for strain gradient plasticity in plane-stress deformation. The displacements, strains, stresses, strain gradients and higher-order stresses in three-dimensional strain gradient plasticity are expanded into a power series of th…

Metal and Thin Film MechanicsBoron and Carbon Nanomaterials ResearchNonlocal and gradient elasticity in micro/nano structures