Materials Literature
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In this study, titanium nitride-vanadium nitride fibers of core-shell structures were prepared by the coaxial electrospinning, and subsequently annealed in the ammonia for supercapacitor applications. These core-shell (TiN-VN) fibers incorporated mesoporous structure into high electronic conducting transition nitride…
Functionalized trialkoxysilanes are widely used to modify the surface properties of materials and devices. It will be shown that the photoinitiated radical-based thiol-ene "click" reaction provides a simple and efficient route to diverse trialkoxysilanes. A total of 15 trialkoxysilanes were synthesized by reacting eit…
Much like the world described in Abbott's "Flatland", graphene is a two-dimensional object. And, as "Flatland" is "A Romance of Many Dimensions", graphene is much more than just a flat crystal. It possesses a number of unusual properties which are often unique or superior to those in other materials. In this brief lec…
Macromolecular crowding in biological media is an essential factor for cellular function. The interplay of intermolecular interactions at multiple time and length scales governs a fine-tuned system of reaction and transport processes, including particularly protein diffusion as a limiting or driving factor. Using quas…
A modified Stöber method is introduced to synthesize Fe@SiO 2 nanoparticles (NPs) using 3-aminopropyltriethoxysilane (APTES) as a primer to render the metal particle surface compatible with silica. High-resolution transmission electron microscopy (HRTEM) and selected area electron diffraction (SAED) results indicate a…
Although carbodiimides and succinimides are broadly employed for the formation of amide bonds (i.e., in amino acid coupling), their use in the coupling of peptides to water-soluble carboxylic-terminated colloidal gold nanoparticles remains challenging. In this article, we present an optimization study for the successf…
Polymer hydrogels with characteristics distinct from those of solid materials are one of the most promising candidates for smart materials. Here, we report that a nanocomposite hydrogel (NC gel) consisting of a unique polymer/clay network structure, can exhibit complete self-healing through autonomic reconstruction of…
This critical review aims to update the recent development in the selective oxidation of organic compounds by gold catalysis, highlighting the progress in the last three years. Following the impressive developments in the last decades, several protocols for catalytic oxidation are today available, which are based on t…
Our society requires new materials for a sustainable future, and carbon nanotubes (CNTs) are among the most important advanced materials. This Review describes the state-of-the-art of CNT synthesis, with a focus on their mass-production in industry. At the nanoscale, the production of CNTs involves the self-assembly o…
Tremendous progress has been achieved during the past 20 years on not only improving the yields of carbon nanotubes and move progressively towards their mass production, but also on gaining a profound fundamental understanding of the nucleation and the growth processes. Parameters that influence the yield but also the…
Ultralayered Co 3 O 4 structures with high porosity have been synthesized by a facile homogeneous precipitation process under hydrothermal conditions. The superstructures consist of well-arranged micrometer length rectangular 2D flakes with high specific surface area, pore volume, and uniform pore size distribution. T…
The thermal expansion coefficient (TEC) of single-layer graphene is estimated with temperature-dependent Raman spectroscopy in the temperature range between 200 and 400 K. It is found to be strongly dependent on temperature but remains negative in the whole temperature range with a room temperature value of (-8.0 ± 0.…
Monodisperse citrate-stabilized gold nanoparticles with a uniform quasi-spherical shape of up to ∼200 nm and a narrow size distribution were synthesized following a kinetically controlled seeded growth strategy via the reduction of HAuCl(4) by sodium citrate. The inhibition of any secondary nucleation during homogeneo…
A moiré pattern is formed when two copies of a periodic pattern are overlaid with a relative twist. We address the electronic structure of a twisted two-layer graphene system, showing that in its continuum Dirac model the moiré pattern periodicity leads to moiré Bloch bands. The two layers become more strongly coupled…
In this paper, the effect of Er element on ignition-proof property of Mg-Zn alloys was studied. XRD, SEM and EDS were used to investigate the ignition-proof performance and the oxidation film of the alloys. The element of Er tended to enrich in the surface of molten magnesium alloys during the oxidation process. And t…
Carbon Nanotubes (CNTs) are functionalized with ethylenediamine by chemical cut and grafting process. CNTs/nylon-6 (PA6) composite is prepared by solution-evaporation method. The dispersivity of CNTs and mechanical properties of CNTs/PA6 composites are tested. Reinforced mechanism is also investigated. The results sho…
A double-sheets model was proposed to investigate the interlayer structure and properties of hydrotalcite (HT) containing CO 3 2- , CrO 4 2- , SO 4 2- and NO 3 - using density functional theory, and the configuration and distribution of four anions in the interlayer of HT were obtained. The frontier orbital of the hos…
Using corundum particles and fine powder, α-Al 2 O3 powder, silicon powder, aluminum powder and some additives as raw materials, β-Sialon bonded corundum composite was synthesized in-situ at the nitrogen atmosphere. The influence of Z value in sialon phase and sintering temperature on physical properties, mechanical p…
The title compound Fe 2 Mo 3 O 12 is prepared using a wet chemical method from aqueous solutions of ferrous nitrate and ammonium molybdate. The various process parameters were optimized to get a suitable precursor, which upon calcination at 700°C for 2 h gave a well crystalline product. The product was characterized b…
The effect of Yb 2 O 3 addition on sintering of MgO ceramics was studied in this work. Increasing of Yb 2 O 3 addition is helpful to densification and grain growth. The effect of Yb 2 O 3 amount on densification decreased when the sintering temperature was increased from 1400°C to 1550°C. Quick densification and rapid…