Materials Literature
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In the case of the strongly deformed graphene, gapless graphene may turn to gapped graphene at the critical deformation. We find that, like semi-massless fermions, electrons in the deformed graphene, at the critical point, mimic the dispersions of the massless fermions in one direction and the massive fermions in the…
Chemisorbed molecules at a fuel cell electrode are a very sensitive probe of the surrounding electrochemical environment, and one that can be accurately monitored with different spectroscopic techniques. We develop a comprehensive electrochemical model to study molecular chemisorption at either constant charge or fixe…
A nonlocal finite element model is developed for solving elasto-static frictional contact problems of nanostructures and nanoscale devices. A two dimensional Eringen-type nonlocal elasticity model is adopted. The material is characterized by a stress-strain constitutive relation of a convolution integral form whose ke…
A new green home designed to save money while at the same time saving the environment with some of the finest green features available in the market. Composite column composed of structural steel and structural glued laminated timber is avery Eco-friendly building products for design building because that use recycled…
The cocoon of the commercial silkworm Bombyx mori is used as a model natural nonwoven composite to formulate a model for structural properties of nonwoven composites. The model is based upon open cell foam structures for the intrinsic undamaged elastic properties using the component materials in the cocoon, combined w…
We have studied the formation and the stability of ionomer complexes from grafted copolymers (GICs) in solution and the influence of GIC coatings on the adsorption of the proteins β-lactoglobulin (β-lac), bovine serum albumin (BSA), and lysozyme (Lsz) on silica and polysulfone. The GICs consist of the grafted copolyme…
In thermal “passive” microrheology, the random Brownian motion of anisotropically shaped probe particles embedded within an isotropic viscoelastic material can be used to extract the material’s frequency-dependent linear viscoelastic modulus. We unite the existing theoretical frameworks for separately treating transla…
Abstract N-(2-Anthryl)-2-[bis(pentafluorophenyl)boryl]benzylideneamine changed its fluorescence color from yellow to green upon addition of an equimolar amount of cyanide ion, in contrast to the N-phenyl derivatives, which showed quenching of the emission. Theoretical calculations suggested that switching of the imine…
The UV-induced cross-linked network structures of methacryl-oligosiloxane nanoclusters (MONCs) were analyzed with a hydrofluoric acid dissolution derived gel permeation chromatography technique (HF-GPC) to study their network structure–property relationships. With this method the oligosiloxane cores were dissolved in…
An efficient method based in template wetting is applied for fabrication of ordered Poly(9,9-dioctylfluorene) (PFO) nanopillars with β-phase morphology. In this process, nanoporous alumina obtained by anodization process is used as template. PFO nanostructures are prepared under ambient conditions via infiltration of…
The effect of eliminating D-lactate synthesis in poly(3-hydroxybutyrate) (PHB)-accumulating recombinant Escherichia coli (K24K) was analyzed using glycerol as a substrate. K24KL, an ldhA derivative, produced more biomass and had altered carbon partitioning among the metabolic products, probably due to the increased av…
The effect of sweet ovine whey powder on physical–chemical and textural changes during storage of Amaretti cookies is reported. The aim of the study was to study the impact of the ovine whey powder on the shelf life of cookies. Two batches of Amaretti cookies were prepared, with and without whey powder. Freshly baked…
Cylinder- and bamboo-shaped boron nitride nanotubes (BNNTs) have been synthesized in large scale via a facile chemical vapor reaction route using ammonia borane as a precursor. The structure and chemical composition of the as-synthesized BNNTs are extensively characterized by X-ray diffraction, scanning electron micro…
The combination of two techniques of controlled free radical polymerization, namely the reversible addition fragmentation chain transfer (RAFT) and the atom transfer radical polymerization (ATRP) techniques, together with the use of a macromonomer allowed the synthesis of symmetrical triblock copolymers, designed as a…
Micron scale ferromagnetic tubes placed on the ends of ferromagnetic CoTaZr spin waveguides are explored in order to enhance the excitation of Backward Volume Magnetostatic Spin Waves. The tubes produce a closed magnetic circuit about the signal line of the coplanar waveguide and are, at the same time, magnetically co…
Aliphatic polycarbonates are often referenced for their interesting applications due to their lower tendency to undergo hydrolysis, lower Tg, and their degradation in renewable resources. Their synthesis is described using a series of metal-free catalysts allowing preparation of well-defined polymers in terms of molec…
Conducting and semiconducting (conjugated) polymers have a unique set of properties, combining the electronic properties of metals and semiconductors with the processing advantages and mechanical properties of polymers. Now, thirty-five years after their discovery, metallic conducting polymers have been demonstrated i…
Abstract Presence of planar, bulky heterocyclic pendant groups, attached to polymer chains, alters the thermal properties and, once gelled, they modify their rheological properties as well. The authors report generation of stiff gels coming from terpolymers containing 1,2,4‐oxadiazolic pendant groups, obtained by chem…
A new type of inorganic nanoparticle-organic hybrid crystalline material consisting of gold nanoparticles (Au NPs) and p-hydroxyacetanilide (pHA) is reported. The composite crystals were on the order of several millimeters in dimensions. They could be grown from a solution of Au NPs and pHA at 35 °C. The optical prope…
The rheology of cement pastes can be controlled by polymeric dispersants such as branched polyelectrolytes that adsorb on the surfaces of silicate particles. In the present work, we analyze the adsorption behavior of ad hoc-prepared end-carboxylated poly(ethylene glycol), or PEG, on CaCO(3) particles as a model of cem…