Materials Literature
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In this work we report on the formation of pure polyaniline fibres by the electrospinning method. The fibres present diameters ranging from hundreds of nanometres to a few micrometres and have lengths of hundreds of micrometres. The fibres were collected on SiO 2 /Si and Si wafer pieces in the form of isolated fibres.…
Abstract A series of poly(amic acid)s have been synthesized from cyclobutane‐1,2,3,4‐tetracarboxylic dianhydride (CBDA), a functional diamine, 1‐(3,5‐diaminophenyl)‐3‐(1‐octadecyl)‐succinicimide and 4,4‐diaminodiphenylmethane (DDM) to give liquid crystal alignment layers with high pretilt angle after a rubbing process…
Although a number of chalcogenostannates have been obtained by using [M(amine)m]n+ as the structure director, these materials with chiral metal complex ions are usually achiral because they are a racemic mix of chiral complex cations. A chiral selenidostannate, [Mn(tepa).Sn3Se7]n (1; tepa = tetraethylenepentamine), co…
Carbon encapsulated magnetic (metal) nanoparticles (CEMNPs) have wide applications in biomedicine and the magnetic recording industry. However, synthesis of such particles with a high coercive force and good ferromagnetism is still a great challenge. The present study reports a new method for the continuous production…
The design of nano- and microstructures based on self-organization is a key area of research in the search for new materials, and it has a variety of potential applications in tissue engineering scaffolds. We have reported a honeycomb-patterned polymer film (honeycomb film) with highly regular pores that is formed by…
Hexagonal Eu(3+):ZnO nanocrystals were synthesized by a modified solgel method. By means of the site-selective spectroscopy at 10 K, two kinds of luminescence sites of Eu(3+) are identified. One site exhibits a long lifetime of (5)D(0) and sharp emission and excitation peaks, which are ascribed to the inner lattice si…
Dielectric transmission gratings with a similar period as the wavelength of the incident light can exhibit strong polarization dependence. By optimizing the groove width of a negative first-order Littrow transmission grating it can be achieved that light is transmitted to the zeroth order for one polarization, regardl…
This paper presents the effects of chemical and thermal treatments on the strength of vegetable fibers that were being considered as reinforcements in cementitious matrix composites for affordable housing. These include vegetable fibers extracted from banana trunks and sugar cane residues. The results suggested that p…
A simple method was developed for preparation of core colloids modified with Au (Ag) nanoparticles (NPs). The core colloids vary from polymer colloids (polystyrene spheres) to dielectric inorganic spheres (SiO 2 ) and semiconductors (ZnO) particles. The composite colloids were obtained by heating the solution of the c…
Recently, metal−molecule−metal junctions have been actively researched due to their potential applications in molecular electronics, and probing the structure of the molecules in the junctions is crucial for understanding electron-transfer properties. In this paper, self-assembled monolayers (SAMs) of p -aminothiophen…
With increasing interest in nanotechnology, development of nanofibers (n-fibers) by using the technique of electrospinning is gaining new momentum. Among important potential applications of n-fiber-based structures, scaffolds for tissue-engineering represent an advancing front. Nanoscaffolds (n-scaffolds) are closer t…
We report on the oxidative stability of thiol-passivated Au monolayer-protected clusters (MPCs) made via a modified Brust-Schiffrin method. A sequential oxidation of the anchored thiol groups to disulfide and sulfonate groups and the oxidation of Au atoms to Au3+ species is observed upon exposure of Au MPCs to air in…
The influence of annealing temperature on the hydrophilic property of WO 3 thin films deposited by thermal evaporation and sol–gel dip-coating methods was studied and compared for the first time. The thermal evaporated WO 3 thin films annealed at 400 °C showed a nearly super-hydrophilic property without UV and visible…
Novel electrochromic copolymers from o -phenylenediamine ( o PD) with aniline (ANi) were facilely synthesized by a chemical oxidative polymerization. The synthesis, structure, and properties of the copolymers were systematically studied by changing o PD content and polymerization temperature. The dependence of the pol…
This work evaluates the influence of three different intensities of refinement of sisal pulp and the effect of accelerated aging cycles on the behavior of composites. Fiber-cements were prepared by the slurry de-watering method and pressing as a crude simulation of the Hatschek process. Mechanical behavior of composit…
The x-ray structure factor for liquid SiO2 has been measured by laser heating of an aerodynamically levitated droplet. The main structural changes of the melt compared to the room temperature glass are associated with an increase in the size of the SiO4 tetrahedra, indicating a small reduction in the average Si-O-Si b…
In this work, we investigate the configuration of the contact line of a water drop lying on an ultrahydrophobic post surface using the numerical algorithm Surface Evolver. For the special situation of Cassie wetting, we propose a modified definition of the contact line as the line in space where the meniscus starts to…
[structure: see text] Versatile dyes based on diisoindolodithienylpyrromethene substituted at the boron center by alkynylaryl chromophores have been developed that efficiently fluorescence in the near infrared. Fast intramolecular energy transfer from the appended alkynyl units to the central core provides Stokes shif…
Abstract Wood fiber reinforced polymer composites represent a relatively small but rapidly growing material class, extensively applied in interior building applications and in the automotive industry. The polymer‐wood fiber composites utilize fibers as reinforcing filler in the polymer matrix and are known to be advan…
A three-terminal spectroscopy that probes both subsurface energy barriers and interband optical transitions in a semiconductor heterostructure is demonstrated. A metal-base transistor with a unipolar p-type semiconductor collector embedding InAs/GaAs quantum dots (QDs) is studied. Using minority/majority carrier injec…