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A mathematically closed form expression for the electric field between arbitrarily shaped surfaces is derived utilizing the techniques of differential geometry. This solution is then applied to the problem of Fowler-Nordheim emission from non-planar surfaces. Knowledge of the field everywhere on the emitting surface a…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTDynamic Jahn-Teller effect in a manganese(III) complex. Synthesis and structure of hexakis(urea)manganese(III) perchlorateHossein Aghabozorg, Gus J. Palenik, R. Carl Stoufer, and J. SummersCite this: Inorg. Chem. 1982, 21, 11, 3903–3907Publication Date (Print):November 1, 19…
Thin metallic films have reduced conductivity when thickness is not larger than electron mean free path, a phenomenon studied by Lord Thompson. Formulas given by Liao are valid for small thickness; a general formula is available for all ranges of film thickness. The result is in terms of an exponential integral which…
Abstract The effect of tetrasodium pyrophosphate decahydrate (Na4P2O7·10H2O) as a nucleation catalyst for sodium acetate trihydrate (CH3CO2Na·3H2O) is shown. The supercooled melt of 10 g of CH3CO2Na·3H2O recrystallized at about 5 degrees below the melting point only when 0.1 g of Na4P2O7·10H2O was added to it. More th…
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Age-related differences of human skin collagen in solubility, susceptibility to pepsin digestion, and the spectrum of collagen molecules were systematically examined. Less than .5% of the skin collagen were solubilized in a neutral salt solution. The solubility in acetic acid decreased rapidly during maturation and th…
A new modification of the diamond anvil pressure cell was made for high-temperature and high-pressure use. After this modification, a high temperature of up to 700°C could be obtained at a pressure of up to 7 GPa. Various sensor materials for pressure measurement at high temperatures were also investigated. It was fou…
The magnetic characteristis of cores with step-lap joints are analyzed by using the finite element method taking into account eddy current and magnetic saturation. The effects of the following factors on the magnetic characteristics such as flux and eddy current distributions and magnetizing current are clarified quan…
Abstract The sorption of swelling penetrants in glassy polymers is modeled as a diffusion problem with moving boundary. The velocity of the swelling front is related to the stress exerted by the penetrant on the glassy matrix at the moving boundary. The solvent stress is considered as the sum of the osmotic tension an…
Soliton propagation in nematic liquid crystals under shear is shown to be possible and studied theoretically. Calculations including those pertaining to the modulation of monochromatic or white light passing through such a liquid-crystal cell are presented. Recent experiments are interpreted accordingly and are in goo…
The magnetic properties of the following intermetallic compounds were determined: HFCo2, HfCo3, Hf6Co23, HfCo7, TaCo2, TaCo3, NbCo2, and NbCo3. Several amorphous alloys of the type Y1−xCox (in the concentration range x=0.30 to x=0.55) were prepared by melt spinning. Their magnetic properties have been compared with th…
In order to improve the stability of w/o/w multiple emulsions which have isopropyl myristate as the non-aqueous 'oil' phase, either the internal aqueous phase of the multiple system or the secondary (outer or continuous) aqueous phase can be gelled. Production, by gamma-irradiation, or cross-linked polyacrylamide or p…
Abstract Olefinic thermoplastic vulcanizates (OTV's) comprise rubber in the form of discrete, completely crosslinked particles uniformly dispersed in an olefinic thermoplastic matrix. By their nature, they flow like filled polymer melts: die swell is low, and shows evidence of a particle association at low shear rate…
The effects of radiation on the rare‐earth silicate, Ca 2 Nd 8 (SiO 4 ) 6 O 2 , with the apatite structure was investigated using 244 Cm doping and alpha, gamma, and electron irradiations. Amorphization of the initially crystalline material was observed to occur only in the Cm‐doped material. Alpha irradiation produce…
The magnetization density per cm3 of Ni-content of compositionally modulated Cu–Ni thin films at 5 K was found to depend on the modulation wavelength (λ) and amplitude (A) and reached ∼90% of that of pure Ni. Short-λ and low-T studies on Cu–Ni showed an inter-wavelength coupling of the moments of Ni-rich regions that…
Abstract The reaction of poly(vinyl chloride) powder with aqueous sodium hydroxide solution in the presence of quaternary ammonium or phosphonium halides yielded dehydrochlorinated products of conjugated polyene structure. The reaction was discussed in terms of a phase transfer catalytic mechanism between aqueous and…
A model for the effect of demagnetizing field caused by closed pores and grain boundaries in ferrites was developed. This paper presents the expressions to transform the magnetic properties free from the demagnetizing field into the apparent magnetic properties. The expression for the apparent permeability is\mu_{app}…
Branching ratios have been obtained for 33 lines originating from nine levels in Ar ii by Fourier spectroscopic measurements on a high-current hollow cathode. The values are compared with recent literature data.
Abstract The dc component Δ n of the electric birefringence of poly(γ‐benzyl‐ L ‐glutamate) in m ‐cresol is measured under an ac electric field at frequencies from 0.5 Hz to 200 kHz for solutions covering the dilute and semidilute regions. The dispersion curve indicates that at low frequencies Δ n decreases with incre…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTElectrochemical synthesis and characterization of the single-electron oxidation products of ferric porphyrinsMartin A. Phillippi and Harold M. GoffCite this: J. Am. Chem. Soc. 1982, 104, 22, 6026–6034Publication Date (Print):November 1, 1982Publication History Published onli…