Materials Literature
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The capacitance of PbZrO 3 –Pb(Zr 0.8 Ti 0.2 )O 3 epitaxial multilayers is significantly enhanced as the number of interfaces increases at the same total thickness of the structure. A possible explanation for this enhancement can be the increase of the dielectric susceptibility due to the presence of some interfacial…
We report on the controlled manipulation of two, three and four gold nanoparticles (AuNPs) using an atomic force microscope (AFM) for use as surface-enhanced Raman scattering substrates. For each arrangement, the interparticle electromagnetic (EM) coupling between adjacent AuNPs is studied at different polarization an…
Multiwalled carbon nanotubes (MWNTs) were manipulated inside a high-resolution transmission electron microscope combined with a nano manipulator, and a single MWNT emitter freestanding on a platinum surface was fabricated by nanowelding. The electron field emission properties of the single MWNT were in situ measured a…
Lattice parameter profiles and the chemical structure of InP self-assembled islands grown on GaAs(001) were determined with x-ray resonant scattering. By accessing four different photon energies, near x-ray absorption edges of two of the atomic species present on the samples, composition maps of all four atomic consti…
Abstract New polymeric ligand (resin) was prepared by the condensation of thiosemicarbazides with formaldehyde in the presence of acidic medium. Thisemicarbazide–formaldehyde polymer–metal complexes were prepared with Mn(II), Co(II), Ni(II), Cu(II) and Zn(II) in 1:2 metal:ligand molar ratio. The polymeric ligand and i…
Ethylene vinyl acetate (EVA)/natural rubber (SMR L)/organoclay thermoplastic elastomer nanocomposites were melt compounded in an internal mixer, Haake Rheometer, at 120°C at a rotor speed of 50 rpm. The thermoplastic elastomer nanocomposites were dynamically vulcanized using sulfur and peroxide systems. In this articl…
Abstract A series of ZnMgO thin‐film nanophosphors with varied Zn:Mg ratio has been prepared by chemical bath deposition. The structure, photoluminescence, time‐resolved decay and chromaticity of the films are presented. ZnMgO films absorb light efficiently in the near UV (330–400 nm) and the emission covers a large p…
A violet luminescence band at 3.1099eV was observed at 12.5K in phosphorus-doped ZnO epitaxial films deposited by O2 plasma-assisted pulsed laser ablation. The band results from a transition between a shallow donor and a deep acceptor induced by phosphorus doping. The activation energy of the acceptor varies with the…
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We report the fabrication of patterned nanocrystalline diamond (NCD) submicrometer-tip arrays. This includes synthesis of silica (a-SiO2) templates by conventional vapor-liquid-solid method and conformal coating of the a-SiO2 nanowires with 5–10nm sized nanodiamond grains by microwave plasma chemical vapor deposition.…
In this research, poly(vinyl chloride) (PVC)/ethylene vinyl acetate copolymer (EVA)/ organomodified montmorillonite (OMMT) nanocomposites have been prepared and characterized for their structure, properties, and morphology. The blend nanocomposites were prepared through the melt mixing of PVC/EVA at weight ratios of 1…
Collagen forms the well characterized triple helical secondary structure, stabilized by interchain H-bonds. Here we have investigated the stability of fully optimized collagen triple helices and beta-pleated sheets by using first principles (ab initio and DFT) calculations so as to determine the secondary structure pr…
Strong suppression of the effects caused by the internal electric field in ZnO/ZnMgO quantum wells following ion-implantation and rapid thermal annealing, is revealed by photoluminescence, time-resolved photoluminescence, and band structure calculations. The implantation and annealing induces Zn/Mg intermixing, result…
Epitaxial magnetoelectric Pb(Zr0.52Ti0.48)O3∕SrRuO3∕CoFe2O4 composite thin films are fabricated on SrTiO3 single crystal substrate by pulsed-laser deposition. x-ray diffraction study reveals their crystalline structure and epitaxial relationship, which is cubic on cubic without in-plane rotation. The good dielectric,…
Coordinate transformation approach has previously been used for designing a cloak which can shield an interior region in a homogeneous medium. In this paper, we consider the case where the background is no longer a homogeneous medium and determine the relative constitutive parameters of the cloak according to the mult…
A large inverse magnetocaloric effect has been reported to be associated with the austenite to martensite phase transition in Ni50Mn34In16. It is shown here that the magnitude of the observed magnetocaloric effect as well as effective refrigerant capacity depend significantly on the thermo-magnetic history of the samp…
We report the achievement of very thin films (thickness of about 50nm) of thermotropic columnar liquid crystal in homeotropic (columns normal to the interface) orientation on indium tin oxide (ITO) electrodes. The face-on alignment of the discotic compound has been obtained by thermal annealing without any intermediat…
The effect of physisorption of NO2 gas molecules on quantum transport properties of semiconducting carbon nanotubes is studied using ab initio calculations and Green function formalism. The results show that the conductance change is mainly due to the electric dipole moment of NO2. It is also shown that upon exposure…
Superhydrophobic surfaces were prepared on Ti/Si substrates via the fabrication of a platinum (Pt) nanowire array. The Pt nanowire array was obtained by dc electrodeposition of Pt into the pores of an anodic aluminium oxide (AAO) template on the substrate followed by the removal of the template. Transmission electron…
Polyphosphoesters and polyphosphoramidates are important two classes of phosphorous-containing polymers, which have received more and more attention in the past decade for the application in biomedical field. The unique characteristic of biodegradation, biocompatibility and structure versatility of polyphosphoesters a…