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X-ray photoelectron spectroscopy and high resolution electron microscopy studies of Aurivillius compounds: Bi4−xLaxTi3O12(x=0, 0.5, 0.75, 1.0, 1.5, and 2.0)

Ming‐Wen Chu、M. Ganne、Maria Teresa Caldés 等 4 位作者2002-03-01Journal of Applied Physics

In order to determine the fatigue-free origin of the ferroelectric Bi3.25La0.75Ti3O12, a series of x-ray photoelectron spectroscopy and high resolution electron microscopy studies were performed on the polycrystalline Bi4−xLaxTi3O12 (BLTx, x=0, 0.5, 0.75, 1.0, 1.5, and 2.0) powders. From the XPS study, the surfaces of…

Ferroelectric and Piezoelectric MaterialsMultiferroics and related materialsMicrowave Dielectric Ceramics Synthesis

Smooth and high-rate reactive ion etching of diamond

Yutaka Ando、Yoshiki Nishibayashi、Koji Kobashi 等 5 位作者2002-03-01Diamond and Related Materials

Diamond surfaces with patterned Al masks were etched by a reactive ion etching (RIE) system under conditions that the RF power was 100–280 W, the CF 4 /O 2 ratio was 0–12.5% and the gas pressure 2–40 Pa. It was found that the roughness of the etched diamond surface decreased with an increase in the CF 4 /O 2 ratio, al…

Metal and Thin Film MechanicsSemiconductor materials and devicesDiamond and Carbon-based Materials Research

Cross Sections for Low-Energy (10 – 50 eV) Electron Damage to DNA

Badia Boudaı̈ffa、Pierre Cloutier、D. J. Hunting 等 5 位作者2002-03-01Radiation Research

We report direct measurements of the formation of single-, double- and multiple strand breaks in pure plasmid DNA as a function of exposure to 10-50 eV electrons. The effective cross sections to produce these different types of DNA strand breaks were determined and were found to range from approximately 10(-17) to 3 x…

Atomic and Molecular PhysicsElectron and X-Ray Spectroscopy TechniquesRadiation Effects and Dosimetry

Cellular Uptake Studies with -Peptides

Magnus Rueping、Yogesh R. Mahajan、Markus Sauer 等 4 位作者2002-03-01ChemBioChem

Translocation across the membrane into cells is possible for certain peptides and proteins. To investigate the structural requirements of β-peptides for this process, a series of fluorescein-labeled β-peptides has been synthesized and their cellular uptake into 3T3 mouse fibroblast cells determined by fluorescence mic…

Chemical Synthesis and AnalysisSupramolecular Self-Assembly in MaterialsClick Chemistry and Applications

High-Resolution Simulation of Multidimensional Crystal Growth

Laurent David、Danesh K. Tafti、Richard D. Braatz2002-03-01Industrial & Engineering Chemistry Research

Many of the crystals in the pharmaceuticals, photographic, and other industries are multidimensional; that is, their growth is associated with the change of multiple internal coordinates. The main governing equation for such systems is a highly nonlinear multidimensional population balance equation that must be solved…

Coagulation and Flocculation StudiesCrystallization and Solubility StudiesThermal and Kinetic Analysis

Three-Dimensional Cubic Mesoporous Structures of SBA-12 and Related Materials by Electron Crystallography

Yasuhiro Sakamoto、Isabel Dı́az、Osamu Terasaki 等 7 位作者2002-03-01The Journal of Physical Chemistry B

The chemical potential difference between homopolymer fractions in block copolymers can be readily used to selectively design, and cooperatively assemble, inorganic species into highly ordered three-dimensional (3d) periodic composite arrays of separated mesoscale regions. The actual details and symmetry of these regi…

Metal-Organic Frameworks: Synthesis and ApplicationsMesoporous Materials and CatalysisPolyoxometalates: Synthesis and Applications

Proof of the Double Bubble Conjecture

Michael Hutchings、Frank Morgan、Manuel Ritoré 等 4 位作者2002-03-01Annals of Mathematics

We prove that the standard double bubble provides the least-area way to enclose and separate two regions of prescribed volume in R 3 .

Pickering emulsions and particle stabilization

Submicron x-ray diffraction and its applications to problems in materials and environmental science

Nobumichi Tamura、Richard Celestre、Alastair A. MacDowell 等 9 位作者2002-03-01Review of Scientific Instruments

The availability of high brilliance third generation synchrotron sources together with progress in achromatic focusing optics allows us to add submicron spatial resolution to the conventional century-old x-ray diffraction technique. The new capabilities include the possibility to map in situ, grain orientations, cryst…

X-ray Spectroscopy and Fluorescence AnalysisElectron and X-Ray Spectroscopy TechniquesX-ray Diffraction in Crystallography

Phase equilibria and glass transition in colloidal systems with short-ranged attractive interactions: Application to protein crystallization

Giuseppe Foffi、Gavin D. McCullagh、Aonghus Lawlor 等 9 位作者2002-03-01Physical review. E, Statistical physics, plasmas, fluids, and related interdisciplinary topics

We have studied a model of a complex fluid consisting of particles interacting through a hard-core and short-range attractive potential of both Yukawa and square-well form. Using a hybrid method, including a self-consistent and quite accurate approximation for the liquid integral equation in the case of the Yukawa flu…

Phase Equilibria and ThermodynamicsMaterial Dynamics and PropertiesRheology and Fluid Dynamics Studies

Saddle points and dynamics of Lennard-Jones clusters, solids, and supercooled liquids

Jonathan P. K. Doye、David J. Wales2002-03-01The Journal of Chemical Physics

The properties of higher-index saddle points have been invoked in recent theories of the dynamics of supercooled liquids. Here we examine in detail a mapping of configurations to saddle points using minimization of |∇E|2, which has been used in previous work to support these theories. The examples we consider are a tw…

Phase Equilibria and ThermodynamicsMaterial Dynamics and PropertiesTheoretical and Computational Physics

PLASMON MODES IN METAL NANOWIRES AND LEFT-HANDED MATERIALS

Viktor A. Podolskiy、Andrey K. Sarychev、Vladimir M. Shalaev2002-03-01Journal of Nonlinear Optical Physics & Materials

The electromagnetic field distribution for thin metal nanowires is found, by using the discrete dipole approximation. The plasmon polariton modes in wires are numerically simulated. These modes are found to be dependent on the incident light wavelength and direction of propagation. The existence of localized plasmon m…

Metamaterials and Metasurfaces ApplicationsPlasmonic and Surface Plasmon ResearchPhotonic Crystals and Applications

Towards the understanding of mechanical properties of super- and ultrahard nanocomposites

S. Vepřek、A. S. Argon2002-03-01Journal of Vacuum Science & Technology B Microelectronics and Nanometer Structures Processing Measurement and Phenomena

This article presents an attempt to explain in a simple way, understandable to a broad spectrum of readers, the unusual combination of the mechanical properties of the recently developed new class of superhard nanocomposites, such as high hardness which significantly exceeds that of the rule of mixtures, enhancement o…

Metal and Thin Film MechanicsDiamond and Carbon-based Materials ResearchBoron and Carbon Nanomaterials Research

Tensile properties of polyester/cotton blended yarns

V. K. Kothari、S. M. Ishtiaque、Vinayak Ogale2002-03-01Indian Journal of Fibre & Textile Research

Effect of blend ratio, strain rate and cone winding from ring bobbins on the tensile properties of polyester/cotton blended yarns under static and dynamic conditions has been studied using USTER Tensorapid and Constant Tension Transport testers. It is observed that the static tensile test overestimates tensile strengt…

Textile materials and evaluationsStructural Analysis and Optimization

Crystallization Mechanism and Kinetics of BaO-Li2O-ZrO2-SiO2 Glasses

Cristian Berto da Silveira、Sílvia Denofre de Campos、Elvio A. de Campos 等 4 位作者2002-03-01Materials Research

Differential thermal analysis and scanning electron microscopy were used to determine the influence of the addition of BaO on the crystallization mechanism of Li2O-ZrO2-SiO2 systems. As the concentration of BaO in the samples increased, a transition occurred in the predominant crystallization mechanism, which passed f…

Correlation between Corrosion Potential and Pitting Potential for AISI 304L Austenitic Stainless Steel in 3.5% NaCl Aqueous Solution

Neusa Alonso-Falleiros、Stephan Wolynec2002-03-01Materials Research

We investigated the effect of surface finish of two AISI 304L (UNS S30403) stainless steels on the corrosion potential (Ecorr) in 3.5% NaCl aqueous solution and its value was compared with the pitting potential (Ep) value and the type of anodic potentiodynamic curve obtained for determination of Ep in this solution. F…

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsWelding Techniques and Residual Stresses

Structure Refinement of (Sr,Ba)Nb2O6 Ceramic Powder from Neutron and X-Rays Diffraction Data

Juan Alfredo Guevara Carrió、Yvonne Primerano Mascarenhas、W. B. Yelon 等 6 位作者2002-03-01Materials Research

The structure of polycrystalline strontium barium niobate at room temperature was refined by the Rietveld method. Sintered ceramic samples were used to collect powder neutron and X-ray diffraction data. The ratio Sr/Ba ~ 64/36 was found from the initial batch composition Sr0.61Ba0.39Nb2O6, corroborating with the quant…

Ferroelectric and Piezoelectric MaterialsAcoustic Wave Resonator TechnologiesMicrowave Dielectric Ceramics Synthesis

Conservation of the stone in Cibeles Fountain, Madrid , Spain

M. C. López de Azcona、R. Fort González、F. Mingarro Martín2002-03-01Materiales de Construccion

The water in Cibeles Fountain flows in a closed circuit and is replaced every 6 months. After this period of time, an increase in bicarbonate, sulfate, calcium and magnesium contents is registered in the water, as well as a slight increase in its acidity. This acidity, favored by atmospheric pollution, is the main cau…