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Effect of zinc phosphate chemical conversion coating on corrosion behaviour of mild steel in alkaline medium: protection of rebars in reinforced concrete

Florica Simescu and Hassane Idrissi2008-01-01Science and Technology of Advanced Materials

We outline the ability of zinc phosphate coatings, obtained by chemical conversion, to protect mild steel rebars against localized corrosion, generated by chloride ions in alkaline media. The corrosion resistance of coated steel, in comparison with uncoated rebars and coated and uncoated steel rebars embedded in morta…

TOPICAL REVIEW Fabrication and characterization of nanostructures on insulator substrates by electron-beam-induced deposition

Minghui Song and Kazuo Furuya2008-01-01Science and Technology of Advanced Materials

The fabrication, characterization, and decoration with metallic nanoparticles of nanostructures such as nanowhiskers, nanodendrites, and fractal-like nanotrees on insulator substrates by electron-beam-induced deposition (EBID) are reviewed. Nanostructures with different morphologies of whiskers, dendrites, or trees ar…

Characterization of ITO/CdO/glass thin films evaporated by electron beam technique

Hussein Abdel-Hafez Mohamed and Hazem Mahmoud Ali2008-01-01Science and Technology of Advanced Materials

A thin buffer layer of cadmium oxide (CdO) was used to enhance the optical and electrical properties of indium tin oxide (ITO) films prepared by an electron-beam evaporation technique. The effects of the thickness and heat treatment of the CdO layer on the structural, optical and electrical properties of ITO films wer…

Positive segregation as a function of buoyancy force during steel ingot solidification

Zarko Radovic, Nada Jaukovic, Milisav Lalovic and Nebojsa Tadic2008-01-01Science and Technology of Advanced Materials

We analyze theoretically and experimentally solute redistribution in the dendritic solidification process and positive segregation during solidification of steel ingots. Positive segregation is mainly caused by liquid flow in the mushy zone. Changes in the liquid steel velocity are caused by the temperature gradient a…

Application of dynamic impedance spectroscopy to atomic force microscopy

Kazimierz Darowicki, Artur Zieliński and Krzysztof J Kurzydłowski2008-01-01Science and Technology of Advanced Materials

Atomic force microscopy (AFM) is a universal imaging technique, while impedance spectroscopy is a fundamental method of determining the electrical properties of materials. It is useful to combine those techniques to obtain the spatial distribution of an impedance vector. This paper proposes a new combining approach ut…

Reinforcement of dynamically vulcanized EPDM/PP elastomers using organoclay fillers

Yuhsin Tsai, Jyh-Horng Wu, Yao-Tsu Wu, Chia-Hao Li and Ming-Tsong Leu2008-01-01Science and Technology of Advanced Materials

Dynamically vulcanized EPDM/PP (ethylene-propylene-diene/polypropylene) elastomers reinforced with various amounts of organoclay were prepared using octylphenol-formaldehyde resin and stannous chloride dehydrate as vulcanizing agents. The effects of organoclay on vulcanization characteristics, rheological behavior, mo…

A novel method for synthesis of α-Si3N4 nanowires by sol–gel route

Mahua Ghosh Chaudhuri et al2008-01-01Science and Technology of Advanced Materials

Silicon nitride (Si3 N4) nanowires have been prepared by carbothermal reduction followed by the nitridation (CTRN) of silica gel containing ultrafine excess carbon obtained by the decomposition of dextrose over the temperature range of 1200–1350 °C. This innovative process involves repeated evacuation followed by purg…

Crystal growth and structure of L-methionine L-methioninium hydrogen maleate—a new NLO material

Subramanian Natarajan et al2008-01-01Science and Technology of Advanced Materials

A new organic nonlinear optical (NLO) crystal from the amino acid family, viz., L-methionine L-methioninium hydrogen maleate (LMMM), has been grown by slow evaporation method from aqueous solution. Bulk crystals were grown using submerged seed solution method. The structure was elucidated using the single crystal x-ra…

Magnetic alignment and patterning of cellulose fibers

Fumiko Kimura and Tsunehisa Kimura2008-01-01Science and Technology of Advanced Materials

The alignment and patterning of cellulose fibers under magnetic fields are reported. Static and rotating magnetic fields were used to align cellulose fibers with sizes ranging from millimeter to nanometer sizes. Cellulose fibers of the millimeter order, which were prepared for papermaking, and much smaller fibers with…

The stability of polysiloxanes incorporating nano-scale physical property modifiers

James P Lewicki et al2008-01-01Science and Technology of Advanced Materials

Reported here is the synthesis and subsequent characterization of the physical and chemical properties of novel polysiloxane elastomers modified with a series of polyhedraloligomericsilsequioxane (POSS) molecular silicas. The physical properties of the formulated nanocomposite systems have been characterized with a co…

Investigation of low-resistivity from hydrogenated lightly B-doped diamond by ion implantation

Cui Xia Yan et al2008-01-01Science and Technology of Advanced Materials

We have implanted boron (B) ions (dosage: 5×1014 cm-2) into diamond and then hydrogenated the sample by implantating hydrogen ions at room temperature. A p-type diamond material with a low resistivity of 7.37 mΩ cm has been obtained in our experiment, which suggests that the hydrogenation of B-doped diamond results in…

Foreword: Focus on Superconductivity in Semiconductors

Yoshihiko Takano2008-01-01Science and Technology of Advanced Materials

Since the discovery of superconductivity in diamond, much attention has been given to the issue of superconductivity in semiconductors. Because diamond has a large band gap of 5.5 eV, it is called a wide-gap semiconductor. Upon heavy boron doping over 3×1020 cm−3, diamond becomes metallic and demonstrates superconduct…

Investigation of ordering phenomenon in Me–Pt (Me=Fe,Ni) liquid alloys

Yisau Adelaja Odusote2008-01-01Science and Technology of Advanced Materials

The phase diagrams of Fe–Pt and Ni–Pt liquid alloy systems show the existence of FePt and NiPt intermetallic compounds, respectively, in their solid intermediate states, and the associative tendency between unlike atoms in these liquid alloys has been analysed using the self-association model. The concentration depend…

Growth of ZnO nanowires on nonwoven polyethylene fibers

Sunandan Baruah et al2008-01-01Science and Technology of Advanced Materials

We report the growth of ZnO nanowires on nonwoven polyethylene fibers using a simple hydrothermal method at a temperature below the boiling point of water. The ZnO nanowires were grown from seed ZnO nanoparticles affixed onto the fibers. The seed ZnO nanoparticles, with diameters of about 6–7 nm, were synthesized in i…

TOPICAL REVIEW: Rational design of new materials for spintronics: Co2FeZ (Z=Al, Ga, Si, Ge)

Benjamin Balke et al2008-01-01Science and Technology of Advanced Materials

Spintronic is a multidisciplinary field and a new research area. New materials must be found for satisfying the different types of demands. The search for stable half-metallic ferromagnets and ferromagnetic semiconductors with Curie temperatures higher than room temperature is still a challenge for solid state scienti…

TOPICAL REVIEW: Present status and future prospects of spherical aberration corrected TEM/STEM for study of nanomaterials

Nobuo Tanaka2008-01-01Science and Technology of Advanced Materials

The present status of Cs-corrected TEM/STEM is described from the viewpoint of the observation of nanomaterials. Characteristic features in TEM and STEM are explained using the experimental data obtained by our group and other research groups. Cs correction up to the 3rd-order aberration of an objective lens has alrea…

Electronic structures and three-dimensional effects of boron-doped carbon nanotubes

Takashi Koretsune and Susumu Saito2008-01-01Science and Technology of Advanced Materials

We study boron-doped carbon nanotubes by first-principles methods based on the density functional theory. To discuss the possibility of superconductivity, we calculate the electronic band structure and the density of states (DOS) of boron-doped (10,0) nanotubes by changing the boron density. It is found that the Fermi…

Effect of metal-ion-to-fuel ratio on the phase formation of bioceramic phosphates synthesized by self-propagating combustion

Swamiappan Sasikumar and Rajagopalan Vijayaraghavan2008-01-01Science and Technology of Advanced Materials

Synthetic calcium hydroxyapatite (HAP, Ca10 (PO4)6 (OH)2) is a well-known bioceramic material used in orthopedic and dental applications because of its excellent biocompatibility and bone-bonding ability due to its structural and compositional similarity to human bone. Here we report, for the first time, the synthesis…

TOPICAL REVIEW: Highly spin-polarized materials and devices for spintronics

Koichiro Inomata et al.2008-01-01Science and Technology of Advanced Materials

The performance of spintronics depends on the spin polarization of the current. In this study half-metallic Co-based full-Heusler alloys and a spin filtering device (SFD) using a ferromagnetic barrier have been investigated as highly spin-polarized current sources. The multilayers were prepared by magnetron sputtering…