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Nanofibers Formed Through π···π Stacking of the Complexes of Glucosyl-C2-salicyl-imine and Phenylalanine: Characterization by Microscopy, Modeling by Molecular Mechanics, and Interaction by α-Helical and β-Sheet Proteins

Amitabha Acharya、Balaji Ramanujam、Atanu Mitra 等 4 位作者2010-06-03ACS Nano

This paper deals with the self-assembly of the 1:1 complex of two different amphiphiles, namely, a glucosyl-salicyl-imino conjugate (L) and phenylalanine (Phe), forming nanofibers over a period of time through pi...pi interactions. Significant enhancement observed in the fluorescence intensity of L at approximately 42…

Luminescence and Fluorescent MaterialsSupramolecular Self-Assembly in MaterialsPolydiacetylene-based materials and applications

A water‐soluble amphoteric copolymer: Synthesis and its dispersion properties on cement particles

Wei‐Hung Weng、Kung‐Chung Hsu、Yeong‐Nain Sheen2010-06-03Journal of Applied Polymer Science

Abstract A new water‐soluble amphoteric copolymer (PAC) was synthesized and evaluated as a dispersion agent for cement particles. PAC was prepared from acrylamide and 2‐(3‐carboxyacryloyloxy)‐ N ‐(carboxymethyl)‐ N,N ‐dimethyl ethanaminium (CAC) through free‐radical polymerization. The structure of the prepared polyme…

Concrete and Cement Materials ResearchPolymer Nanocomposites and PropertiesSynthesis and properties of polymers

Biosynthesis of polyhydroxyalkanotes in wildtype yeasts

AM Desuoky、Abd El-Haleem、S. S. Zaki 等 6 位作者2010-06-03Journal of applied science and environmental management

Biosynthesis of the biodegradable polymers polyhydroxyalkanotes (PHAs) are studied extensively in wild type and genetically modified prokaryotic cells, however the content and structure of PHA in wild type yeasts are not well documented. The purpose of this study was to screen forty yeast isolates collected from diffe…

biodegradable polymer synthesis and propertiesElectrospun Nanofibers in Biomedical ApplicationsMicroplastics and Plastic Pollution

Effect of primary α content on creep and creep crack growth behaviour of near α-Ti alloy

C.M. Omprakash、D.V.V. Satyanarayana、Vikas Kumar2010-06-03Materials Science and Technology

The effect of primary α content on creep and creep crack growth behaviour of a near α-Ti alloy has been investigated at 600°C. The alloy was heat treated at different temperatures so as to obtain different volume fractions of equiaxed primary α in the range from 5 to 40%. Constant load creep tests were carried out at…

High Temperature Alloys and CreepIntermetallics and Advanced Alloy PropertiesTitanium Alloys Microstructure and Properties

Synthesis and characterization of electrically conducting copolymers based on biphenyl and thiophene

J. Simitzis、Despina Triantou、Spyridon Soulis2010-06-03Journal of Applied Polymer Science

Abstract New electrically conducting copolymers based on biphenyl and thiophene in a form of film were synthesized by electropolymerization using potentiostatic conditions and the corresponding homopolymers, polyphenylenes, and polythiophenes, for comparison reasons. Different values of applied potential were used, to…

Organic Electronics and PhotovoltaicsAdvanced Sensor and Energy Harvesting MaterialsConducting polymers and applications

Relaxation kinetics of stretched disclination lines in a nematic liquid crystal

Natan Osterman、Jurij Kotar、Eugene M. Terentjev 等 4 位作者2010-06-03Physical Review E

The dynamics of disclination defect lines in a nematic liquid crystal are measured experimentally and considered theoretically. An optical trap is used to deform the line, enabling the previously unexplored regime of large deformation to be accessed. The relaxation follows a linear decay at large amplitude, crossing o…

Liquid Crystal Research AdvancementsOrbital Angular Momentum in OpticsMolecular spectroscopy and chirality

Volume-Based Thermoelasticity: Compressibility of Mineral-Structured Materials

Leslie Glasser2010-06-03The Journal of Physical Chemistry C

Thermodynamic properties, such as entropy among others, have been shown to correlate well with formula volume, thus permitting prediction of these properties on the basis of chemical formula and density alone, with no structural detail required. We here extend these studies to the thermoelastic property of isothermal…

High-pressure geophysics and materialsCalcium Carbonate Crystallization and InhibitionThermal Expansion and Ionic Conductivity

Synthesis and application of methylcellulose extracted from waste newspaper in CPV‐ARI Portland cement mortars

Geandre de Carvalho Oliveira、Guimes Rodrigues Filho、Júlia Graciele Vieira 等 9 位作者2010-06-03Journal of Applied Polymer Science

Abstract Cellulose extracted from waste newspaper was methylated using dimethylsulfate to produce methylcellulose with degree of substitution of 1.46 ± 0.06. This material was characterized by FTIR and DSC. An aqueous dispersion of methylcellulose was used to produce mortars of Portland cement (CPV‐ARI). The results s…

Concrete and Cement Materials ResearchAdvanced Cellulose Research StudiesInnovations in Concrete and Construction Materials

TGA/DTG/DSC investigation of thermal ageing effects on polyamide–imide enamel

B. Górnicka、L. Górecki2010-06-03Journal of Thermal Analysis and Calorimetry

Thermoanalytical investigations TGA/DTG/DSC of polyamide–imide enamel after thermal ageing have been presented. The lifetimes at 260, 270, 280, 290, 300 °C were determined. The thermograms of the enamels after attaining of their lifetimes much depend on the ageing temperature. The temperatures of 5% loss of mass that…

Dental materials and restorationsThermography and Photoacoustic TechniquesThermal and Kinetic Analysis

Alternative oxidizers in polyaniline synthesis

Jacek Nizioł、Maciek Sniechowski、Anna Podraza-Guba 等 4 位作者2010-06-03Polymer Bulletin

The article describes a modified method of polyaniline synthesis. The classical oxidizer—aqueous solution of hydrogen peroxide was replaced by different solid state hydrogen peroxide complexes, what helped keep constant temperature of the reaction mixture. The highest yield of the polymerization was obtained using ure…

Electrochemical sensors and biosensorsConducting polymers and applicationsAnalytical Chemistry and Sensors

Polypropylene/carbon nanotube composites prepared with a environmentally benign processes

Junsuk Kim、Yeonsu Jung、Young‐Je Kwark 等 4 位作者2010-06-03Journal of Applied Polymer Science

Abstract Polypropylene (PP)/multiwalled carbon nanotube (MWNT) composites were prepared with an environmentally benign processes. The surface functionalization of the MWNTs was performed with water as a solvent, and the functionalized MWNTs were mixed with PP to form composites with a melt process. The effects of the…

Carbon Nanotubes in CompositesPolymer Nanocomposites and PropertiesPolymer Nanocomposite Synthesis and Irradiation

Influence of cryogenic modification of silica on thermal properties and flammability of cross-linked nitrile rubber

Przemysław Rybiński、G. Janowska、L. Ślusarski2010-06-03Journal of Thermal Analysis and Calorimetry

The article presents the results of testing thermal properties and combustibility of butadieneacrylonitrile rubber with 18% contents of bounded acrylonitrile, NBR 18. Two types of silica, Zeosil 175C and Ultrasil VN-3, with different specific surfaces were used as filler. Zeosil 175C and Ultrasil VN-3 were modified vi…

Polymer Nanocomposites and PropertiesFlame retardant materials and propertiesPolymer Science and Applications

Study of PP/PS Interpolymer Foam Rod Extrusion; Surface and Cell Wall Quality

Shau-Tarng Lee2010-06-03Journal of Cellular Plastics

PP/PS interpolymer foam was tested in the rod extrusion process while using chemical blowing agents (CBA) and carbon dioxide physical blowing agent (PBA), respectively. Foam density decreases as blowing agent level increases. After it dips to a minimum, the foam density curve goes up. Although both CBA and PBA show th…

Phase Equilibria and ThermodynamicsRheology and Fluid Dynamics StudiesPolymer Foaming and Composites

An investigation into the morphology and electro‐optical properties of 2‐hydroxy ethyl methacrylate polymer dispersed liquid crystals

Huey‐Ling Chang、Chih‐Ming Chen2010-06-03Journal of Applied Polymer Science

Abstract Polymer dispersed liquid crystal (PDLC) films are fabricated using E7 liquid crystals, tetraethylene glycol diacrylate (TeGDA) crosslinking agent, and 0–66.49 mol % 2‐hydroxy ethyl methacrylate (HEMA). The effects of different levels of HEMA addition on the microstructure and electro‐optical properties of the…

Liquid Crystal Research AdvancementsPhase-change materials and chalcogenidesPlant Reproductive Biology

Rapid Synthesis of Uniform Magnetic Microspheres by Combing Premix Membrane Emulsification and in Situ Formation Techniques

Jian Yang、Dongxia Hao、Cai-Xia Bi 等 6 位作者2010-06-03Industrial & Engineering Chemistry Research

Uniform magnetic poly(styrene-co-2-hydroxyethyl methacrylate) (PST-HEMA) microspheres were fabricated by a novel route combining premix membrane emulsification of double emulsion and an in situ magnetization technique. The fabrication involved, first, the preparation of uniform double W/O/W emulsions with ferrous ferr…

Micro and Nano RoboticsPickering emulsions and particle stabilizationCharacterization and Applications of Magnetic Nanoparticles

Reactions during Electrochemically Induced Nucleation of Mullite from a MgO/Al2O3/TiO2/SiO2/B2O3/CaO Melt

Robert Carl、Wolfgang Wisniewski、Christian Rüssel2010-06-03Crystal Growth & Design

Glasses with the composition 52.6 SiO 2 ·18.7 Al 2 O 3 ·14.3 MgO·7.7 TiO 2 ·4.7 B 2 O 3 ·2.0 CaO were crystallized using electrochemically induced nucleation at temperatures from 1200 to 1400 °C. The crystals grew with their fastest growing axis pointing away from the surface of the electrode. At the cathode, Ti 4+ is…

Luminescence Properties of Advanced MaterialsGlass properties and applicationsMetallic Glasses and Amorphous Alloys

Effect of modified layered silicates on the confined crystalline morphology and thermomechanical properties of poly(ethylene oxide) nanocomposites

Thomas Abraham、Suchart Siengchin、Debdatta Ratna 等 4 位作者2010-06-03Journal of Applied Polymer Science

Abstract In this work, poly(ethylene oxide) (PEO)/organoclay nanocomposites with three different types of nanoclays (Cloisite 30B, Somasif JAD400, and Somasif JAD230) were prepared by melt mixing with a laboratory kneader followed by compression molding. The nanocomposites were characterized by atomic force microscopy…

Polymer crystallization and propertiesPolymer Nanocomposites and Propertiesbiodegradable polymer synthesis and properties

Total Synthesis of Hematoporphyrin and Protoporphyrin: A Conceptually New Approach

Pierre Martin、Markus Müller、Dietmar Flubacher 等 6 位作者2010-06-03Organic Process Research & Development

The total synthesis of protoporphyrin IX and its disodium salt using a new alternative method to the classical MacDonald condensation is reported. The key step is the reaction of the new unsymmetrical diiodo dipyrrylmethane 1 with the known dipyrrylmethane 2 . Coupling of the two fragments leads directly to porphyrin…

Photosynthetic Processes and MechanismsPorphyrin and Phthalocyanine ChemistryPhotodynamic Therapy Research Studies

Role of a compatibilizer in the structure and micromechanical properties of recycled poly(ethylene terephthalate)/polyolefin blends with clay

Abdelhak Hellati、D. Benachour、M. E. Cagiao 等 5 位作者2010-06-03Journal of Applied Polymer Science

Abstract The comparison of the degree of crystallinity and the micromechanical properties in the blends of recycled amorphous poly(ethylene terephthalate) (PET) with isotactic polypropylene (iPP) and high‐density polyethylene (HDPE) with a compatibilizer in different proportions is reported. The physical study of the…

Polymer crystallization and propertiesPolymer Nanocomposites and Propertiesbiodegradable polymer synthesis and properties

Rotational Foam Molding of Metallocene Catalyzed Polyethylene: CBA Screening and Process Characteristics

Maryam Emami、E. Takács、J. Vlachopoulos2010-06-03Journal of Cellular Plastics

The objective of this work is to investigate the effects of different chemical blowing agents (CBAs) and processing conditions on the cellular structure of foamed metallocene polyethylene and characterize an appropriate blowing agent. An experimental study was conducted to produce metallocene polyethylene foams in dry…

Epoxy Resin Curing ProcessesInjection Molding Process and PropertiesPolymer Foaming and Composites