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Electrochemical and optical properties of biphenyl bridged-dicarbazole oligomer films: Electropolymerization and electrochromism

Sermet Koyuncu、Burak Gültekin、Ceylan Zafer 等 8 位作者2009-05-14Electrochimica Acta

4,4′-Di(N-carbazoyl)biphenyl monomer (CBP) was synthesized and coated onto ITO–glass surface by electrochemical oxidative polymerization. Its CV shows two distinct one-electron and stepwise oxidation processes occurred at 1.29 and 1.61 V. By using this property, the monomer was electrochemically polymerized separately…

Conducting polymers and applicationsTransition Metal Oxide NanomaterialsOrganic Electronics and Photovoltaics

Benzothiazole- and Benzoxazole-Substituted Pyridine-2-Carboxylates as Efficient Sensitizers of Europium Luminescence

N.M. Shavaleev、Rosario Scopelliti、F. Gumy 等 4 位作者2009-05-14Inorganic Chemistry

A facile synthesis of benzothiazole- and benzoxazole-substituted pyridine-2-carboxylic acids has been developed. These ligands form mononuclear nine-coordinate complexes [Ln(kappa(3)-ligand)(2)(kappa(1)-ligand)(H(2)O)(2)] with light and heavy trivalent lanthanides, as established from the X-ray analysis of 11 complexe…

Medical Imaging Techniques and ApplicationsLanthanide and Transition Metal ComplexesAdvanced MRI Techniques and Applications

Chemical Redox Modulation of the Surface Chemistry of CdTe Quantum Dots for Probing Ascorbic Acid in Biological Fluids

Ying‐Jun Chen、Xiu‐Ping Yan2009-05-14Small

Most of the fluorescence resonance energy transfer (FRET)-based sensors employing quantum dots (QDs) usually use organic fluorophores and gold nanoparticles as the quenchers. However, complex processes for the modification/immobilization of the QDs are always necessary, as the generation of FRET requires strict distan…

Advanced biosensing and bioanalysis techniquesCarbon and Quantum Dots ApplicationsQuantum Dots Synthesis And Properties

Continuous-Wave Pumping of Multiexciton Bands in the Photoluminescence Spectrum of a Single CdTe-CdSe Core-Shell Colloidal Quantum Dot

Ruth Osovsky、Dima Cheskis、Viki Kloper 等 6 位作者2009-05-14Physical Review Letters

Single-exciton, biexciton, triexciton, and quadraexciton bands were resolved in the microphotoluminescence spectrum of a single CdTe/CdSe core-shell colloidal quantum dot, revealing nearly blinking-free behavior. Multiexcitons were generated by a sequential filling of electronic shells with the increase of a continuou…

Semiconductor Quantum Structures and DevicesChalcogenide Semiconductor Thin FilmsQuantum Dots Synthesis And Properties

Synthesis, Characterization, and Photocatalytic Application of Different ZnO Nanostructures in Array Configurations

Yang Liu、Zhenhui Kang、Zhenhua Chen 等 8 位作者2009-05-14Crystal Growth & Design

Arrays of well-aligned one-dimensional ZnO nanostructures (nanowires, nanorods, nanoribbons, nanobuds, and flocky nanorods) with high aspect ratios have been grown on zinc substrates by a solution-phase method using a mixture of ethylenediamine, ethanol, and water. The morphology of the ZnO nanostructures has been mod…

Ga2O3 and related materialsZnO doping and propertiesGas Sensing Nanomaterials and Sensors

Spatial distribution of local density of states in vicinity of impurity on semiconductor surface

V. N. Mantsevich、N. S. Maslova2009-05-14arXiv

We present the results of detailed theoretical investigations of changes in local density of total electronic surface states in 2D anisotropic atomic semiconductor lattice in vicinity of impurity atom for a wide range of applied bias voltage. We have found that taking into account changes in density of continuous spec…

Mesoscale and Nanoscale PhysicsMaterials Science

Transformation kinetics of alloys under non-isothermal conditions

Ali R. Massih、Lars O. Jernkvist2009-05-14arXiv

The overall solid-to-solid phase transformation kinetics under non-isothermal conditions has been modeled by means of a differential equation method. The method requires provisions for expressions of the fraction of the transformed phase in equilibrium condition and the relaxation time for transition as functions of t…

Materials Science

A compact apparatus for studies of element and phase-resolved ferromagnetic resonance

D. A. Arena、Y. Ding、E. Vescovo 等 6 位作者2009-05-14arXiv

We present a compact sample holder equipped with electromagnets and high frequency transmission lines; the sample holder is intended for combined x-ray magnetic circular dichroism (XMCD) and ferromagnetic resonance measurements (FMR). Time-resolved measurements of resonant x-ray detected FMR during forced precession a…

Materials ScienceMesoscale and Nanoscale Physics

Galvanomagnetic properties and noise in a barely metallic film of V2O3

Clara Grygiel、Alain Pautrat、Pierre Rodiere2009-05-14arXiv

We have measured the magnetotransport properties of a strained metallic V2O3 thin film. Most of the properties are similar to V2O3 single crystals that have been submitted to a large pressure. In addition, resistance noise analysis indicates that conductivity fluctuations are freezing out at T\approx 10K. Examination…

Strongly Correlated ElectronsMaterials Science

MgN: a new promising material for spintronic applications

A. Droghetti、N. Baadji、S. Sanvito2009-05-14arXiv

Density functional theory calculations demonstrate that rocksalt MgN is a magnetic material at the verge of half-metallicity, with an electronic structure robust against strong correlations and spin-orbit interaction. Furthermore the calculated heat of formation describes the compound as metastable and suggests that i…

Materials Science

Single-Spin Microscope with Sub-Nanoscale Resolution Based on Optically Detected Magnetic Resonance

Gennady P. Berman、Boris M. Chernobrod2009-05-14arXiv

We summarize our new scanning magnetic 3-D imaging system. This scanning system uses optically detected magnetic resonance in a single nitrogen vacancy center in a diamond nanocrystal. The theoretical analysis and the first experimental demonstrations have proved that this method has single spin sensitivity and a sub-…

Mesoscale and Nanoscale PhysicsMaterials Science

Controlling Affinity Binding with Peptide‐Functionalized Poly(ethylene glycol) Hydrogels

Chien‐Chi Lin、Kristi S. Anseth2009-05-14Advanced Functional Materials

Poly(ethylene glycol) (PEG) hydrogels functionalized with peptide moieties have been widely used in regenerative medicine applications. While many studies have suggested the importance of affinity binding within PEG hydrogels, the relationships between the structures of the peptide motifs and their binding to protein…

Silk-based biomaterials and applicationsGlycosylation and Glycoproteins ResearchHydrogels: synthesis, properties, applications

Dynamic Disorder in Negative Thermal Expansion Compound Zn(CN)2

R. Mittal、S. Mitra、H. Schober 等 5 位作者2009-05-14arXiv

Dynamical disorder in negative thermal expansion compound Zn(CN)2 is investigated by quasielastic neutron scattering technique in the temperature range 170-320 K. Significant quasielastic broadening is observed above the phase transition temperature of about 250 K, however no broadening is observed at 220 K and below.…

Materials Sciencecond-mat.other

Electric-field-dependent energy structure of quasi-one-dimensional conductor o-TaS_3

V. F. Nasretdinova、S. V. Zaitsev-Zotov2009-05-14arXiv

Energy structure of the Peierls gap in orthorhombic TaS$_3$ is examined by spectral study of photoconduction. The gap edge and energy levels inside the Peierls gap are observed. The amplitude of the energy levels is found to depend on both the temperature and the electric field. The electric field of the order of 10 V…

Materials ScienceStrongly Correlated Electrons

Dynamic Effects Induced Transition of Droplets on Biomimetic Superhydrophobic Surfaces

Yong Chae Jung、Bharat Bhushan2009-05-14Langmuir

Superhydrophobic surfaces have considerable technological potential for various applications because of their extreme water-repellent properties. Dynamic effects, such as the bouncing and vibration of a droplet, can destroy the composite solid-air-liquid interface. The impact pressure of a bouncing droplet and the ine…

Fluid Dynamics and Heat TransferAdhesion, Friction, and Surface InteractionsSurface Modification and Superhydrophobicity

One-Step Hydrothermal Crystallization of a Layered Double Hydroxide/Alumina Bilayer Film on Aluminum and Its Corrosion Resistance Properties

Xiaoxiao Guo、Sailong Xu、Lili Zhao 等 7 位作者2009-05-14Langmuir

A zinc-aluminum layered double hydroxide (ZnAl-LDH)/alumina bilayer film has been fabricated on an aluminum substrate by a one-step hydrothermal crystallization method. The LDH film was uniform and compact. XRD patterns and SEM images showed that the LDH film was highly oriented with the c-axis of the crystallites par…

Thermal Expansion and Ionic ConductivityLayered Double Hydroxides Synthesis and ApplicationsMagnesium Oxide Properties and Applications

The importance of dispersal related and local factors in shaping the taxonomic structure of diatom metacommunities

Elie Verleyen、Wim Vyverman、Mieke Sterken 等 14 位作者2009-05-14Oikos

To date, little is known about the relative importance of dispersal related versus local factors in shaping microbial metacommunities. A common criticism regarding existing datasets is that the level of taxonomic resolution might be too coarse to reliably assess microbial community structure and study biogeographical…

Diatoms and Algae ResearchMicrobial Community Ecology and PhysiologyFreshwater macroinvertebrate diversity and ecology

Unusual Tuning of Mechanical Properties of Isotactic Polypropylene Using Counteraction of Shear Flow and β-Nucleating Agent on β-Form Nucleation

Yanhui Chen、Gan‐Ji Zhong、Yan Wang 等 5 位作者2009-05-14Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVNoteNEXTUnusual Tuning of Mechanical Properties of Isotactic Polypropylene Using Counteraction of Shear Flow and β-Nucleating Agent on β-Form NucleationYan-Hui Chen†, Gan-Ji Zhong†, Yan Wang†, Zhong-Ming Li*†, and Liangbin Li‡View Author Information† College of Polymer Science and Engi…

Polymer crystallization and propertiesbiodegradable polymer synthesis and propertiesPolymer Nanocomposites and Properties

Polarization Holography

L. Nikolova、P. S. Ramanujam2009-05-14Cambridge University Press eBooks

Current research into holography is concerned with applications in optically storing, retrieving, and processing information. Polarization holography has many unique properties compared to conventional holography. It gives results in high efficiency, achromaticity, and special polarization properties. This books revie…

Liquid Crystal Research Advancements

Low Temperature Studies of the Excited-State Structure of Negatively Charged Nitrogen-Vacancy Color Centers in Diamond

Anton Batalov、V. Jacques、Florian Kaiser 等 10 位作者2009-05-14Physical Review Letters

We report a study of the 3E excited-state structure of single negatively charged nitrogen-vacancy (NV) defects in diamond, combining resonant excitation at cryogenic temperatures and optically detected magnetic resonance. A theoretical model is developed and shows excellent agreement with experimental observations. In…

Laser-Ablation Synthesis of NanoparticlesDiamond and Carbon-based Materials ResearchNonlinear Optical Materials Studies