Materials Literature
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Spin-polarized tunneling was demonstrated on La0.7Sr0.3MnO3 epitaxial thin film with a La0.7Sr0.3MnO3-coated PtIr tip at room temperature. A magnetic-field-dependent gap structure was found in the differential tunneling spectra due to the spin-valve effect. The spatial mapping of the differential tunneling conductance…
The encapsulation of monomer molecules in liquid crystal droplets dispersed in a thermoplastic matrix provides a convenient method to control the orientation of liquid crystal directors. The imprint of droplet interfaces is obtained by photopolymerization of monomer molecules by means of a polymerization induced phase…
ZrO 2 :Mn , Cl luminescent powders have been synthesized at temperatures ranging from 250 to 500 °C. X-ray diffraction measurements indicate changes in the crystallinity of the material as a function of the processing temperature. The photoluminescence spectra show bands associated with transitions from the 4T1 level…
In order to provide experimental support for quantum confinement models describing electronic effects in porous silicon (p-Si), the Si 2s and Si 2p plasmon losses have been studied by x-ray photoelectron spectroscopy. The p-Si plasmon energy was found at a value 0.8÷1.6 eV higher than that of bulk Si (17.4 eV), as mea…
A Cu/ZrW 2 O 8 metal matrix composite was thermally cycled between 298 and 591 K while being subjected to x-ray diffraction in transmission using high-intensity synchrotron radiation. The reversible allotropic phase transformations of ZrW 2 O 8 between its two low-pressure phases and its high-pressure phase were obser…
This work investigates the effect of hydrostatic pressure on the excitation and emission spectra, as well as on the lifetime, of Al 2 O 3 :Ti 3+ at room temperature. The aim is to establish correlations between the pressure-induced band shifts and the corresponding local structural changes undergone by the TiO 6 compl…
We have performed variable-temperature multimode quantitative microwave microscopy of in situ epitaxial Ba1−xSrxTiO3 thin-film composition spreads fabricated on (100) LaA1O3 substrates. Dielectric properties were mapped as a function of continuously varying composition from BaTiO3 to SrTiO3. We have demonstrated nonde…
The fabrication, initial structural characterization, and diode measurements are reported for a boron carbide/silicon carbide heterojunction diode. Current–voltage curves are obtained for operation at temperatures from 24 to 351 °C. Plasma-enhanced chemical-vapor deposition (PECVD) -deposited undoped boron carbide mat…
Recently the study of liquid drainage through foams has generated considerable experimental and theoretical research. This research has usually made the assumptions that the liquid content is very low and that the viscous resistance is limited to occurring within either the Plateau borders or vertices. This paper pres…
The magnetic, structural, and transport properties of the Heusler alloy Co2MnSi are reported for sputtered thin films and a single crystal. X-ray diffraction reveals a phase pure L21 structure for all films grown between 573 and 773 K. Films grown at 773 K display a four-fold decrease in the resistivity relative to th…
We report the observation of giant photoresistivity in electrochemically self-assembled CdS and ZnSe nanowires electrodeposited in a porous alumina film. The resistance of these nanowires increases by one to two orders of magnitude when exposed to infrared radiation, possibly because of real-space transfer of electron…
Large-scale copper nanowires have been fabricated by potentiostatic electrochemical deposition (ECD) of copper sulphate solution within the nanochannels of porous anodic alumina templates. Scanning electron microscopy, transmission electron microscopy, selected-area electron diffraction and x-ray diffraction technique…
Many materials containing colloids or polymers are polydisperse: they comprise particles with properties (such as particle diameter, charge, or polymer chain length) that depend continuously on one or several parameters. This review focuses on the theoretical prediction of phase equilibria in polydisperse systems; the…
The structures of tungsten trioxide, WO 3 , have been studied in fine temperature steps, from room temperature to 1000 °C, by means of very high-resolution neutron powder diffraction. It was confirmed that the sample used was single-phase monoclinic in space group P 2 1 / n at room temperature. In addition to this mon…
Flexoelectric coefficient μ12 is greatly enhanced in the relaxor ferroelectric lead magnesium niobate ceramic. Phenomenological analysis suggests the high dielectric permittivity is inadequate to explain the great enhancement. Temperature dependent measurement reveals a close relation between the flexoelectric polariz…
We study Mode I fracture in a viscoelastic lattice model with a nonlinear force law, with a focus on the velocity and linear stability of the steady-state propagating solution. This study is a continuation both of the study of the piece-wise linear model in Mode I, and the study of more general nonlinear force laws in…
Upon cooling from its hexagonal high-temperature modification, AlPO4 (aluminium phosphate) tridymite successively transforms to several displacively distorted forms, including a normal structure-incommensurate-lock-in phase transition sequence. The space-group symmetries in this series are P112(1), P112(1)(alphabeta0)…
The structure of the hydrothermally synthesized compound AgCo3PO4(HPO4)2, silver tricobalt phosphate bis(hydrogen phosphate), consists of edge-sharing CoO6 chains linked together by the phosphate groups and hydrogen bonds. The three-dimensional framework delimits two types of tunnels which accommodate Ag+ cations and…
The crystal structure of (4,4'-dimethyl-2,2'-bipyridyl)tris[3,3,3-trifluoro-1-(2-thenoyl)propan-2-onato]europium(III), or more commonly (4,4'-dimethyl-2,2'-bipyridyl)tris(2-thenoyltrifluoroacetonato)europium(III), [Eu(C8H4F3O2S)3(C12H12N2)], has been determined. Crystals of the complex emit vivid red light when scratc…
Results are presented for the temperature dependence of the thermodynamic and conformational properties of cis-1,4 polyisoprene (PI) melts from detailed atomistic parallel-tempering end-bridging Monte Carlo (ptEBMC) simulations. The simulations have been performed with a C80 cis-1,4 PI melt system which was simultaneo…