Materials Literature
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In this study, titanium dioxide (TiO(2)) films were fabricated by cosputtering of a titanium (Ti) target and an aluminum (Al) slice in a smaller area by an ion-beam sputtering deposition method. The sputtered films were postannealed at 450 degrees C. The x-ray photoelectron spectroscopy spectra were categorized by the…
Good surface properties and biocompatibility are crucial to porous NiTi shape memory alloys (SMA) used in medical implants, as possible nickel release from porous NiTi may cause deleterious effects in the human body. In this work, oxygen plasma immersion ion implantation (O-PIII) was used to reduce the amount of nicke…
Self-organized surface nanostructures were formed during laser molecular beam epitaxy of nonpolar ZnO (10−10). The growth mechanism of the nanostructures was related to a Schwoebel barrier effect generated during ZnO homoepitaxy. Small islands elongated along the [001] direction were generated on two-dimensional (2D)…
An inorganic-organic hybrid semiconductor, ZnS/CHA (CHA = cyclohexylamine) nanocomposites was successfully synthesized via a solvothermal method using CHA as solvent, which yielded uniform and ultralong nanowires with widths of 100-1000 nm and lengths of 5-20 microm. Changing the reaction conditions could alter the mo…
This paper employs an atomic-scale finite element method (AFEM) to study the postbuckling behavior of carbon nanotubes (CNTs). The computed energy curves and critical strain for the (8, 0) single-walled CNT (SWNT) agree well with atomistic simulations. The AFEM is very fast and versatile owing to the efficiency of the…
A scalable and economical method to control the pretilt alignment of nematic liquid crystal (LC) to ∼45° has long been sought as it constitutes the foundation of some key technologies of LC displays. We demonstrate that nanotextured surfaces fabricated by mixing horizontal and vertical polyimides allow complete LC pre…
Large scale power production benefits from the high efficiency of gas-steam combined cycles. In the lower power range, fuel cells are a good candidate to combine with gas turbines. Such systems can achieve efficiencies exceeding 60%. High-temperature solid oxide fuel cells (SOFC) offer good opportunities for this coup…
Dielectric relaxation processes occurring near the ferroelectric-paraelectric phase transition of ferroelectromagnetic Pb(Fe1∕2Nb1∕2)O3 ceramics obtained by different precursors are discussed using microstructural and equivalent circuit modeling and the impedance spectroscopy technique. The frequency-temperature respo…
We study the phase behavior of a mixture of colloidal hard rods with a length-to-diameter ratio of L/sigma(c)=5 and nonadsorbing ideal polymer. We map our binary mixture onto an effective one-component system by integrating out the degrees of freedom of the polymer coils. We derive a formal expression for the exact ef…
Design and experimental realization of a three-dimensional superlens based on inductively and capacitively loaded transmission lines are presented. Transmission properties of the designed structure are studied experimentally and the observed lens properties are compared with analytical predictions. Backward-wave propa…
Nanocrystalline CaTiO3:Pr3+ phosphor layers were coated on nonaggregated, monodisperse, and spherical SiO2 particles by the sol-gel method, resulting in the formation of core-shell structured SiO2–CaTiO3:Pr3+ particles. X-ray diffraction, Fourier transform infrared spectroscopy, field emission scanning electron micros…
The room-temperature optical pseudo-dielectric-functions of single-phase, single-crystalline rocksalt-structure MgxZn1−xO with Mg-content x between 0.68 and 1 were determined in the photon energy range from 0.75to9.10eV using spectroscopic ellipsometry. The refractive index determined in the spectral region below the…
The correlated Einstein and Debye models for EXAFS parallel mean-square relative displacement (MSRD) are derived from the general expression in terms of eigenfrequencies and eigenvectors of the dynamical matrix, without ad hoc assumptions. The two models are generalized to parameterize also the EXAFS perpendicular MSR…
A yellow-orange nitrogen-doped zinc oxide (ZnO:N) film was deposited on a quartz glass substrate at 510K by reactive radio-frequency magnetron sputtering of a ZnO target with sputtering gas of nitrogen. The lattice constants of the as-grown ZnO:N are much larger than those of undoped ZnO, and decrease with increasing…
Te O 2 – Pb O – Ge O 2 glass samples containing silver nanoparticles (NPs) and complex nanostructures were prepared and characterized. Nucleation of NPs and formation of NP structures were obtained following the procedure of powder fusion and thermal annealing at 350°C. Electron microscopy revealed the diffusion paths…
We study the thermal conductivity of single-walled carbon nanotube bundles and multi-walled carbon nanotubes. It is shown that, for an individual single-walled carbon nanotube, its thermal conductivity is both diameter and chirality dependent. In defect-free bundles and multi-walled carbon nanotubes, the phonon essent…
The synthesis, structure, and physical properties of a novel series of oxalate-based bimetallic magnets obtained by using the Ir(ppy)2(bpy)]+ cation as a template of the bimetallic [M(II)M(III)(ox)3]- network are reported. The compounds can be formulated as [Ir(ppy)2(bpy)][M(II)Cr(III)(ox)3] x 0.5 H2O (M(II) = Ni, Mn,…
Phosphoenolpyruvate carboxykinase catalyzes the reversible decarboxylation of oxaloacetic acid with the concomitant transfer of the gamma-phosphate of GTP to form PEP and GDP as the first committed step of gluconeogenesis and glyceroneogenesis. The three structures of the mitochondrial isoform of PEPCK reported are co…
We report the structural, magnetic, electrical transport, and specific heat properties of polycrystalline ${\mathrm{GaCNi}}_{3}$ sample. The ${T}^{2}$ temperature dependence of resistivity and the large values of the Kadowaki-woods ratio $A∕{\ensuremath{\gamma}}^{2}$ $(7.2\phantom{\rule{0.3em}{0ex}}\mathrm{\ensuremath…
Materials with nanometric dimensions exhibit higher electrical resistivity due to additional scattering centers for the conduction electrons, mainly from surfaces and grain boundaries. In this study we focus on the effect of surfaces by implementing an experimental technique in which the resistivity of thin films is m…