Materials Literature
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Organic−inorganic polymer hybrids were synthesized utilizing the host−guest interaction. Cyclodextrins (CDs, α-, β-, γ-CD) could be dispersed in the silica gel matrix at a nanometer level because of the hydrogen-bonding interaction between hydroxyl moieties of CD and residual silanol groups of silica gel. It is known…
We report electro-optic experiments in liquid crystalline freestanding films of achiral hockey stick shaped mesogens with a straight aromatic core. The material forms two smectic mesophases. In the higher temperature phase, a spontaneous polarization exists in the smectic layer plane and the films show polar switching…
Silver–silica nanocomposite thin films were prepared by high pressure d.c. sputtering technique. Films deposited at lower substrate temperature showed a narrow distribution of nanoparticles with nearly spherical shape. Increase in substrate temperature resulted in films with a non-uniform size and shape due to the agg…
Nitrogen radicals were irradiated on the (0001) and (0001) surfaces of the ZnO single crystals, and the stability and the states of N ions on the surfaces were investigated by Auger electron spectroscopy (AES) and X-ray photoelectron spectroscopy (XPS). On the (0001) surface, many N ions replaced the O ions of ZnO dur…
The novel, functionalized heteropolymolybdate [(O(2)CCH(2)PO(3))(2)Mo(5)O(15)](6-) (1) has been synthesized and characterized by IR and (31)P NMR spectroscopy and elemental analysis. Single-crystal X-ray analysis was carried out on Rb(4)KNa[(O(2)CCH(2)PO(3))(2)Mo(5)O(15)].H(2)O, which crystallizes in the monoclinic sy…
The spin-$\frac{1}{2}$ molecular system ${\mathrm{V}}_{15}$ shows no barrier against spin reversal. This makes possible direct phonon activation between the two levels. By tuning the field sweeping rate and the thermal coupling between the sample and the thermal reservoir we have control over the phonon-bottleneck phe…
Using a In 2 O 3 and ZnO powder mixture with a ratio of 95:5 in wt% as a target, highly transparent conducting oxide (TCO) films are prepared on polyethylene terephthalate (PET) substrates by rf-magnetron sputtering. These films have amorphous structures with excellent electrical stability, surface uniformity and adhe…
First-principle studies on the total energy, electronic structure, and bonding nature of $R\mathrm{NiIn}$ $(R=\mathrm{La},$ Ce, and Nd), and their saturated hydrides ${(R}_{3}{\mathrm{Ni}}_{3}{\mathrm{In}}_{3}{\mathrm{H}}_{4}=R{\mathrm{NiInH}}_{1.333})$ are performed using a full-potential linear muffin-tin orbital ap…
Single-wall carbon nanotubes (SWNTs) promise wide applications in many technical fields. As a result purified SWNT material is sold now on the West market at more than $1000 per 1 gram. Thus developing an effective technology for SWNTs production rises to a very important scientific problem. The perspectives of three…
Evidence is presented for the secondary nucleation of beta-L-glutamic acid on the surface of the alpha-polymorph, using a combination of Scanning Electron Microscopy and Raman spectroscopy.
Caesium salts of mono-ruthenium(III) substituted Keggin-type silicopolytungstate ([SiW11O39RuIII(H2O)]5− (1)) and its oxo-bridged dimeric species ([{SiW11O39RuIV/III}2O]11− (8)) were prepared and characterized by elemental analysis, infrared-spectroscopy, UV-Vis spectroscopy, and cyclic voltammetry for the first time.…
The one-dimensional structure of carbon nanotubes leads to quantum confinement of the wave vectors for the electronic states, thus making the double resonance Raman process selective, not only of the magnitude, but also of the direction of the phonon wave vectors. This additional selectivity allows us to reconstruct t…
A new molecular system combining an open-shell organic radical that acts as an acceptor group, different from an o-quinone moiety, covalently linked to a ferrocene moiety, acting as the donor group, is shown to exhibit valence tautomerism.
Dielectric properties are studied in quantum paraelectric SrTiO 3 under UV-light illumination from 100 Hz to 1 MHz at low temperatures. We demonstrate that the complex dielectric constant is strongly enhanced by interband photo-excitation. Dispersion measurements confirm that the photo-induced Debye-type relaxator enh…
Nano-structured ZnO thin films were synthesized by the nanoparticle assisted pulsed-laser deposition in an oxygen background gas. Crystallized and c -axis oriented ZnO nanorods with a size of approximately 300 nm in average diameter and 6 µm in length were grown on sapphire substrates heated at approximately 700°C by…
Atomic deposition on a surface can be controlled at the nanometre scale by means of optical and magnetic forces. Impingement of atoms on the surface can lead to growth of a structured array (direct deposition) or to chemical modifications of the surface (neutral atom lithography). In this report we survey requirements…
A low-temperature hydrothermal reaction has been utilized to generate crystalline barium titanate and strontium titanate nanotubes, which have been characterized by means of X-ray diffraction and transmission electron microscopy, coupled with energy dispersive X-ray analysis.
We have studied the microscopic dynamics of hydrogen adsorbed to bundles of single walled carbon nanotubes using inelastic neutron scattering. Evidence is obtained for much higher storage capacities in chemically treated compared to as prepared material. This indicates an additional adsorption layer inside the tubes.…
Stress transmission in planar open-cell cellular solids is analysed using a recent theory developed for marginally rigid granular assemblies. This is made possible by constructing a one-to-one mapping between the two systems. General trivalent networks are mapped onto assemblies of rough grains, while networks where P…
The full parameter space of the transition from Townsend to glow discharge is investigated numerically in one space dimension in the classical model: with electrons and positive ions drifting in the local electric field, impact ionization by electrons ($α$ process), secondary electron emission from the cathode ($γ$ pr…