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Embden–Meyerhof–Parnas and Entner–Doudoroff pathways in Thermoproteus tenax: metabolic parallelism or specific adaptation?

Hatim Ahmed、Britta Tjaden、Reinhard Hensel 等 4 位作者2004-04-01Biochemical Society Transactions

Genome data as well as biochemical studies have indicated that--as a peculiarity within hyperthermophilic Archaea--Thermoproteus tenax uses three different pathways for glucose metabolism, a variant of the reversible EMP (Embden-Meyerhof-Parnas) pathway and two different modifications of the ED (Entner-Doudoroff) path…

Glycosylation and Glycoproteins ResearchMetabolism and Genetic DisordersEnzyme Structure and Function

Direct observation of the crossover from α-relaxation to Rouse dynamics in a polymer melt

Dieter Richter、M. Monkenbusch、Lutz Willner 等 6 位作者2004-04-01Europhysics Letters (EPL)

In this letter we report a large experimental effort exploring the dynamics of poly(vinyl ethylene) on length scales covering Rouse dynamics and below. The results establish the simultaneous existence of a generic sublinear diffusion regime which underlies the α-process in addition to the Rouse process. Both regimes a…

Polymer crystallization and propertiesMaterial Dynamics and PropertiesRheology and Fluid Dynamics Studies

Corrosion Protection by Electropolymerised and Polymer Pigmented Coatings - A Review

S. Sathiyanarayanan、S. Muralidharan、G. Venkatachari 等 4 位作者2004-04-01Corrosion Reviews

The aqueous electropolymerisation process can be used for the production of primer coatings on metals. Recent studies have shown that such types of coatings are highly corrosion resistant. Further it is also shown that electropolymerisation coating with pigment is feasible. Besides, the use of polymers such as polyani…

Advanced Sensor and Energy Harvesting MaterialsConducting polymers and applicationsAnalytical Chemistry and Sensors

Synergistic effects of carbon fillers on tensile and impact properties in nylon 6,6 and polycarbonate based resins

Jeremiah P. Konell、Julia A. King、İ. Miskioğlu2004-04-01Polymer Composites

Abstract Electrically and thermally conductive resins can be produced by adding conductive fillers to insulating polymers. Mechanical properties such as tensile modulus, ultimate tensile strength, strain at ultimate tensile strength, and notched Izod impact strength are also important and cannot be ignored. This resea…

Mechanical Behavior of CompositesPolymer crystallization and propertiesFiber-reinforced polymer composites

Formation of a fibrillar morphology of crosslinked epoxy in a polystyrene continuous phase by reactive extrusion

Françoise Fenouillot、Hervé Perier‐Camby2004-04-01Polymer Engineering and Science

Abstract An immiscible polymer blend where the dispersed phase is fibrillar was prepared by in situ crosslinking of the minor phase. A model polystyrene/epoxy‐amine blend was selected on the basis of rheological (achievement of the fibrillar structure) and reactivity (fast crosslinking) criteria. The system was a poly…

Polymer crystallization and propertiesPolymer composites and self-healingEpoxy Resin Curing Processes

Diamond-to-graphite conversion in nanodiamond and the electronic properties of nanodiamond-derived carbon system

Toshiaki Enoki2004-04-01Physics of the Solid State

Heat-treatment-induced conversion of nanodiamond to nanographite is investigated. Graphitization starts at the surface region around a heat-treatment temperature of 900°C, then it proceeds inward in the particle, and finally it is completed around 1600°C, where nanographite particles form a polyhedron with a hollow in…

Carbon Nanotubes in CompositesGraphene research and applicationsDiamond and Carbon-based Materials Research

Colloidal silver as an antimicrobial agent: fact or fiction?

van Hasselt P.、Gashe B.A.、Javed Ahmad2004-04-01Journal of Wound Care

OBJECTIVE: Colloidal silver preparations are marketed on the internet as omnipotent antimicrobial agents, but scientific support for these claims is lacking. This study reports the results of in vitro tests of colloidal silver's antimicrobial activity against several pathogenic or non-pathogenic microorganisms. METHOD…

Nanoparticles: synthesis and applicationsGold and Silver Nanoparticles Synthesis and ApplicationsContact Dermatitis and Allergies

Tetrakis(diethyl‐phosphonat)‐, Tetrakis(ethyl‐phenylphosphinat)‐ und Tetrakis(diphenylphosphin‐oxid)‐substituierte Phthalocyanine

Gottfried Märkl、Karl Gschwendner、Ingrid Rötzer 等 4 位作者2004-04-01Helvetica Chimica Acta

Abstract Tetrakis(diethyl phosphonate), Tetrakis(ethyl phenylphosphinate)‐, and Tetrakis(diphenylphosphine oxide)‐Substituted Phthalocyanines The title compounds 7, 9 , and 11 are obtained by tetramerization of diethyl (3,4‐dicyanophenyl)phosphonate ( 5 ), ethyl (3,4‐dicyanophenyl)phenylphosphinate ( 8 ), and 4‐(diphe…

Metal complexes synthesis and propertiesMolecular Sensors and Ion DetectionPorphyrin and Phthalocyanine Chemistry

Poly(styrene sulfonate) self‐organization: electrostatic and secondary interactions

H. Ahrens、Klaus Büscher、Dirk van Eck 等 9 位作者2004-04-01Macromolecular Symposia

Abstract We investigate the self‐organization of PSS in brushes and polyelectrolyte multilayers with X‐ray, neutron and optical reflectivity. The electrostatic force dominates brush phases and adsorption behavior, additionally we find evidence of a strong hydrophobic force: (ι) within amphiphilic diblock copolymer mon…

Polymer Surface Interaction StudiesMolecular Junctions and NanostructuresForce Microscopy Techniques and Applications

Metastable Crystal Structure of Strontium‐ and Magnesium‐Substituted LaGaO 3

Michael Rozumek、Peter Majewski、Fritz Aldinger2004-04-01Journal of the American Ceramic Society

The metastable crystal structure of strontium‐ and magnesium‐substituted LaGaO 3 (LSGM) was studied at room and intermediate temperatures using powder X‐ray diffractometry and Rietveld refinement analysis. With increased strontium and magnesium content, phase transitions were found to occur from orthorhombic (space gr…

Advancements in Solid Oxide Fuel CellsMagnetic and transport properties of perovskites and related materialsElectronic and Structural Properties of Oxides

Neutron and Gamma Ray Source Evaluation of LWR High Burn-up UO2and MOX Spent Fuels

Akihiro Sasahara、Tetsuo Matsumura、G. Nicolaou 等 4 位作者2004-04-01Journal of Nuclear Science and Technology

The axial neutron emission and gamma ray source distribution were measured for LWR high burn-up UO2 and MOX spent fuel rods. The gamma rays of 134Cs, 137Cs and 106Ru were measured on the fuel rods, and consequently compared with the results of the ORIGEN2/82 calculation, in which both the original library and ORLIBJ32…

Nuclear reactor physics and engineeringNuclear Materials and PropertiesNuclear and radioactivity studies

The Ordering of HDTMA in the Interlayers of Vermiculite and the Influence of Solvents

P. G. Slade、Will P. Gates2004-04-01Clays and Clay Minerals

Abstract X-ray basal reflections of several HDTMA-vermiculites show that when these contain co-adsorbed molecules of HDTMA-Br, their interlayer spacings are ∼29.5 Å. After HDTMA-Br has been leached out with ethanol, spacings decrease to ∼26 Å, but when exposed to toluene vapor the spacings increase to ∼36 Å, and to ∼4…

Concrete and Cement Materials ResearchSoil and Unsaturated FlowClay minerals and soil interactions

Aggregation of Thionine within AlMCM-48

Wei Xu、Metin Aydın、Sheuli Zakia 等 4 位作者2004-04-01The Journal of Physical Chemistry B

We report the formation of aggregated thionine molecules encapsulated within an Al-containing mesoporous molecular sieve material (specifically, AlMCM-48) that possesses a cubic pore structure. XRD, UV−vis absorption, fluorescence, and Raman measurements were used, where appropriate, as spectroscopic tools to characte…

Mesoporous Materials and CatalysisPorphyrin and Phthalocyanine ChemistryCovalent Organic Framework Applications

Comparative Physico-chemical and in Vitro Properties of Fibrillated Collagen Scaffolds from Different Sources

Shanmugasundaram Natesan、T. Ravikumar、Mary Babu2004-04-01Journal of Biomaterials Applications

Collagen from different sources was isolated and designed as scaffolds to act as a three-dimensional substrate for culturing human skin fibroblasts, which can be used as dermal substitutes. The thermodynamic behavior of the scaffolds developed was analyzed through Differential Scanning Calorimetric (DSC) and Thermogra…

Bone Tissue Engineering MaterialsSilk-based biomaterials and applicationsCollagen: Extraction and Characterization

Preparation and Combustion Properties of Flame Retardant Styrene‐Butyl Acrylate Copolymer/Graphite Oxide Nanocomposites

Rui Zhang、Yuan Hu、Jiayan Xu 等 6 位作者2004-04-01Macromolecular Materials and Engineering

Abstract Summary: Styrene‐butyl acrylate copolymer (St‐BA)/graphite oxide (GO) nanocomposites and St‐BA/GO/MPP [melamine poly(metaphosphate)] composites were prepared via an intercalation process by the ball‐milling method and characterized by X‐ray diffraction (XRD), transmission electron microscopy (TEM), and field…

Polymer Nanocomposites and PropertiesFire dynamics and safety researchFlame retardant materials and properties

Analysis of the Information Structure of Protein Sequences: A New Method for Analyzing the Domain Organization of Proteins

A. N. Nekrasov2004-04-01Journal of Biomolecular Structure and Dynamics

The amino acid sequences of gamma-crystallin, Haloalkane Dehalogenase, Phthalate Dioxygenase, Porphobilinogen Deaminase and Myosin Regulatory Domain c-chain were analyzed for their information content. Sites of increased degree of information coordination between residues (IDIC-sites) were identified, and their organi…

Protein Structure and DynamicsComputational Drug Discovery MethodsEnzyme Structure and Function

Built‐in Nanostructures in Transparent Oxides for Novel Photonic and Electronic Functions Materials

Hideo Hosono2004-04-01International Journal of Applied Ceramic Technology

We review distinct photonic/electronic properties originating from built‐in nanostructures in transparent oxide‐based materials, emphasizing potential of nanostructures hidden in crystal structure. Materials focused on are oxychalcogenides LaCuOCh (Ch = chalcogen ion) and homologous oxides InGaO 3 (ZnO) m (m = integer…

ZnO doping and propertiesCopper-based nanomaterials and applicationsElectronic and Structural Properties of Oxides

Pathway‐Dependent Melting in a Low‐Molecular‐Weight Polyethylene‐block‐Poly(ethylene oxide) Diblock Copolymer

Lu Sun、Yuxiu Liu、Lei Zhu 等 5 位作者2004-04-01Macromolecular Rapid Communications

Abstract Summary: In a low‐molecular‐weight polyethylene‐ block ‐poly(ethylene oxide) (PE‐ b ‐PEO) diblock copolymer, two pathway‐dependent melting processes were observed: Upon slow heating, the PE lamellar crystals melted at ≈97 °C into a disordered state. However, when the temperature rapidly jumped to above the me…

Polymer crystallization and propertiesRheology and Fluid Dynamics StudiesBlock Copolymer Self-Assembly

Proposal for a New Ferroelectric Gate Field Effect Transistor Memory Based on Ferroelectric-Insulator Interface Conduction

Gen Hirooka、Minoru Noda、Masanori Okuyama2004-04-01Japanese Journal of Applied Physics

A new type of ferroelectric gate field effect transistor (FET) using ferroelectric-insulator interface conduction has been proposed. Drain current flows along the interface between the ferroelectric and insulator layers and needs no semiconductor. The FET has been fabricated by forming drain and source electrodes on a…

Ferroelectric and Piezoelectric MaterialsAcoustic Wave Resonator TechnologiesFerroelectric and Negative Capacitance Devices

Local Change of Carbon Nanotube-Metal Contacts by Current Flow through Electrodes

Hideyuki Maki、Masaki Suzuki、Koji Ishibashi2004-04-01Japanese Journal of Applied Physics

The new processes of current flow through electrodes at carbon nanotube (CNT)-electrode junctions were carried out to change the contact resistance of CNT conductors and the tunnel barriers of CNT quantum dots. When the current flow process was applied to CNT conductors with the Au/Ti electrodes deposited on multiwall…

Carbon Nanotubes in CompositesGraphene research and applicationsNanopore and Nanochannel Transport Studies