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Hierarchical assembly of Ti(iv)/Sn(ii) co-doped SnO2 nanosheets along sacrificial titanate nanowires: synthesis, characterization and electrochemical properties

Hongkang Wang、Liujiang Xi、Jiří Tuček 等 9 位作者2013-01-01Nanoscale

Hierarchical assembly of Ti(IV)/Sn(II)-doped SnO₂ nanosheets along titanate nanowires serving as both sacrificial templates and a Ti(IV) source is demonstrated, using SnCl2 as a tin precursor and Sn(II) dopants and NaF as the morphology controlling agent. Excess fluoride inhibits the hydrolysis of SnCl2, promoting het…

ZnO doping and propertiesGas Sensing Nanomaterials and SensorsTransition Metal Oxide Nanomaterials

Indacenodithieno[3,2-b]thiophene-based broad bandgap polymers for high efficiency polymer solar cells

Yun‐Xiang Xu、Chu-Chen Chueh、Hin‐Lap Yip 等 8 位作者2013-01-01Polymer Chemistry

Two broad bandgap polymers, poly{(indacenodithieno[3,2-b]thiophene)-alt-[2,5-bis(thiophen-2-yl)thiazolo[5,4-d]thiazole-5,5′-diyl]} PIDTT-TzTz and poly{(indacenodithieno[3,2-b]thiophene)-alt-[2,5-bis(6-octylthieno[3,2-b]thiophen-2-yl)thiazolo[5,4-d]thiazole-5,5′-diyl]} PIDTT-TzTz-TT, were designed and synthesized by co…

Organic Electronics and PhotovoltaicsConducting polymers and applicationsNanowire Synthesis and Applications

Assessment of Antioxidant and Cytotoxicity Activities of Saponin and Crude Extracts of Chlorophytum borivilianum

Mehdi Farshad Ashraf、Maheran Abd Aziz、Johnson Stanslas 等 5 位作者2013-01-01The Scientific World JOURNAL

The present paper focused on antioxidant and cytotoxicity assessment of crude and total saponin fraction of Chlorophytum borivilianum as an important medicinal plant. In this study, three different antioxidant activities (2,2-diphenyl-1-picrylhydrazyl radical scavenging (DPPH), ferrous ion chelating (FIC), and β -caro…

Natural product bioactivities and synthesisPhytochemistry and Biological ActivitiesPhytochemistry and Bioactive Compounds

A (3,14)-connected three-dimensional metal–organic framework based on the unprecedented enneanuclear copper(ii) cluster [Cu9(μ3-OH)4(μ2-OH)2]

Xia Zhu、Shan Zhao、Yanfen Peng 等 5 位作者2013-01-01CrystEngComm

A hydrothermal reaction of Cu(NO3)2, 1,2-bis(1,2,4-triazol-1-yl)ethane (bte) and 5-sulfoisophthalate (sip) yields an interesting three-dimensional metal–organic framework {[Cu9(OH)6(bte)2(sip)4(H2O)3]·6H2O}n (1). A single-crystal analysis revealed that compound 1 consists of a (3,14)-connected three-dimensional MOF wi…

Metal-Organic Frameworks: Synthesis and ApplicationsMetal complexes synthesis and propertiesMagnetism in coordination complexes

Electroactive Performances of Conductive Polythiophene/hydrogel Hybrid Artificial Muscle

Datchanee Pattavarakorn、Pornpun Youngta、Sutawan Jaesrichai 等 5 位作者2013-01-01Energy Procedia

The conductive polythiophene/chitosan/carboxymethylchitosan (PTH/CS/CMCS) hydrogel were prepared in this study. Polythiophene was synthesized via oxidative polymerization in chloroform at 40 °C. For CMCS synthesis, CS was alkalized with sodium hydroxide in isopropanol and then reacted with monochloroacetic acid at 50…

Advanced Sensor and Energy Harvesting MaterialsConducting polymers and applicationsDielectric materials and actuators

Interaction of Green Polymer Blend of Modified Sodium Alginate and Carboxylmethyl Cellulose Encapsulation of Turmeric Extract

Sa‐Ad Riyajan、Janthanipa Nuim2013-01-01International Journal of Polymer Science

Turmeric extract (tmr) loaded nanoparticles were prepared by crosslinking modified carboxylmethyl cellulose (CMC) and modified sodium alginate (SA) with calcium ions, in a high pressure homogenizer. The FTIR spectra of CMC and SA were affected by blending due to hydrogen bonding. The negative zeta potential increased…

Nanoparticle-Based Drug Deliverybiodegradable polymer synthesis and propertiesCurcumin's Biomedical Applications

Synthesis of Single-Phase LiSi by Ball-Milling: Electrochemical Behavior and Hydrogenation Properties

Wan Si Tang、Jean‐Noël Chotard、Raphaël Janot2013-01-01Journal of The Electrochemical Society

The Li-Si phase diagram shows the existence of four stable phases [Li 12 Si 7 , Li 7 Si 3 , Li 13 Si 4 and Li 22 Si 5 ]. In addition, Zintl phase LiSi, usually prepared under high temperature-pressure (873 K-4 GPa), has recently been added into the diagram as LiSi is also indeed stable under ambient conditions. A nove…

Advancements in Battery MaterialsGraphene research and applicationsSemiconductor materials and interfaces

Influence of Chemical Composition and Heat Treatment on Long-term Creep Strength of Grade 91 Steel

Kazuhiro Kimura、Kota Sawada、Hideaki Kushima 等 4 位作者2013-01-01Procedia Engineering

Long-term creep strength of ASTM/ASME Grade 91 steels was investigated. Two heats of Grade 91 steels indicated lower creep rupture strength than the other four heats from short-term to long-term, and presence of delta ferrite phase was observed. In the short-term, no difference in creep rupture strength was observed a…

High Temperature Alloys and CreepNuclear Materials and PropertiesFire effects on concrete materials

Mechanical properties of porous titanium with different distributions of pore size

Xiaohua、Wang、Jinshan 等 10 位作者2013-01-01Acta Scientiarum Naturalium Universitatis Sunyatseni

为了满足多孔的骨头代用品,的机械、生物的要求,有预先设计的二种不同毛孔尺寸的多孔的 Ti 被空间持有者 sintering 过程制作。多孔的 Ti 的机械性质经由房间温度 compressive~tests 被探索。毛孔尺寸和形状在整个标本是一致的,孔从 36% ~ 63%。压缩力量和有弹性的模量分别地在从 94.05 ~ 468.57 MPa 和 2.662 ~ 18 GPa 的范围。在压缩力量和孔之间的关系是在机械性质上的毛孔尺寸分布的效果以外的完全线性的关系,是值得注意的。从 Gibson-Ashby 模型完成的经常的 C 的价值建议毛孔尺寸影响多孔的 Ti 的收益力量和密度代表(n)的价值因为有二种不同毛孔尺寸的多孔的 T…

Bone Tissue Engineering MaterialsCellular and Composite StructuresTitanium Alloys Microstructure and Properties

Dynamics, crystallization and structures in colloid spin \ncoating

M. (Moorthi) Pichumani、P. (P.) Bagheri、K.M. (Kristin M.) Poduska 等 5 位作者2013-01-01Memorial University Research Repository (Memorial University)

Spin coating is an out-of-equilibrium technique for producing polymer films and colloidal crystals quickly and reproducibly. In this review, we present an overview of theoretical and experimental studies of the spin coating of colloidal suspensions. The dynamics of the spin coating process is discussed first, and we p…

Liquid Crystal Research AdvancementsTheoretical and Computational PhysicsPhotonic Crystals and Applications

1,1-Bis[(di-4-tolylamino)phenyl]cyclohexane for fast response organic photodetectors with high external efficiency and low leakage current

Dezhi Yang、Dongge Ma2013-01-01Journal of Materials Chemistry C

Fast response organic photodetectors were developed based on a high mobility hole-transporting organic semiconductor 1,1-bis[(di-4-tolylamino)phenyl]cyclohexane (TAPC). The active layer was constructed by mixing TAPC with a high electron mobility C70 and sandwiched between TAPC and C70. This kind of planar-mixed heter…

Organic Electronics and PhotovoltaicsOrganic Light-Emitting Diodes ResearchConducting polymers and applications

Chromenoquinoline-based thiol probes: a study on the quencher position for controlling fluorescent Off–On characteristics

Dnyaneshwar Kand、Arunasree M. Kalle、Pinaki Talukdar2013-01-01Organic & Biomolecular Chemistry

The design, synthesis and thiol sensing ability of chromenoquinoline-based fluorescent probes 4, 5 and 6 and are reported here. The relative position of the maleimide moiety was varied along the chromenoquinoline fluorophore to decrease the background fluorescence. Lower background fluorescence in probes 4 and 6 was r…

Molecular Sensors and Ion DetectionLuminescence and Fluorescent MaterialsSulfur Compounds in Biology

Ti2S@D3h(24109)-C78: a sulfide cluster metallofullerene containing only transition metals inside the cage

Fangfang Li、Ning Chen、Marc Mulet-Gas 等 8 位作者2013-01-01Chemical Science

A new titanium-based sulfide clusterfullerene, Ti2S@D3h(24109)-C78, has been successfully synthesized by arc-discharging graphite rods packed with pure TiO2 and graphite powder under an atmosphere of SO2 and helium. Multistage HPLC methods were utilized to isolate and purify the Ti2S@C78, and mass spectrometric charac…

Graphene research and applicationsFullerene Chemistry and ApplicationsBoron and Carbon Nanomaterials Research

Gas-assisted growth of boron-doped nickel nanotube arrays: rapid synthesis, growth mechanisms, tunable magnetic properties, and super-efficient reduction of 4-nitrophenol

Xiangzi Li、Konglin Wu、Yin Ye 等 4 位作者2013-01-01Nanoscale

Highly ordered noncrystalline boron-doped nickel nanotube arrays are rapidly synthesized within 150 s by template-based electroless deposition. The as-prepared nanotubes have tunable magnetic properties and exhibit super efficient catalytic activity (∼70 s) for the reduction of 4-nitrophenol.

Copper-based nanomaterials and applicationsMXene and MAX Phase MaterialsNanomaterials for catalytic reactions

A novel biomass-based support (Starbon) for TiO 2 hybrid photocatalysts: a versatile green tool for water purification

Juan Carlos Colmenares、Paweł Lisowski、Dariusz Łomot2013-01-01RSC Advances

Novel carbonaceous support (Starbon) for TiO 2 photocatalysts synthesized by a simple ultrasound-assisted impregnation technique. High phenol photo-oxidation rate to complete mineralization. Renewable materials for a straightforward photocatalysts synthesis.

TiO2 Photocatalysis and Solar CellsAdvanced Photocatalysis TechniquesAdvanced Nanomaterials in Catalysis

Reduction-free synthesis of stable acetylide cobalamins

Mikołaj Chromiński、Agnieszka Lewalska、Dorota Gryko2013-01-01Chemical Communications

A straightforward, reduction-free method for the synthesis of organometallic cobalamins has been developed. Stable phenylacetylide derivatives were characterized by X-ray analysis, showing a pronounced influence of the electronic nature of substituents on their structure.

Porphyrin and Phthalocyanine ChemistryCO2 Reduction Techniques and CatalystsPorphyrin Metabolism and Disorders

Aptamer-functionalized silver nanoclusters-mediated cell type-specific siRNA delivery and tracking

Jingjing Li、Wenjing Wang、Defang Sun 等 8 位作者2013-01-01Chemical Science

The use of small interfering RNA (siRNA) to silence target genes involved in disease has generated much excitement in the scientific community. While promising, the clinical application of RNA interference (RNAi) is still challenging in achieving effective delivery and tracking of siRNA to target cells. A new multifun…

Advanced biosensing and bioanalysis techniquesRNA Interference and Gene DeliveryNanocluster Synthesis and Applications

In situ XRD studies of nanocrystallization of Fe-based metallic glass: a comparative study by reciprocal and direct space methods

Jozef Bednarčík、Š. Michalik、Vladimír Kolesár 等 5 位作者2013-01-01Physical Chemistry Chemical Physics

Structural changes occurring in an Fe(72.5)Cu1Nb2Mo2Si(15.5)B7 alloy during a combination of constant rate heating (20 K min(-1)) and isothermal holding at 500 and 520 °C were investigated using in situ high-energy X-ray diffraction. We found that the ferromagnetic-to-paramagnetic transition of the amorphous phase is…

Metallic Glasses and Amorphous AlloysPhase-change materials and chalcogenidesX-ray Spectroscopy and Fluorescence Analysis

Inorganic material surfaces made bioactive by immobilizing growth factors for hard tissue engineering

Di Zhou、Yoshihiro Ito2013-01-01RSC Advances

Medical and dental titanium has become the fundamental material in clinical use, in applications from surgical instruments and orthopedic rods to pins and plates. Besides titanium, various inorganic materials have been used in tissue engineering because of their unique mechanical properties. However, inorganic materia…

Bone Tissue Engineering MaterialsElectrospun Nanofibers in Biomedical ApplicationsPolymer Surface Interaction Studies

Fabrication of Ag3PO4–PAN composite nanofibers for photocatalytic applications

Hongchao Yu、Zhengbo Jiao、Hongyan Hu 等 6 位作者2013-01-01CrystEngComm

Necklace-like Ag3PO4–polyacrylonitrile (PAN) hetero-nanofibers have been successfully fabricated through a simple and facile electrospinning technique and exhibit excellent photocatalytic activities for the degradation of organic contaminants under visible light irradiation.

Advanced Photocatalysis TechniquesCopper-based nanomaterials and applicationsCovalent Organic Framework Applications