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Capillary Break-up Rheometry of Low-Viscosity Elastic Fluids
We investigate the dynamics of the capillary thinning and break-up process for low viscosity elastic fluids such as dilute polymer solutions. Standard measurements of the evolution of the midpoint diameter of the necking fluid filament are augmented by high speed digital video images of the break up dynamics. We show…
39th Meeting of the French Rheology Group (GFR)
Prof. Pierre J. Carreau 65th Birthday Symposium
Rheology and Microstructure of Complex Fluid Systems Symposium in Honour of Prof. Jan Mewis
Influence of the Molar Mass Distribution on the Elongational Behaviour of Polymer Solutions in Capillary Breakup
Commercially available, blended methylhydroxyethyl celluloses with similar weight-average molar masses but varying molar mass distributions were characterized by different techniques like steady shear flow and uniaxial elongation in capillary breakup experiments. The determined relaxation times t were then correlated…
Handbook of Ellipsometry
Patents
Characteristic Times of Microsturcture Formation in Electrorheological Fluids, Determined by Viscosity and Speckle Activity Measurements
Viscosity measurements of a suspension of cornstarch in silicone oil, at several concentrations and subject to different electrical field strengths, were conducted. An increase in the apparent viscosity, in correlation with the field strength, which is characteristic of the so-called electrorheological fluids (ERF), w…
Metallodendritic Catalysis for Redox and CarbonCarbon Bond Formation Reactions: A Step towards Green Chemistry.
Abstract Metallodendritic catalysts combine the advantages of homogeneous and heterogeneous catalysts: they are soluble and perfectly well defined on the molecular level, and yet they can be recovered by precipitation, ultra‐filtration or ultra‐centrifugation (as biomolecules) and recycled several times. In this artic…
On the effect of dose rate on irradiation hardening of RPV steels
The effect of dose rate (DR), or neutron flux (ϕ), on irradiation hardening (Δσy) and embrittlement of reactor pressure vessel (RPV) steels is a key unresolved issue. We report a rigorous evaluation of DR effects based on a very large Δσy database we developed for RPV steels with a wide range of compositions, includin…
Photon correlation studies of single GaN quantum dots
We present measurements of the second-order coherence function on emission from single GaN quantum dots. In some cases a large degree of photon antibunching is observed, demonstrating isolation of a single quantum system. For a selected quantum dot, we study the dependence of photon antibunching on excitation power an…
Direct Observation of the Growth Process of MgO Nanoflowers by a Simple Chemical Route
Novel flowerlike nanostructures consisting of MgO nanofibers were successfully synthesized by a simple chemical route with H(2)O at 950 degrees C in an Ar atmosphere. Various durations of heating gave different growth stages that led to varied product morphologies. The synthesized products were systematically studied…
Microstructural Characterization of SCC Crack Tip and Oxide Film for SUS 316 Stainless Steel in Simulated PWR Primary Water at 320°C
Recent studies on stress corrosion cracking (SCC) behaviors of austenitic stainless steels in hydrogenated high-temperature water show that low potential SCC (LPSCC) can occur on cold-worked SUS 316 stainless steel (hereinafter, 316SS). In this study, oxide films and crack tips on cold-worked 316SS exposed to hydrogen…
Advancing controlled release packaging through smart blending
Abstract Researchers from Rutgers University and Clemson University have collaborated to develop a concept of using smart blending to generate functional packaging films for the controlled release of active compounds such as antimicrobials, antioxidants and flavour compounds to extend the shelf‐life of food. In this p…
The effect of material parameter values on the relation between the energy gap width and the scatterer symmetry in two-dimensional phononic crystals
The phononic band structures of two-dimensional solid phononic crystals with different lattice and scatterer symmetry are studied numerically, with three types of lattice (square, triangular and rectangular) and four different scatterer shapes (circle, hexagon, square and rectangle) considered. XY and $Z$ vibration mo…
Nonsingular stress and strain fields of dislocations and disclinations in first strain gradient elasticity
The aim of this paper is to study the elastic stress and strain fields of dislocations and disclinations in the framework of Mindlin's gradient elasticity. We consider simple but rigorous versions of Mindlin's first gradient elasticity with one material length (gradient coefficient). Using the stress function method,…
Spin gap antiferromagnets: materials and phenomena
There are several interacting spin systems which have a gap in their spin excitation spectrum. The gap does not occur due to anisotropies present in the system but is quantum mechanical in origin. We give a brief overview on the different types of spin gap (SG) antiferromagnets, the models proposed to describe their p…
Radial Anisotropic Growth of Rhodium Nanoparticles
In this contribution, we report the synthesis of rhodium multipods that result from a homogeneous seeded growth mechanism. Small Rh nanocrystal seeds were synthesized by the reduction of RhCl3 in ethylene glycol in the presence of PVP. These seed particles could be subsequently used, without isolation, to form larger…
Resonance Raman spectroscopy(n,m)-dependent effects in small-diameter single-wall carbon nanotubes
This paper presents an accurate analysis of (i) the electronic transition energies ${E}_{22}^{S}$ and ${E}_{11}^{M}$, (ii) the radial breathing mode (RBM) frequencies ${\ensuremath{\omega}}_{\mathrm{RBM}}$, and (iii) the corresponding RBM intensities from 40 small-diameter single-wall carbon nanotubes (SWNTs) in the d…