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Suppression of geminate charge recombination in organic photovoltaic devices with a cascaded energy heterojunction

Chris Groves2013-01-01Energy & Environmental Science

The effect of cascaded energy heterojunctions on geminate charge recombination in organic photovoltaic devices is examined using a kinetic Monte Carlo model. The structure of the cascaded heterojunction, which encourages spatial separation of the geminate charge pair, is varied to recreate that found in ternary blends…

Organic Electronics and PhotovoltaicsThin-Film Transistor TechnologiesConducting polymers and applications

Materials for the Active Layer of Organic Photovoltaics: Ternary Solar Cell Approach

Yung‐Chung Chen、Chih‐Yu Hsu、Ryan Yeh‐Yung Lin 等 5 位作者2013-01-01ChemSusChem

Power conversion efficiencies in excess of 7% have been achieved with bulk heterojunction (BHJ)-type organic solar cells using two components: p- and n-doped materials. The energy level and absorption profile of the active layer can be tuned by introduction of an additional component. Careful design of the additional…

Organic Electronics and PhotovoltaicsQuantum Dots Synthesis And PropertiesConducting polymers and applications

Mechanical depolymerisation of acidulated cellulose: understanding the solubility of high molecular weight oligomers

Abhijit Shrotri、Lynette K. Lambert、Akshat Tanksale 等 4 位作者2013-01-01Green Chemistry

Water soluble oligomers of cellulose were produced by milling acidulated microcrystalline cellulose. Acids with low pKa were found to be more effective for the treatment. The yield of water soluble fraction was proportional to the increasing severity of milling or the acid amount. Soluble oligomers were found to have…

Advanced Cellulose Research StudiesCatalysis for Biomass ConversionLignin and Wood Chemistry

Curcumin-Loaded Chitosan/Gelatin Composite Sponge for Wound Healing Application

Van Cuong Nguyen、Van Cuong Nguyen、Van Boi Nguyen 等 5 位作者2013-01-01International Journal of Polymer Science

Three composite sponges were made with 10% of curcumin and by using polymers, namely, chitosan and gelatin with various ratios. The chemical structure and morphology were evaluated by FTIR and SEM. These sponges were evaluated for water absorption capacity, antibacterial activity,in vitrodrug release, andin vivowound…

Nanocomposite Films for Food PackagingElectrospun Nanofibers in Biomedical ApplicationsWound Healing and Treatments

The influence of shell thickness of Au@TiO2 core–shell nanoparticles on the plasmonic enhancement effect in dye-sensitized solar cells

Weiliang Liu、Fan-Cheng Lin、Yuchen Yang 等 7 位作者2013-01-01Nanoscale

Plasmonic core-shell nanoparticles (PCSNPs) can function as nanoantennas and improve the efficiency of dye-sensitized solar cells (DSSCs). To achieve maximum enhancement, the morphology of PCSNPs needs to be optimized. Here we precisely control the morphology of Au@TiO2 PCSNPs and systematically study its influence on…

TiO2 Photocatalysis and Solar CellsAdvanced Photocatalysis TechniquesCopper-based nanomaterials and applications

Monolithic Integration of InGaN-Based Nanocolumn Light-Emitting Diodes with Different Emission Colors

Katsumi Kishino、Kazuya Nagashima、K. Yamano2013-01-01Applied Physics Express

We demonstrate the monolithic integration of green and orange InGaN-based nanocolumn light-emitting diodes (LEDs). Four nanocolumn LED crystals (LEDs 1 to 4), which consisted of regularly arranged InGaN-based nanocolumns in a triangular lattice of 400 nm lattice constant, were grown on the same GaN template on a (0001…

ZnO doping and propertiesGaN-based semiconductor devices and materialsMetal and Thin Film Mechanics

First Observation of Blending-Zone Morphology at Interface of Reclaimed Asphalt Binder and Virgin Bitumen

Sayeda Nahar、M. Mohajeri、A.J.M. Schmets 等 6 位作者2013-01-01Transportation Research Record Journal of the Transportation Research Board

One of the challenges in designing recycled asphalt mixtures with a high amount of reclaimed asphalt pavement (RAP) is estimating the blending degree between RAP binder and added virgin bitumen. The extent of blending is crucial because asphalt concrete response is influenced by the final binder properties. This paper…

Asphalt Pavement Performance EvaluationCorrosion Behavior and InhibitionPolymer Nanocomposites and Properties

Extremely deep blue and highly efficient non-doped organic light emitting diodes using an asymmetric anthracene derivative with a xylene unit

Ran Kim、Sunghun Lee、Kwon‐Hyeon Kim 等 7 位作者2013-01-01Chemical Communications

A new highly twisted asymmetric anthracene derivative with naphthalene and triphenylamine substituted xylene was synthesized as an extremely deep blue emitting material. A non-doped device using the new asymmetric blue emitter displays a maximum EQE of 4.62% with CIE color coordinates of (0.154, 0.049).

Organic Electronics and PhotovoltaicsOrganic Light-Emitting Diodes ResearchConducting polymers and applications

CuO/PVDF nanocomposite anode for a piezo-driven self-charging lithium battery

Xinyu Xue、Ping Deng、Shuang Yuan 等 7 位作者2013-01-01Energy & Environmental Science

An integrated self-charging power cell (SCPC) is realized from a CuO/PVDF nanocomposite piezo-anode. The efficiency of the integrated SCPC is higher than that of the non-integrated SCPC. The intimate and large contact between CuO and PVDF results in an effective use of the piezoelectric field in the internal piezo-ele…

ZnO doping and propertiesAdvanced Sensor and Energy Harvesting MaterialsConducting polymers and applications

A Statistical Analysis of Optimization of Wear Behaviour of Al- Al2O3 Composites Using Taguchi Technique

A. Baradeswaran、A. Elayaperumal、R. Franklin Issac2013-01-01Procedia Engineering

This work deals with the effect of Al2O3 on wear properties of AA7075 metal matrix composite and the results were optimized by Taguchi technique. The composites were prepared by conventional liquid casting method with varying the Al2O3 content. The wear test was conducted with pin-on-disc apparatus with the controllin…

Advanced ceramic materials synthesisAluminum Alloys Composites PropertiesAdditive Manufacturing and 3D Printing Technologies

Correlating cation ordering and voltage fade in a lithium–manganese-rich lithium-ion battery cathode oxide: a joint magnetic susceptibility and TEM study

Debasish Mohanty、Athena S. Sefat、Jianlin Li 等 9 位作者2013-01-01Physical Chemistry Chemical Physics

Structure-electrochemical property correlation is presented for lithium-manganese-rich layered-layered nickel manganese cobalt oxide (LMR-NMC) having composition Li1.2Co0.1Mn0.55Ni0.15O2 (TODA HE5050) in order to examine the possible reasons for voltage fade during short-to-mid-term electrochemical cycling. The Li1.2C…

Advancements in Battery MaterialsSupercapacitor Materials and FabricationAdvanced Battery Materials and Technologies

SBA-15 confined synthesis of TiNb2O7 nanoparticles for lithium-ion batteries

Ling Fei、Yun Xu、Xiaofei Wu 等 8 位作者2013-01-01Nanoscale

Unlike most conventional anode materials, the newly developed TiNb2O7 (TNO) does not form a solid electrolyte interface (SEI) layer, which makes it safe for high power requiring lithium-ion batteries. In this paper, we demonstrated an SBA-15 confined synthetic approach to prepare TNO nanoparticles (S-TNO) with a small…

Advancements in Battery MaterialsTransition Metal Oxide NanomaterialsMicrowave Dielectric Ceramics Synthesis

A new green, ascorbic acid-assisted method for versatile synthesis of Au–graphene hybrids as efficient surface-enhanced Raman scattering platforms

Maria Iliuţ、Cosmin Leordean、Valentin Canpean 等 5 位作者2013-01-01Journal of Materials Chemistry C

A new green method for the synthesis of reduced graphene oxide–gold nanoparticle (rGO–AuNP) hybrids in aqueous solution that exploits the ability of ascorbic acid (AA) to operate as an effective dual agent for both graphene oxide (GO) and gold ion reduction is reported. Through careful investigation of the production…

Graphene research and applicationsGold and Silver Nanoparticles Synthesis and ApplicationsGraphene and Nanomaterials Applications

Recent progress in organic–inorganic hybrid solar cells

Xia Fan、Mingliang Zhang、Xiaodong Wang 等 5 位作者2013-01-01Journal of Materials Chemistry A

Organic–inorganic hybrid solar cells were expected to adopt the advantages of both organic and inorganic materials. Due to several crucial problems, the power conversion efficiency of most hybrid solar cells was lower than 1%. Recent work reported the highest power conversion efficiency of a hybrid solar cell as 11.3%…

Organic Electronics and PhotovoltaicsPerovskite Materials and ApplicationsConducting polymers and applications

A hierarchical heterostructure based on Pd nanoparticles/layered double hydroxide nanowalls for enhanced ethanol electrooxidation

Jingwen Zhao、Mingfei Shao、Dongpeng Yan 等 11 位作者2013-01-01Journal of Materials Chemistry A

Finely dispersed Pd nanoparticles (PdNPs) anchored to CoAl layered double hydroxide nanowalls (LDH-NWs) have been fabricated via a facile in situ redox reaction between the LDH-NWs and the PdCl42− precursor. The integrated LDH-NWs play the roles of both a hierarchical support and a reductant without any external agent…

Electrocatalysts for Energy ConversionAdvanced battery technologies researchLayered Double Hydroxides Synthesis and Applications

A facile hydrothermal deposition of ZnFe2O4 nanoparticles on TiO2 nanotube arrays for enhanced visible light photocatalytic activity

Mengye Wang、Lan Sun、Jianhuai Cai 等 6 位作者2013-01-01Journal of Materials Chemistry A

ZnFe2O4 coupled TiO2 nanotube arrays (ZnFe2O4–TiO2 NTAs) were synthesized by modifying TiO2 nanotube arrays with ZnFe2O4 nanoparticles. Self-organized TiO2 NTAs with a tube diameter of 100 nm and length of 400 nm were prepared by an electrochemical anodization method. ZnFe2O4 nanoparticles were deposited on the surfac…

TiO2 Photocatalysis and Solar CellsAdvanced Photocatalysis TechniquesQuantum Dots Synthesis And Properties

Transparent, stretchable, carbon-nanotube-inlaid conductors enabled by standard replication technology for capacitive pressure, strain and touch sensors

Xiaolong Wang、Tingjie Li、Jillian Adams 等 4 位作者2013-01-01Journal of Materials Chemistry A

This paper describes a standard replication approach for preparing transparent elastomeric conductors with single-walled carbon nanotubes (SWCNTs) inlaid just below the surface. The elastic conductors were fabricated by spray coating a SWCNT suspension in chloroform on a fluorinated substrate, followed by the standard…

Advanced Sensor and Energy Harvesting MaterialsConducting polymers and applicationsAdvanced Materials and Mechanics

Improving the photoelectrochemical and photocatalytic performance of CdO nanorods with CdS decoration

Wei Li、Mingyang Li、Shilei Xie 等 10 位作者2013-01-01CrystEngComm

Herein, we report an effective and simple strategy to greatly improve the photoactivity of CdO nanorods (NRs) by decorating them with CdS. The CdO–CdS heterostructured NRs grown on a FTO substrate exhibited substantially higher visible-light-driven photoactivity for a PEC cell and the degradation of methylene blue (MB…

Advanced Photocatalysis TechniquesQuantum Dots Synthesis And PropertiesCopper-based nanomaterials and applications

Thermal stability of high concentration lysozyme across varying pH: A Fourier Transform Infrared study

Sathyadevi Venkataramani、Jeremy Truntzer、DenisR Coleman2013-01-01Journal of Pharmacy And Bioallied Sciences

AIM: The current work is aimed at understanding the effect of pH on the thermal stability of hen egg white lysozyme (HEWL) at high concentration (200 mg/mL). MATERIALS AND METHODS: Fourier Transform Infrared (FTIR) Spectroscopy with modified hardware and software to overcome some of the traditional challenges like wat…

Enzyme Catalysis and ImmobilizationEnzyme Structure and FunctionProtein Interaction Studies and Fluorescence Analysis

The role of yttrium content in improving electrochemical performance of layered lithium-rich cathode materials for Li-ion batteries

Ning Li、Ran An、Yuefeng Su 等 9 位作者2013-01-01Journal of Materials Chemistry A

The promising layered lithium-rich cathode materials, Li1.2Mn0.6−xNi0.2YxO2 (0 ≤ x ≤ 0.05), have been synthesized by substituting Mn4+ in Li1.2Mn0.6Ni0.2O2 with unusually large Y3+ ions, in order to improve their cycling performance and rate capability. An oxalate co-precipitation method is adopted in the synthetic pr…

Advancements in Battery MaterialsSupercapacitor Materials and FabricationAdvanced Battery Materials and Technologies