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Lanthanide-doped luminescent nanoprobes: controlled synthesis, optical spectroscopy, and bioapplications

Yongsheng Liu、Datao Tu、Haomiao Zhu 等 4 位作者2013-01-01Chemical Society Reviews

Lanthanide-doped inorganic nanoparticles possess superior physicochemical features such as long-lived luminescence, large antenna-generated Stokes or anti-Stokes shifts, narrow emission bands, high resistance to photobleaching and low toxicity, and thus are regarded as a new generation of luminescent bioprobes as comp…

Luminescence Properties of Advanced MaterialsNanoplatforms for cancer theranosticsLanthanide and Transition Metal Complexes

Highly active and durable nanostructured molybdenum carbide electrocatalysts for hydrogen production

Wei‐Fu Chen、Chen‐Hao Wang、Kotaro Sasaki 等 8 位作者2013-01-01Energy & Environmental Science

In an attempt to tailor low-cost, precious-metal-free electrocatalysts for water electrolysis in acid, molybdenum carbide (β-Mo2C) nanoparticles are prepared by in situ carburization of ammonium molybdate on carbon nanotubes and XC-72R carbon black without using any gaseous carbon source. The formation of Mo2C is inve…

Electrocatalysts for Energy ConversionCatalysis and Hydrodesulfurization StudiesMXene and MAX Phase Materials

Metal–organic frameworks as platforms for clean energy

Shun-Li Li、Qiang Xü2013-01-01Energy & Environmental Science

In order to void environmental pollution and an energy shortage, the application of clean and renewable energy, such as solar, instead of fossil fuel is foreseen as a prospective issue. It is urgent and important to develop and optimize various energy storage and conversion technologies and materials aimed at utilizat…

Metal-Organic Frameworks: Synthesis and ApplicationsSupercapacitor Materials and FabricationMXene and MAX Phase Materials

Engineering metal-based luminescence in coordination polymers and metal–organic frameworks

Johanna Heine、Klaus Müller‐Buschbaum2013-01-01Chemical Society Reviews

The rapidly growing number of luminescent coordination polymers (CPs) and metal-organic frameworks (MOFs) illustrates high interest as well as accessibility of such materials. The interplay between inorganic and organic components in these materials offers a large number of viable luminescence processes. The enormous…

Metal-Organic Frameworks: Synthesis and ApplicationsMagnetism in coordination complexesLanthanide and Transition Metal Complexes

Update on Na-based battery materials. A growing research path

Verónica Palomares、Montse Casas‐Cabanas、Elizabeth Castillo‐Martínez 等 5 位作者2013-01-01Energy & Environmental Science

This work presents an up-to-date information on Na-based battery materials. On the one hand, it explores the feasibility of two novel energy storage systems: Na-aqueous batteries and Na–O2 technology. On the other hand, it summarises new advances on non-aqueous Na-ion systems. Although all of them can be placed under…

Advancements in Battery MaterialsAdvanced Battery Materials and TechnologiesThermal Expansion and Ionic Conductivity

Metallic anodes for next generation secondary batteries

Hansu Kim、Goojin Jeong、Young-Ugk Kim 等 6 位作者2013-01-01Chemical Society Reviews

Li-air(O2) and Li-S batteries have gained much attention recently and most relevant research has aimed to improve the electrochemical performance of air(O2) or sulfur cathode materials. However, many technical problems associated with the Li metal anode have yet to be overcome. This review mainly focuses on the electr…

Advancements in Battery MaterialsAdvanced Battery Materials and TechnologiesThermal Expansion and Ionic Conductivity

Gamma-valerolactone, a sustainable platform molecule derived from lignocellulosic biomass

David Martín Alonso、Stephanie G. Wettstein、James A. Dumesic2013-01-01Green Chemistry

Lignocellulosic biomass typically contains more than 50 wt% sugars that can be upgraded to valuable platform molecules, such as levulinic acid (LA) and gamma-valerolactone (GVL). This article focuses on upgrading GVL produced from lignocellulosic biomass to various chemicals and fuels, such as polymers, fuel additives…

Biofuel production and bioconversionSupercapacitor Materials and FabricationCatalysis for Biomass Conversion

Arylamine organic dyes for dye-sensitized solar cells

Mao Liang、Jun Chen2013-01-01Chemical Society Reviews

Arylamine organic dyes with donor (D), π-bridge (π) and acceptor (A) moieties for dye-sensitized solar cells (DSCs) have received great attention in the last decade because of their high molar absorption coefficient, low cost and structural variety. In the early stages, the efficiency of DSCs with arylamine organic dy…

TiO2 Photocatalysis and Solar CellsAdvanced Photocatalysis TechniquesQuantum Dots Synthesis And Properties

Visible light driven type II heterostructures and their enhanced photocatalysis properties: a review

Yajun Wang、Qisheng Wang、Xueying Zhan 等 6 位作者2013-01-01Nanoscale

Considerable efforts have been devoted to enhancing the photocatalytic activity and solar energy utilization of photocatalysts. The fabrication of type II heterostructures plays an important role in photocatalysts modification and has been extensively studied. In this review, we briefly trace the application of type I…

TiO2 Photocatalysis and Solar CellsAdvanced Photocatalysis TechniquesQuantum Dots Synthesis And Properties

Recent developments in transition metal carbides and nitrides as hydrogen evolution electrocatalysts

Wei‐Fu Chen、James T. Muckerman、Etsuko Fujita2013-01-01Chemical Communications

The production of hydrogen by the electrolysis of water, a sustainable and greenhouse-gas-free source, requires an efficient and abundant electrocatalyst that minimizes energy consumption. Interest in transition metal carbides and nitrides has been aroused by their promising properties that make them potential substit…

Electrocatalysts for Energy ConversionFuel Cells and Related MaterialsMXene and MAX Phase Materials

A review of fabrication and applications of carbon nanotube film-based flexible electronics

Steve Park、Michael Vosguerichian、Zhenan Bao2013-01-01Nanoscale

Flexible electronics offer a wide-variety of applications such as flexible circuits, flexible displays, flexible solar cells, skin-like pressure sensors, and conformable RFID tags. Carbon nanotubes (CNTs) are a promising material for flexible electronics, both as the channel material in field-effect transistors (FETs)…

Carbon Nanotubes in CompositesAdvanced Sensor and Energy Harvesting MaterialsNeuroscience and Neural Engineering

Hallmarks of mechanochemistry: from nanoparticles to technology

Peter Baláž、Marcela Achimovičová、Matěj Baláž 等 16 位作者2013-01-01Chemical Society Reviews

The aim of this review article on recent developments of mechanochemistry (nowadays established as a part of chemistry) is to provide a comprehensive overview of advances achieved in the field of atomistic processes, phase transformations, simple and multicomponent nanosystems and peculiarities of mechanochemical reac…

Advanced materials and compositesnanoparticles nucleation surface interactionsX-ray Diffraction in Crystallography

Chemical exfoliation of graphitic carbon nitride for efficient heterogeneous photocatalysis

Jing Xu、Liwu Zhang、Rui Shi 等 4 位作者2013-01-01Journal of Materials Chemistry A

Single atomic layer nanosheet materials show great application potential in many fields due to their enhanced intrinsic properties compared to their counterparts and newly born properties. Herein, g-C3N4 nanosheets with a single atomic layer structure are prepared by a simple chemical exfoliation method. The as-prepar…

Advanced Photocatalysis Techniques2D Materials and ApplicationsGas Sensing Nanomaterials and Sensors

New directions in thermoresponsive polymers

Debashish Roy、William L. A. Brooks、Brent S. Sumerlin2013-01-01Chemical Society Reviews

Interest in thermoresponsive polymers has steadily grown over many decades, and a great deal of work has been dedicated to developing temperature sensitive macromolecules that can be crafted into new smart materials. However, the overwhelming majority of previously reported temperature-responsive polymers are based on…

Hydrogels: synthesis, properties, applicationsElectrospun Nanofibers in Biomedical ApplicationsPolymer Surface Interaction Studies

Enhanced photocatalytic performance of direct Z-scheme g-C3N4–TiO2 photocatalysts for the decomposition of formaldehyde in air

Jiaguo Yu、Shuhan Wang、Jingxiang Low 等 4 位作者2013-01-01Physical Chemistry Chemical Physics

Formaldehyde (HCHO) is a major indoor pollutant and long-term exposure to HCHO may cause health problems such as nasal tumors and skin irritation. Photocatalytic oxidation is considered as the most promising strategy for the decomposition of HCHO. Herein, for the first time, a direct g-C3N4-TiO2 Z-scheme photocatalyst…

Advanced Photocatalysis TechniquesCatalytic Processes in Materials ScienceGas Sensing Nanomaterials and Sensors

Triplet photosensitizers: from molecular design to applications

Jianzhang Zhao、Wanhua Wu、Jifu Sun 等 4 位作者2013-01-01Chemical Society Reviews

Triplet photosensitizers (PSs) are compounds that can be efficiently excited to the triplet excited state which subsequently act as catalysts in photochemical reactions. The name is originally derived from compounds that were used to transfer the triplet energy to other compounds that have only a small intrinsic tripl…

Perovskite Materials and ApplicationsOrganic Light-Emitting Diodes ResearchLuminescence and Fluorescent Materials

Halogen bonding and other σ-hole interactions: a perspective

Peter Politzer、Jane S. Murray、Timothy Clark2013-01-01Physical Chemistry Chemical Physics

A σ-hole bond is a noncovalent interaction between a covalently-bonded atom of Groups IV-VII and a negative site, e.g. a lone pair of a Lewis base or an anion. It involves a region of positive electrostatic potential, labeled a σ-hole, on the extension of one of the covalent bonds to the atom. The σ-hole is due to the…

Crystallography and molecular interactionsNonlinear Optical Materials ResearchSolid-state spectroscopy and crystallography

Luminescent probes and sensors for temperature

Xudong Wang、Otto S. Wolfbeis、Robert J. Meier2013-01-01Chemical Society Reviews

Temperature (T) is probably the most fundamental parameter in all kinds of science. Respective sensors are widely used in daily life. Besides conventional thermometers, optical sensors are considered to be attractive alternatives for sensing and on-line monitoring of T. This Review article focuses on all kinds of lumi…

Gas Sensing Nanomaterials and SensorsLuminescence and Fluorescent MaterialsAnalytical Chemistry and Sensors

Nanostructured metal chalcogenides: synthesis, modification, and applications in energy conversion and storage devices

Min‐Rui Gao、Yun‐Fei Xu、Jun Jiang 等 4 位作者2013-01-01Chemical Society Reviews

Advanced energy conversion and storage (ECS) devices (including fuel cells, photoelectrochemical water splitting cells, solar cells, Li-ion batteries and supercapacitors) are expected to play a major role in the development of sustainable technologies that alleviate the energy and environmental challenges we are curre…

Electrocatalysts for Energy ConversionQuantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin Films

A facile synthesis of UiO-66, UiO-67 and their derivatives

Michael J. Katz、Zachary J. Brown、Yamil J. Colón 等 8 位作者2013-01-01Chemical Communications

A scalable, reproducible method of synthesizing UiO-66- and UiO-67-type MOFs, entailing the addition of HCl to the reaction mixture, has been investigated. The new protocol requires a fraction of the time of previously reported procedures, yields exceptional porosities, and works with a range of linkers.

Metal-Organic Frameworks: Synthesis and ApplicationsLanthanide and Transition Metal ComplexesPolyoxometalates: Synthesis and Applications