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Hydrogenation of semiconductor surfaces: Si-terminated cubic SiC(100) surfaces

Daniel G. Trabada、F. Flóres、José Ortega2009-08-13Physical Review B

We analyze the hydrogenation of the Si-terminated surfaces $3\text{C-SiC}(100)\text{\ensuremath{-}}3\ifmmode\times\else\texttimes\fi{}2$ and $3\text{C-SiC}(100)\text{\ensuremath{-}}c(4\ifmmode\times\else\texttimes\fi{}2)$ using density-functional-theory techniques. For the Si-rich $3\ifmmode\times\else\texttimes\fi{}2…

Graphene research and applicationsSilicon Carbide Semiconductor TechnologiesBoron and Carbon Nanomaterials Research

Magnetic properties of a Heisenberg coupled-trimer molecular magnet: General results and application to spin-12vanadium clusters

J. T. Haraldsen、T. Barnes、J. W. Sinclair 等 6 位作者2009-08-13Physical Review B

We report predictions for the energy eigenstates and inelastic neutron-scattering excitations of an isotropic Heisenberg hexamer consisting of general spin $S$ and ${S}^{\ensuremath{'}}$ trimers. Specializing to spin-1/2 ions, we give analytic results for the energy excitations, magnetic susceptibility, and inelastic…

Magnetism in coordination complexesLanthanide and Transition Metal ComplexesOrganic and Molecular Conductors Research

Dielectric-substrate-induced surface-enhanced Raman scattering

O. J. Glembocki、R. W. Rendell、Dimitri Alexson 等 6 位作者2009-08-13Physical Review B

It is shown through experimental mapping of surface-enhanced Raman scattering (SERS) from dielectric core nanowires exposed to benzene thiol that any dielectric substrate plays a critical role in the SERS enhancement. Theoretical calculations of the plasmonic enhancement using finite element methods confirms the role…

Gold and Silver Nanoparticles Synthesis and ApplicationsAdvanced biosensing and bioanalysis techniquesPlasmonic and Surface Plasmon Research

Steam Reforming of Methanol with Sm2O3−CeO2-Supported Palladium Catalysts: Influence of the Thermal Treatments of Catalyst and Support

L.M. Gómez-Sainero、Richard T. Baker、Arturo J. Vizcaíno 等 7 位作者2009-08-13Industrial & Engineering Chemistry Research

The design of new anode materials to promote the reforming of methanol is important for the development of intermediate temperature direct methanol solid oxide fuel cells. A previous study showed Pd/CeO 2 −Sm 2 O 3 to be a good candidate. Here, the influence of the calcination pretreatment of the support and the reduc…

Catalytic Processes in Materials ScienceAdvancements in Solid Oxide Fuel CellsCatalysis and Oxidation Reactions

3-Aminopropyltriethoxysilane Effect on Thermal and Mechanical Properties of Multi-walled Carbon Nanotubes Reinforced Epoxy Composites

Jeong Tai Kim、Hee-Cheul Kim、Sunkuk Kim 等 5 位作者2009-08-13Journal of Composite Materials

Diglycidyl ether of bisphenol A nanocomposites with unmodified multi-walled carbon nanotubes (u-MWCNTs) and silanized multi-walled carbon nanotubes (si-MWCNTs) were prepared by cast molding method. The effects of 3-aminopropyltriethoxysilane functionalization of MWCNTs on the thermal and mechanical properties of the n…

Carbon Nanotubes in CompositesPolymer Nanocomposites and PropertiesFiber-reinforced polymer composites

Base‐free catalytic aerobic oxidation of mercaptans for gasoline sweetening over HTLcs‐derived CuZnAl catalyst

Lida Gao、Qingsong Xue、Ye Liu 等 4 位作者2009-08-13AIChE Journal

Abstract An aerobic oxidative removal of mercaptans from gasoline in the absence of liquid base has been demonstrated for gasoline sweetening over CuZnAl catalyst. This process could proceed at large WHSV of gasoline (50–70 h −1 ) with >95% mercaptan conversion at 150°C (or 300°C) using an O 2 /S molar ratio of 20–…

Catalytic Processes in Materials ScienceCatalysis and Hydrodesulfurization StudiesOxidative Organic Chemistry Reactions

Magnetic and lattice coupling in single-crystal SrFe 2 As 2 : A neutron scattering study

Haifeng Li、Wei Tian、J. L. Zarestky 等 10 位作者2009-08-13Physical Review B

A detailed elastic neutron scattering study of the structural and magnetic phase transitions in single-crystal ${\text{SrFe}}_{2}{\text{As}}_{2}$ reveals that the orthorhombic (O)-tetragonal (T) and the antiferromagnetic transitions coincide at ${T}_{\text{O}}={T}_{\text{N}}=(201.5\ifmmode\pm\else\textpm\fi{}0.25)\tex…

Rare-earth and actinide compoundsIron-based superconductors researchIntellectual Capital and Performance Analysis

Strength and Damage of Elementary Flax Fibers Extracted from Tow and Long Line Flax

J. Andersons、E. Spārniņš、E. Poriķe2009-08-13Journal of Composite Materials

Flax fibers possess high specific strength and stiffness, and thus are competitive in terms of mechanical properties with traditional reinforcing fibers used in polymer-matrix composite materials. For environmental and economical benefit, it would be preferable to apply nontextile grade fibers in composites provided t…

Natural Fiber Reinforced CompositesEngineering and Agricultural InnovationsVaried Academic Research Topics

Competition between quantum fluctuations and antiferroelectric order in Ru-doped Sr0.8Ca0.2Ti1−xRuxO3

Tong Wei、Yipeng Guo、Y. J. Guo 等 8 位作者2009-08-13Journal of Physics Condensed Matter

The competition between quantum fluctuations and the antiferroelectric state in Sr(0.8)Ca(0.2)Ti(1-x)Ru(x)O(3) is investigated by measuring the low-temperature dielectric permittivity and by Raman spectroscopy. We demonstrate the significant impact of quantum fluctuations on the stability of the antiferroelectric pola…

Ferroelectric and Piezoelectric MaterialsMultiferroics and related materialsDielectric properties of ceramics

Preparation of poly(amino‐amide) particles complexed with ZnO particles using silane coupling agents

Yayoi Yoshioka2009-08-13Journal of Polymer Science Part A Polymer Chemistry

Abstract Poly(amino‐amide) particles were prepared by reacting 4,4′‐diphenyldicarbonyl chloride and 3,3′‐diaminobenzidine using a precipitation polymerization method with ultrasonic irradiation. The resulting particles had a narrow size distribution with an average diameter of 334 nm and showed excellent dispersion st…

biodegradable polymer synthesis and propertiesSynthesis and properties of polymersSilicone and Siloxane Chemistry

New Insights into the Control of Self-Assembly of Block Copolymer Membranes

Daniel Fierro、Kristian Buhr、Clarissa Abetz 等 5 位作者2009-08-13Australian Journal of Chemistry

The preparation and morphological characterization of a so-called composite membrane based on a 3-miktoarm star terpolymer on a support layer is reported. It is demonstrated that different levels of order and different morphological orientations can be obtained by directly casting the star terpolymer solution on the s…

Advanced Polymer Synthesis and CharacterizationPolymer Surface Interaction StudiesBlock Copolymer Self-Assembly

Architecture of the Biomineralized Byssus of the Saddle Oyster (Anomiasp.)

Jakob Rostgaard Eltzholtz、Henrik Birkedal2009-08-13The Journal of Adhesion

Nature displays several solutions to underwater adhesion. In the bivalve mussels, an adhesive attachment organ known as the byssus is often used. In the blue mussel and related species the byssal system consists of a series of byssus threads that are organic in nature. In contrast hereto, the jingle shell, Anomia sp.,…

Bone Tissue Engineering MaterialsCalcium Carbonate Crystallization and InhibitionMarine Biology and Environmental Chemistry

Potential of chitosan from Mucor rouxxi UCP064 as alternative natural compound to inhibit Listeria monocytogenes

Roberta Bento、Tânia Lúcia Montenegro Stamford、Galba Maria de Campos‐Takaki 等 5 位作者2009-08-13Brazilian Journal of Microbiology

Listeria monocytogenes is widely distributed in nature and the infection listeriosis is recognized as a potential threat for human health because of its mortality rate. The objective of this study was to evaluate the growth profile and chitosan production by Mucor rouxxi UCP 064 grown in yam bean (Pachyrhizus erosus L…

Nanocomposite Films for Food PackagingMicroencapsulation and Drying ProcessesMedicinal Plants and Neuroprotection

Electrospinning of Poly(alkoxyphenylenevinylene) and Methanofullerene Nanofiber Blends

Harvey A. Liu、Danny Zepeda、John P. Ferraris 等 4 位作者2009-08-13ACS Applied Materials & Interfaces

Poly(p-phenylenevinylene) (PPV) derivatives have long been studied because of their attractive opto- and electroluminescent properties and have potential applications for devices such as light-emitting diodes and photovoltaics. The ability to induce alignment of these PPV derivatives may lead to the enhancement of cha…

Conducting polymers and applicationsElectrospun Nanofibers in Biomedical ApplicationsPolymer composites and self-healing

Optimizing the hyperpolarizability tensor using external electromagnetic fields and nuclear placement

David S. Watkins、Mark G. Kuzyk2009-08-13The Journal of Chemical Physics

We investigate the effects of an external electric and magnetic field on the first hyperpolarizability tensor of a quantum system, such as a molecule or nanoparticle, whose nonlinear response is well below the fundamental limit. We find that the intrinsic hyperpolarizability is optimized when the applied electric and…

Nonlinear Optical Materials ResearchSynthesis and Properties of Aromatic CompoundsNonlinear Optical Materials Studies

Particle Size-Dependent Charge Ordering and Magnetic Properties in Pr0.55Ca0.45MnO3

Ping Chai、Xueyu Wang、Shuang Hu 等 8 位作者2009-08-13The Journal of Physical Chemistry C

A series of Pr 0.55 Ca 0.45 MnO 3 compounds with average particle size ranging from 2000 to 30 nm have been synthesized by the sol−gel method and their charge ordering (CO) and magnetic properties are investigated. It is observed that with particle size decreasing, the CO transition is gradually suppressed and finally…

Advanced Thermoelectric Materials and DevicesMagnetic and transport properties of perovskites and related materialsAdvanced Condensed Matter Physics

Co-sintering of M2/17-4PH Powders for Fabrication of Functional Graded Composite Layers

Vahid Firouzdor、Abdolreza Simchi2009-08-13Journal of Composite Materials

Stepwise-graded composite layer of M2 tool steel and 17-4PH stainless steel was fabricated by a simple powder layering technique and the isothermal and nonisothermal sintering response of the bilayer were examined. It was shown that the materials exhibit poor compatibility during co-sintering, i.e., the amount of mism…

Metal and Thin Film MechanicsTribology and Wear AnalysisMetal Alloys Wear and Properties

Polymer Surface Modification by Aerosol Based DBD Treatment of Foils

Renate Mix、Joerg F. Friedrich、Alexander Rau2009-08-13Plasma Processes and Polymers

Abstract The effect of different nebulized liquids directly introduced into the dielectric barrier discharge (DBD) was compared with simple air DBD treatment of polyethylene foils. Water, alcohols and aqueous solutions of different organic substances (environmentally compatible) and water soluble polymers were applied…

Surface Modification and SuperhydrophobicityAdvanced Sensor and Energy Harvesting MaterialsPlasma Applications and Diagnostics

Long-Term Improvements to Photoluminescence and Dispersion Stability by Flowing SDS-SWNT Suspensions through Microfluidic Channels

Carlos Silvera-Batista、Philip Weinberg、Jason E. Butler 等 4 位作者2009-08-13Journal of the American Chemical Society

Shearing single-walled carbon nanotubes (SWNTs) coated with sodium dodecyl sulfate in microfluidic channels significantly increases the photoluminescence (PL) intensity and dispersion stability of SWNTs. The PL quantum yield (QY) of SWNTs improves by a factor of 3 for initially bright suspensions; on the other hand, S…

Carbon Nanotubes in CompositesNanopore and Nanochannel Transport StudiesIon-surface interactions and analysis

Thermally Responsive Elastomeric Supramolecular Polymers Featuring Flexible Aliphatic Hydrogen-Bonding End-Groups

P. Woodward、Daniel Hermida‐Merino、Ian W. Hamley 等 5 位作者2009-08-13Australian Journal of Chemistry

The present paper details the synthesis, characterization, and preliminary physical analyses of a series of polyisobutylene derivatives featuring urethane and urea end-groups that enable supramolecular network formation to occur via hydrogen bonding. These polymers are readily accessible from relatively inexpensive an…

Advanced Polymer Synthesis and CharacterizationPolymer composites and self-healingSynthesis and properties of polymers