Materials Literature
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An aliphatic/aromatic polyester blend has been dealt with in this study. As an aliphatic polyester, poly(butylene succinate) (PBS) was used, which is thought to possess biodegradability, but it is relatively expensive. It has been blended with poly(butylene terephthalate) (PBT) in order to obtain a biodegradable blend…
The interactions between soluble collagen (C) from calf skin and poly(acrylic acid) (PAA) were studied. Mixing aqueous solutions of collagen and PAA, at various pH values (2.5–4), leads to the formation of complexes that precipitate in the form of insoluble aggregates. The effects of mixture composition, pH, and ionic…
Using first principles density functional calculations, gold monatomic wires are found to exhibit a zigzag shape which remains under tension, becoming linear just before breaking. At room temperature they are found to spin, what explains the extremely long apparent interatomic distances shown by electron microscopy.Th…
The temperature dependence of the elastic stiffness constant c 55 in [N(CH 3 ) 4 ] 2 ZnBr 4 single crystals has been measured using Brillouin scattering and the ultrasonic pulse echo overlap technique. The elastic constant c 55 was found to soften strongly in both the paraelastic and ferroelastic phases. Despite the f…
A new process for producing polyamide from polyester and diamine was proposed. An attempt was made to produce polyamide 6T from polyethyleneterephthalate or dimethylterephthalate with hexamethylenediamine in water, o-dichlorobenzene and sulfolane. Characterization of the products by IR, elemental analysis, solution vi…
Oligomers covering degrees of polymerization up to 23 of 2-(1-imidazolyl)ethyl methacrylate (ImEMA) were synthesized by group transfer polymerization (GTP) in propylene carbonate and tetrahydrofuran (THF). While GTP proceeds smoothly in propylene carbonate, polymerization in THF is accompanied by oligomer precipitatio…
X-ray resonant scattering, due to the anisotropic tensor of susceptibility (ATS), from magnetite, Fe 3 O 4 , near the Fe K-absorption edge, was measured from room temperature to 80 K. The energy dependence of the 002 “forbidden” reflection intensity showed two sharp peaks just above and below the edge. The azimuthal d…
This paper describes the concepts of resolution in the time and temperature domains and illustrates the principles using two new sample controlled thermal analysis (SCTA) techniques. The use of SCTA, where the sample temperature is determined by the rate of reaction, offers a number of advantages over conventional (li…
We have developed an algorithm to analyze the circular dichroism of proteins for secondary structure. Its hallmark is tremendous flexibility in creating the basis set, and it also combines the ideas of many previous workers. We also present a new basis set containing the CD spectra of 22 proteins with secondary struct…
A model system involving a polyanionic alginic acid (AA) overlayer ionically immobilized on a polycationic polyethyleneimine underlayer, in turn linked to plasma oxidized polystyrene, was used to investigate the relationship between surface structure properties and resistance to cell adhesion. X-ray Photoelectron Spec…
This letter presents the equation of capillary hydrodynamics for interfaces between viscous isotropic fluids and nematic liquid crystals (NLCs) to establish the existence of a new class of Marangoni flow. The interfacial stress balance equation involves the surface divergence of the surface stress tensor. It is shown…
2,2,′3,3′-Biphenyltetracarboxylic dianhydride (2,2,′3,3′-BPDA) was prepared by a coupling reaction of dimethyl 3-iodophthalate. The X-ray single-crystal structure determination showed that this dianhydride had a bent and noncopolanar structure, presenting a striking contrast to its isomer, 3,3,′4,4′-BPDA. This dianhyd…
Shear banding of wormlike micelle solution has been studied in the context of constitutive instability of the Johnson-Segalman (JS) model plus Newtonian stress. We have incorporated a higher-order gradient term of the deformation-rate tensor into the JS model for investigating the dynamics of a mechanical interface in…
To obtain molecules that can target malignant cells, two series of new meso glucosylporphyrins bearing amino acid residues are synthesized in four steps. The first series contained n meso glycosyl moieties and (4 − n ) alanyl groups on the ortho or para positions of the meso phenyl. In the second series, the carbohydr…
A series of poly(styrene-block-ferrocenyldimethylsilane) copolymers (SF) with different relative molar masses of the blocks were prepared by sequential anionic polymerization. The bulk morphology of these polymers, studied by TEM and SAXS, showed well-ordered lamellar and cylindrical domains as well as disordered mice…
Memory retention characteristics of metal–ferroelectric–metal–insulator–semiconductor (MFMIS) field effect transistors (FETs) were investigated in detail using a simple structure, referred to as quasi-MFMIS, in which one electrode of the metal–ferroelectric–metal (MFM) capacitor is connected to a gate electrode of a c…
A multiblock copoly(ester–ether) consisting of poly(l-lactic acid) (PLLA) and poly(oxypropylene-co-oxyethylene) (PN) was prepared and characterized. Preparation was done via the solution polycondensation of a thermal oligocondensate of l-lactic acid, a commercially available telechelic polyether (PN: Pluronic-F68), an…
The etching effects on the CdTe surface treated by the different chemical etchants, such as 2% Br-methanol (BM) and 2% Br-20% latic acid in ethylene glycol (BLE) solutions are studied by both photoluminescence (PL) and atomic force microscopy. After etching, the dielectric materials ZnS and CdZnTe are used for the pas…
ADVERTISEMENT RETURN TO ISSUEPREVNoteA Novel Fabrication of Ultrathin Poly(vinylamine) Films with a Molecularly Smooth SurfaceTakeshi Serizawa, Kazuya Yamamoto, and Mitsuru AkashiView Author Information Department of Applied Chemistry and Chemical Engineering, Faculty of Engineering, Kagoshima University, 1-21-40 Kori…
In this work, the Young’s, E, and shear, μ, moduli of Ti3SiC2 are measured ultrasonically in the 20–300 K temperature range. At room temperature, Young’s, ERT, and shear, μRT, moduli are 322±2 and 133.6±0.8 GPa, respectively. Poisson’s ratio is 0.2. Both moduli increase slowly with decreasing temperature and plateau o…