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Solution blowing of ZnO nanoflake-encapsulated carbon nanofibers as electrodes for supercapacitors

Shaojun Shi、Xupin Zhuang、Bowen Cheng 等 4 位作者2013-01-01Journal of Materials Chemistry A

A facile spinning-based strategy is developed to fabricate zinc oxide nanoflake-encapsulated carbon nanofibers (ZnO/CNFs) as electrodes for supercapacitors. The zinc oxide/carbon nanofiber mats were solution blown with zinc acetate (Zn(Ac)2) and polyacrylonitrile (PAN) as the metal and carbon precursor to get Zn(Ac)2…

Advancements in Battery MaterialsSupercapacitor Materials and FabricationAdvanced battery technologies research

Interfacial microfluidic transport on micropatterned superhydrophobic textile

Siyuan Xing、Jia Jiang、Tingrui Pan2013-01-01Lab on a Chip

Textile-enabled interfacial microfluidics, utilizing fibrous hydrophilic yarns (e.g., cotton) to guide biological reagent flows, has been extended to various biochemical analyses recently. The restricted capillary-driving mechanism, however, persists as a major challenge for continuous and facilitated biofluidic trans…

Surface Modification and SuperhydrophobicityAdvanced Sensor and Energy Harvesting MaterialsNanomaterials and Printing Technologies

Enhanced hydrogen desorption from Mg(BH4)2 by combining nanoconfinement and a Ni catalyst

M. A. Wahab、Yi Jia、Dongjiang Yang 等 5 位作者2013-01-01Journal of Materials Chemistry A

Magnesium borohydride (Mg(BH4)2) has been infiltrated into highly ordered mesoporous carbon (CMK3) containing dispersed Ni nanoparticles (Ni NPs) to investigate the possible synergetic effects of nanoconfinement and catalysis by Ni NPs. Ni NPs (5 wt%) were introduced into the CMK3 nanoscaffold (CMK3–Ni) then Mg(BH4)2…

Hydrogen Storage and MaterialsAmmonia Synthesis and Nitrogen ReductionSuperconductivity in MgB2 and Alloys

Inorganic–organic multiferroic hybrid films of Fe3O4 and PVDF with significant magneto-dielectric coupling

O. D. Jayakumar、Balaji P. Mandal、Jerina Majeed 等 6 位作者2013-01-01Journal of Materials Chemistry C

Flexible and self-standing inorganic-organic hybrid films of silica coated Fe3O4 nanoparticles and polyvinylidene fluoride (PVDF) polymer with significant magneto-dielectric coupling have been prepared at low temperature by a simple solvent casting method. PVDF films with two different concentrations of silica coated…

Ferroelectric and Piezoelectric MaterialsMultiferroics and related materialsDielectric properties of ceramics

Polymer thin films for antireflection coatings

Xiao Li、Xinhong Yu、Yanchun Han2013-01-01Journal of Materials Chemistry C

Polymer thin films for antireflection (AR) coatings are reviewed, with particular emphasis on making different kinds of structures and establishing the relationships between structures and antireflective properties. Three kinds of main structures with antireflective properties, namely, homogeneous, inhomogeneous porou…

Advanced Fiber Optic SensorsSurface Modification and SuperhydrophobicityOptical Coatings and Gratings

RE2(MO4)3:Ln3+ (RE = Y, La, Gd, Lu; M = W, Mo; Ln = Eu, Sm, Dy) microcrystals: controlled synthesis, microstructure and tunable luminescence

You Zhou、Bing Yan2013-01-01CrystEngComm

RE2(MO4)3:Ln3+ (RE = Y, La, Gd, Lu; M = W, Mo; Ln = Eu, Sm, Dy) microcrystals with uniform shape and size were synthesized via a hydrothermal method using a polyvinylpyrrolidone (PVP)-assisted processes. The crystalline structure and morphology of these as-prepared samples were characterized by X-ray diffraction (XRD)…

Luminescence Properties of Advanced MaterialsGlass properties and applicationsCrystal Structures and Properties

Lung toxicity and biodistribution of Cd/Se-ZnS quantum dots with different surface functional groups after pulmonary exposure in rats

Jenny R. Roberts、James M. Antonini、Dale W. Porter 等 9 位作者2013-01-01Particle and Fibre Toxicology

BACKGROUND: The potential use of quantum dots (QD) in biomedical applications, as well as in other systems that take advantage of their unique physiochemical properties, has led to concern regarding their toxicity, potential systemic distribution, and biopersistence. In addition, little is known about workplace exposu…

Quantum Dots Synthesis And PropertiesAdvanced Cellulose Research StudiesCarbon and Quantum Dots Applications

On the mechanism of the direct pathway for formic acid oxidation at a Pt(111) electrode

Jie Xu、Dao-Fu Yuan、Fan Yang 等 6 位作者2013-01-01Physical Chemistry Chemical Physics

In order determine whether formate is a reaction intermediate of the direct pathway for formic acid oxidation at a Pt electrode, formic acid (HCOOH) oxidation at a Pt(111) electrode has been studied by normal and fast scan voltammetry in 0.1 M HClO4 solutions with different HCOOH concentrations. The relationship betwe…

Electrocatalysts for Energy ConversionConducting polymers and applicationsCO2 Reduction Techniques and Catalysts

In situ pH measurement during the formation of conversion coatings on an aluminum alloy (AA2024)

Liangliang Li、Annika Laura Desouza、Greg M. Swain2013-01-01The Analyst

The measurement of interfacial pH change is important for understanding the formation mechanism of conversion coatings that are used to protect metals from corrosion. In this work, we used a tungsten microelectrode to measure the interfacial pH change near the surface of an aluminium alloy (AA2024) during the formatio…

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsConcrete Corrosion and Durability

Corrosion and conservation of cultural heritage metallic artefacts

Philippe Dillmann、David Watkinson、Emma Paola Maria Virginia Angelini 等 4 位作者2013-01-01Woodhead Publishing Limited eBooks

The conservation of metallic archaeological and historic artefacts is a major challenge whether they are ancient bronzes or relics of our more recent industrial past. Based on the work of Working Party 21 Corrosion of Archaeological and Historical Artefacts within the European Federation of Corrosion (EFC), this impor…

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsCultural Heritage Materials Analysis

Magnetic Properties and Biological Activity Evaluation of Iron Oxide Nanoparticles

Alina Mihaela Prodan、Simona Liliana Iconaru、Mariana Carmen Chifiriuc 等 8 位作者2013-01-01Journal of Nanomaterials

The aim of this study was to provide information about the biological properties of iron oxide nanoparticles (IO‐NPs) obtained in an aqueous suspension. The IO‐NPs were characterized by transmission electron microscopy (TEM). Analysis of hysteresis loops data at room temperature for magnetic IO‐NPs sample indicated th…

Nanoparticle-Based Drug DeliveryNanoparticles: synthesis and applicationsCharacterization and Applications of Magnetic Nanoparticles

Size-dependent oxygen storage ability of nano-sized ceria

Congting Sun、Dongfeng Xue2013-01-01Physical Chemistry Chemical Physics

We thermodynamically studied the size-dependent oxygen storage ability of nano-sized ceria by tracing the surface Ce/O ratio of octahedral particles with different diameters, from the viewpoint of lattice Ce and O in a CeO2 crystallographic structure. The high surface Ce/O ratio with small scale particle size has more…

Catalytic Processes in Materials ScienceCatalysis and Oxidation ReactionsCopper-based nanomaterials and applications

Coaxial PANI/TiN/PANI nanotube arrays for high-performance supercapacitor electrodes

Xiang Peng、Kaifu Huo、Jijiang Fu 等 6 位作者2013-01-01Chemical Communications

Coaxial PANI/TiN/PANI nanotube arrays prepared by electrochemical polymerization of PANI on nanoporous TiN nanotube arrays exhibit a high specific capacitance of 242 mF cm(-2), excellent rate capability with the capacitance remaining at 69% when the current density is increased 50 times from 0.2 to 10 mA cm(-2), and a…

Advancements in Battery MaterialsSupercapacitor Materials and FabricationMXene and MAX Phase Materials

Reversible fluorescence modulation of spiropyran-functionalized carbon nanoparticles

Bo Liao、Long Peng、Benqiao He 等 7 位作者2013-01-01Journal of Materials Chemistry C

Fluorescent carbon nanoparticles (CNPs) with diameters of about 3 nm which can emit blue-green light were synthesized through the hydrothermal carbonization of ethylenediaminetetraacetic acid disodium salt (EDTA·2Na). Then, the CNPs were functionalized with spiropyrans to obtain the spiropyran-functionalized CNPs. The…

Quantum Dots Synthesis And PropertiesPhotochromic and Fluorescence ChemistryPhotoreceptor and optogenetics research

Dendrimeric Systems and Their Applications in Ocular Drug Delivery

Burçin Yavuz、Sibel Bozdağ Pehlivan、Nurşen Ünlü2013-01-01The Scientific World JOURNAL

Ophthalmic drug delivery is one of the most attractive and challenging research area for pharmaceutical scientists and ophthalmologists. Absorption of an ophthalmic drug in conventional dosage forms is seriously limited by physiological conditions. The use of nonionic or ionic biodegradable polymers in aqueous solutio…

Nanoparticle-Based Drug DeliveryRNA Interference and Gene DeliveryDendrimers and Hyperbranched Polymers

Electrospun composite nanofiber-based transmucosal patch for anti-diabetic drug delivery

Anupama Sharma、Ashish Gupta、Goutam Rath 等 6 位作者2013-01-01Journal of Materials Chemistry B

The intention of the present investigation was to develop an oral formulation for an anti-diabetic drug that not only could deliver it in the active form but also provide a sustained and controlled release profile. A biodegradable poly(vinyl alcohol) (PVA) and sodium alginate (NaAlg) electrospun composite nanofiber ba…

Advanced Sensor and Energy Harvesting MaterialsElectrospun Nanofibers in Biomedical ApplicationsPancreatic function and diabetes

Nanocarriers for Diagnosis and Targeting of Breast Cancer

Arun Sharma、Nitin Jain、Rashmi Sareen2013-01-01BioMed Research International

Breast cancer nanotherapeutics is consistently progressing and being used to remove the various limitations of conventional method available for the diagnosis and treatment of breast cancer. Nanoparticles provide an interdisciplinary area for research in imaging, diagnosis, and targeting of breast cancer. With advance…

Nanoparticle-Based Drug DeliveryNanoplatforms for cancer theranosticsGraphene and Nanomaterials Applications

Atomistic modelling of CVD synthesis of carbon nanotubes and graphene

James A. Elliott、Yasushi Shibuta、Hakim Amara 等 5 位作者2013-01-01Nanoscale

We discuss the synthesis of carbon nanotubes (CNTs) and graphene by catalytic chemical vapour deposition (CCVD) and plasma-enhanced CVD (PECVD), summarising the state-of-the-art understanding of mechanisms controlling their growth rate, chiral angle, number of layers (walls), diameter, length and quality (defects), be…

Carbon Nanotubes in CompositesGraphene research and applicationsDiamond and Carbon-based Materials Research

A face-capped [Fe4L4]8+ spin crossover tetrahedral cage

Alan Ferguson、Marie A. Squire、Diana Siretanu 等 7 位作者2013-01-01Chemical Communications

Reported here is a face-capped Fe(ii) molecular tetrahedron, [Fe(4)L(4)](BF(4))(8), . Single crystal X-ray diffraction at 153 and 293 K suggest spin crossover (SCO) and variable temperature magnetic susceptibility measurements confirm displays thermally driven SCO behaviour in the solid state and in dilute acetone sol…

Magnetism in coordination complexesLanthanide and Transition Metal ComplexesMetal-Catalyzed Oxygenation Mechanisms

Coexistence of plasmonic and magnetic properties in Au89Fe11 nanoalloys

Vincenzo Amendola、Moreno Meneghetti、Osman M. Bakr 等 13 位作者2013-01-01Nanoscale

We describe an environmentally friendly, top-down approach to the synthesis of Au89Fe11 nanoparticles (NPs). The plasmonic response of the gold moiety and the magnetism of the iron moiety coexist in the Au89Fe11 nanoalloy with strong modification compared to single element NPs, revealing a non-linear surface plasmon r…

Nanoparticle-Based Drug DeliveryNanocluster Synthesis and ApplicationsLaser-Ablation Synthesis of Nanoparticles