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Silver nanoparticles (AgNPs) cause degeneration of cytoskeleton and disrupt synaptic machinery of cultured cortical neurons

Fenglian Xu、Cortt G. Piett、Svetlana Farkas 等 5 位作者2013-01-01Molecular Brain

BACKGROUND: Silver nanoparticles (AgNPs), owing to their effective antimicrobial properties, are being widely used in a broad range of applications. These include, but are not limited to, antibacterial materials, the textile industry, cosmetics, coatings of various household appliances and medical devices. Despite the…

Nanoparticle-Based Drug DeliveryNanoparticles: synthesis and applicationsAdvanced Nanomaterials in Catalysis

A mesoporous poly-melamine-formaldehyde polymer as a solid sorbent for toxic metal removal

Mei Xuan Tan、Yin Ngai Sum、Jackie Y. Ying 等 4 位作者2013-01-01Energy & Environmental Science

A mesoporous poly-melamine-formaldehyde (mPMF) polymer with a high surface area, good porosity and high density of amine and triazine functional groups has been designed and synthesized. This porous organic polymer (POP) was found to be highly effective in removing toxic lead ions from water. Of particular interest wa…

Metal-Organic Frameworks: Synthesis and ApplicationsCovalent Organic Framework ApplicationsChemical Synthesis and Characterization

Efficient work-function engineering of solution-processed MoS2 thin-films for novel hole and electron transport layers leading to high-performance polymer solar cells

Jin-Mun Yun、Yong‐Jin Noh、Jun-Seok Yeo 等 12 位作者2013-01-01Journal of Materials Chemistry C

The work-function of MoS2 interfacial layers can be efficiently modulated by p- and n-doping treatments. As a result, the PCE of devices with a p-doped MoS2-based HTL is increased from ∼2.8 to ∼3.4%. Particularly, after n-doping the PCE was dramatically increased due to the change in work-function compared with un-dop…

Organic Electronics and PhotovoltaicsPerovskite Materials and Applications2D Materials and Applications

Cytotoxicity of surface-functionalized silicon and germanium nanoparticles: the dominant role of surface charges

Sourav Bhattacharjee、Ivonne M.C.M. Rietjens、Mani P. Singh 等 16 位作者2013-01-01Nanoscale

Although it is frequently hypothesized that surface (like surface charge) and physical characteristics (like particle size) play important roles in cellular interactions of nanoparticles (NPs), a systematic study probing this issue is missing. Hence, a comparative cytotoxicity study, quantifying nine different cellula…

Nanoparticles: synthesis and applicationsCarbon and Quantum Dots ApplicationsGraphene and Nanomaterials Applications

Effect of Nanoscale Titanium Dioxide Particles on the Germination and Growth of Canola (Brassica napus)

Homa Mahmoodzadeh、Mohammad Sarmad Nabavi、H. Kashefi2013-01-01Journal of ornamental and horticultural plants

An investigation was initiated to examine the effects of nanoscale titanium dioxide particles on plant growth and development. In view of the widespread cultivation of canola in Iran and in other parts of the globe and in view of the potential influence of titanium on its growth, this plant was chosen as the model sys…

TiO2 Photocatalysis and Solar CellsNanoparticles: synthesis and applicationsSilicon Effects in Agriculture

Supramolecular polymerization in water harnessing both hydrophobic effects and hydrogen bond formation

Christianus M. A. Leenders、Lorenzo Albertazzi、Tristan Mes 等 6 位作者2013-01-01Chemical Communications

The formation of supramolecular polymers in water through rational design of a benzene-1,3,5-tricarboxamide (BTA) motif is presented. Intermolecular hydrogen bonding and hydrophobic effects cooperate in the self-assembly into long fibrillar aggregates. Minimal changes in molecular structure significantly affect the in…

Luminescence and Fluorescent MaterialsSupramolecular Self-Assembly in MaterialsPolydiacetylene-based materials and applications

Co-electro-deposition of the MnO2–PEDOT:PSS nanostructured composite for high areal mass, flexible asymmetric supercapacitor devices

Zijin Su、Cheng Yang、Chengjun Xu 等 10 位作者2013-01-01Journal of Materials Chemistry A

To meet the rapidly growing demand, it is necessary to develop novel flexible energy storage devices with a high energy density in a limited area, a fast charging ability, a low cost for mass production and a miniaturized device size. To address the above issues, here we introduce the co-electro-deposition strategy, w…

Supercapacitor Materials and FabricationConducting polymers and applicationsAdvanced battery technologies research

Self-assembly of organic luminophores with gelation-enhanced emission characteristics

Zujin Zhao、Jacky W. Y. Lam、Ben Zhong Tang2013-01-01Soft Matter

Fluorescent self-assembled organogels are interesting supramolecular soft materials with polymer-like structures and have received particular attention due to their fascinating properties and promising practical applications. However, most planar π-conjugated gelators are highly emissive in the solution state but beco…

Luminescence and Fluorescent MaterialsSupramolecular Self-Assembly in MaterialsPolydiacetylene-based materials and applications

Gravity driven separation of emulsified oil–water mixtures utilizing in situ polymerized superhydrophobic and superoleophilic nanofibrous membranes

Meiling Huang、Yang Si、Xiaomin Tang 等 9 位作者2013-01-01Journal of Materials Chemistry A

A novel and scalable strategy was developed for the synthesis of in situ polymerized superhydrophobic and superoleophilic nanofibrous membranes for effective separation of water-in-oil microemulsions, which exhibit an extremely high flux of 892 L m−2 h−1 solely driven by gravity, as well as good antifouling properties…

Surface Modification and SuperhydrophobicityAdvanced Sensor and Energy Harvesting MaterialsFluid Dynamics and Heat Transfer

Controlling lipid oxidation of food by active packaging technologies

Fang Tian、Eric A. Decker、Julie M. Goddard2013-01-01Food & Function

Active packaging is an innovative strategy in preventing lipid oxidation. Different active substances with different mechanisms of action have been investigated for imparting antioxidant activity to active packaging systems, including free radical scavengers, metal chelators, ultraviolet (UV) absorbers, oxygen scaveng…

Nanocomposite Films for Food Packagingbiodegradable polymer synthesis and propertiesEffects and risks of endocrine disrupting chemicals

Design, synthesis and characterization of a novel yellow long-persistent phosphor: Ca2BO3Cl:Eu2+,Dy3+

Wei Zeng、Yuhua Wang、Yuhua Wang 等 9 位作者2013-01-01Journal of Materials Chemistry C

A novel yellow emitting long-persistent phosphor Ca2BO3Cl:Eu2+,Dy3+ is developed. The incorporation of Dy3+ ions, which act as trap centers, largely extends the thermoluminescence characteristics and evidently enhances the persistent luminescence behavior of the phosphor. Both fluorescence and phosphorescence spectra…

Luminescence Properties of Advanced MaterialsRadiation Detection and Scintillator TechnologiesAmmonia Synthesis and Nitrogen Reduction

Multicolour light emission from chlorine-doped graphene quantum dots

Xueming Li、Shu Ping Lau、Libin Tang 等 5 位作者2013-01-01Journal of Materials Chemistry C

Multicolour emission is realized in chlorine-doped GQDs (Cl-GQDs) prepared by a facile hydrothermal method using fructose and hydrochloric acid as source materials. The average diameter of a Cl-GQD is about 5.4 nm with 2 at.% Cl. The emission colour of the Cl-GQDs can be tuned successively from blue to white, orange,…

Luminescence and Fluorescent MaterialsCarbon and Quantum Dots ApplicationsNanocluster Synthesis and Applications

Effect of surface morphology on friction of graphene on various substrates

Dae‐Hyun Cho、Lei Wang、Jin-Seon Kim 等 9 位作者2013-01-01Nanoscale

The friction of graphene on various substrates, such as SiO2, h-BN, bulk-like graphene, and mica, was investigated to characterize the adhesion level between graphene and the underlying surface. The friction of graphene on SiO2 decreased with increasing thickness and converged around the penta-layers due to incomplete…

Graphene research and applicationsDiamond and Carbon-based Materials ResearchForce Microscopy Techniques and Applications

Enhanced efficiency of graphene/silicon heterojunction solar cells by molecular doping

Tongxiang Cui、Ruitao Lv、Zheng‐Hong Huang 等 11 位作者2013-01-01Journal of Materials Chemistry A

Graphene (G) films were grown on copper foils by chemical vapor deposition and transferred onto n-type silicon (Si) to form G/Si Schottky heterojunction solar cells. The power conversion efficiencies (PCEs) of the G/Si solar cells were in the range of 1.94–2.66%. Four volatile oxidants HNO3, HCl, H2O2 and SOCl2 were e…

Graphene research and applicationsSilicon Nanostructures and PhotoluminescenceNanowire Synthesis and Applications

A hierarchically structured graphene foam and its potential as a large-scale strain-gauge sensor

Jun Kuang、Luqi Liu、Yun Gao 等 7 位作者2013-01-01Nanoscale

A hierarchically structured thermal-reduced graphene (ReG) foam with 0.5 S cm(-1) electrical conductivity is fabricated from a well-dispersed graphene oxide suspension via a directional freezing method followed by high-temperature thermal treatment. The as-prepared three-dimensional ReG foam has an ordered macroporous…

Graphene research and applicationsSupercapacitor Materials and FabricationAdvanced Sensor and Energy Harvesting Materials

Effective improvement of the properties of light weight carbon foam by decoration with multi-wall carbon nanotubes

Rajeev Kumar、Sanjay R. Dhakate、Tejendra K. Gupta 等 6 位作者2013-01-01Journal of Materials Chemistry A

In the present investigation, carbon foam (CF) has been decorated with multi-wall carbon nanotubes (MWCNTs) by two different routes to improve its electromagnetic interference (EMI) shielding effectiveness (SE) and mechanical properties. In the first case, a MWCNTs incorporated carbon precursor was used for the develo…

Cellular and Composite StructuresElectromagnetic wave absorption materialsAdvanced Antenna and Metasurface Technologies

Novel organic–inorganic flame retardants containing exfoliated graphene: preparation and their performance on the flame retardancy of epoxy resins

Xiaodong Qian、Lei Song、Bin Yu 等 8 位作者2013-01-01Journal of Materials Chemistry A

In this work, a simple and efficient approach for the preparation of organic–inorganic hybrids flame retardants (FRs-rGO), aiming at improving the flame retardant efficiency was presented. The reduced graphite oxide (rGO) was incorporated into the flame retardants matrix by in situ sol–gel process, resulting in the fo…

Flame retardant materials and propertiesFiber-reinforced polymer compositesSynthesis and properties of polymers

Shape anisotropic colloids: synthesis, packing behavior, evaporation driven assembly, and their application in emulsion stabilization

Venkateshwar Rao Dugyala、Santosh Daware、Madivala G. Basavaraj2013-01-01Soft Matter

The recent surge to explore and exploit the effect of particle shape has led to several interesting and unique observations in various diverse fields, ranging from biology to material science. To this end, the development of novel synthesis methods has contributed immensely, and has directed this exciting research on…

Proteins in Food SystemsSurfactants and Colloidal SystemsPickering emulsions and particle stabilization

A voyage into the synthesis and photophysics of homo- and heterobinuclear ensembles of phthalocyanines and porphyrins

Gema de la Torre、Giovanni Bottari、Michael Sekita 等 6 位作者2013-01-01Chemical Society Reviews

The remarkable properties of both phthalocyanines and porphyrins as individual building blocks have motivated the synthesis and study of homo- and heterobinuclear conjugates as light-harvesting systems. These planar chromophores share important electronic features such as high molar absorption coefficients, rich redox…

Porphyrin and Phthalocyanine ChemistryPhotochemistry and Electron Transfer StudiesPhotochromic and Fluorescence Chemistry

Fe–Co bimetallic alloy nanoparticles as a highly active peroxidase mimetic and its application in biosensing

Yujin Chen、Haiyan Cao、Wenbing Shi 等 5 位作者2013-01-01Chemical Communications

This article presents a new enzyme-mimic activity of non-noble metal-based bimetallic Fe-Co NPs. This type of enzyme-mimic exhibits much higher affinity to H2O2 over other NPs-based peroxidase mimetics by at least one order of magnitude due to the synergistic effects between the two metals.

Advanced biosensing and bioanalysis techniquesElectrochemical sensors and biosensorsAdvanced Nanomaterials in Catalysis