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Texturation boosts the thermoelectric performance of BiCuSeO oxyselenides

Jiehe Sui、J. Li、Jiaqing He 等 9 位作者2013-01-01Energy & Environmental Science

We present a high ZT ∼ 1.4 in textured Bi0.875Ba0.125CuSeO obtained by a hot-forging process. The carrier mobility along the direction perpendicular to the pressing direction was significantly increased, resulting in increase in the electrical conductivity and maximization of the power factor at 923 K from 6.3 μW cm−1…

Advanced Thermoelectric Materials and DevicesMagnetic and transport properties of perovskites and related materialsThermal properties of materials

Facile preparation, high microwave absorption and microwave absorbing mechanism of RGO–Fe3O4 composites

Zong Meng、Ying Huang、Yang Zhao 等 7 位作者2013-01-01RSC Advances

Reduced graphene oxide (RGO)–Fe3O4 composites with obviously enhanced microwave absorption properties were successfully fabricated by a rational one-pot simplified co-precipitation route, which avoided the usage of an inert gas and any additional chemical agents (such as surfactants and stabilizers). Given these advan…

Magnetic Properties and Synthesis of FerritesElectromagnetic wave absorption materialsAdvanced Antenna and Metasurface Technologies

Porous Co3O4 materials prepared by solid-state thermolysis of a novel Co-MOF crystal and their superior energy storage performances for supercapacitors

Fanli Meng、Zhiguo Fang、Zuo‐Xi Li 等 10 位作者2013-01-01Journal of Materials Chemistry A

In this work, porous Co3O4 materials were prepared via a solid-state conversion process of a freshly prepared cobalt-based metal–organic framework (Co-MOF) crystal. Herein, the unique Co-MOF crystal was formed via the specific chemical coordination between the carboxylic ligand azobenzene-3,5,4′-tricarboxylic acid (H3…

Metal-Organic Frameworks: Synthesis and ApplicationsSupercapacitor Materials and FabricationAdvanced battery technologies research

Perspectives on poly(dopamine)

Daniel R. Dreyer、Daniel J. Miller、Benny D. Freeman 等 5 位作者2013-01-01Chemical Science

Poly(dopamine) has emerged in recent years as a readily accessible synthetic analogue of the naturally occurring melanins. However, the polymer's structure has proved difficult to unambiguously elucidate and a variety of models have been proposed. Despite these challenges, poly(dopamine) has found extraordinary utilit…

Conducting polymers and applicationsPolymer Surface Interaction StudiesMolecular Junctions and Nanostructures

Integrated power fiber for energy conversion and storage

Yongping Fu、Hongwei Wu、Shuyang Ye 等 8 位作者2013-01-01Energy & Environmental Science

A new type of integrated power fiber that incorporates a dye-sensitized solar cell (DSSC) and a supercapacitor (SC), which can be used for energy conversation and storage, was introduced for the first time. A stainless steel wire coated with polyaniline via anodic deposition is jointly used as the electrode of the fib…

Advancements in Battery MaterialsSupercapacitor Materials and FabricationAdvanced battery technologies research

Electric-double-layer field-effect transistors with ionic liquids

Takuya Fujimoto、Kunio Awaga2013-01-01Physical Chemistry Chemical Physics

Charge carrier control is a key issue in the development of electronic functions of semiconductive materials. Beyond the simple enhancement of conductivity, high charge carrier accumulation can realize various phenomena, such as chemical reaction, phase transition, magnetic ordering, and superconductivity. Electric do…

Semiconductor materials and devicesElectrochemical Analysis and ApplicationsElectronic and Structural Properties of Oxides

In-Situ Raman Investigation of Polysulfide Formation in Li-S Cells

Markus Hagen、Peter Schiffels、Matt Hammer 等 8 位作者2013-01-01Journal of The Electrochemical Society

To obtain information about the Li-S reaction mechanism through spectroscopy, a Raman literature study, polysulfide vibrational mode calculations and experimental in-situ measurements were performed. A special test cell was constructed to examine in-situ Raman spectra in the spectral range from 100 cm −1 to 600 cm −1…

Advanced Battery Materials and TechnologiesSolid-state spectroscopy and crystallographyThermal and Kinetic Analysis

Hot spots in different metal nanostructures for plasmon-enhanced Raman spectroscopy

Hong Wei、Hongxing Xu2013-01-01Nanoscale

Noble metal nanostructures are able to concentrate light into small volumes, which enhances greatly the local electromagnetic (EM) field near the metal nanostructures. The areas with greatly enhanced EM field become "hot spots" for surface-enhanced Raman spectroscopy (SERS), which utilizes the field enhancement proper…

Gold and Silver Nanoparticles Synthesis and ApplicationsAdvanced biosensing and bioanalysis techniquesPlasmonic and Surface Plasmon Research

Cytotoxicity of Biologically Synthesized Silver Nanoparticles in MDA-MB-231 Human Breast Cancer Cells

Sangiliyandi Gurunathan、Jae Woong Han、Vasuki Eppakayala 等 5 位作者2013-01-01BioMed Research International

Silver nanoparticles (AgNPs) have been used as an antimicrobial and disinfectant agents. However, there is limited information about antitumor potential. Therefore, this study focused on determining cytotoxic effects of AgNPs on MDA-MB-231 breast cancer cells and its mechanism of cell death. Herein, we developed a gre…

Nanoparticle-Based Drug DeliveryNanoparticles: synthesis and applicationsGraphene and Nanomaterials Applications

3D nanostructured conductive polymer hydrogels for high-performance electrochemical devices

Yu Zhao、Borui Liu、Lijia Pan 等 4 位作者2013-01-01Energy & Environmental Science

Conducting polymer hydrogels (CPHs) represent a unique class of materials that synergize the advantageous features of hydrogels and organic conductors and have been used in many applications such as bioelectronics and energy storage devices. This perspective provides a brief overview of current research activities in…

Supercapacitor Materials and FabricationAdvanced Sensor and Energy Harvesting MaterialsConducting polymers and applications

Protein–polyelectrolyte interactions

A. Basak Kayitmazer、Daniel Seeman、Burcu Baykal Minsky 等 5 位作者2013-01-01Soft Matter

The interactions of proteins and polyelectrolytes lead to diverse applications in separations, delivery and wound repair, and are thus of interest to scientists in e.g. (a) glycobiology, (b) tissue engineering, (c) biosensing, and (d) pharmacology. This breadth is accompanied by an assortment of contexts and models in…

Proteins in Food SystemsPolymer Surface Interaction StudiesBlood properties and coagulation

Characterization of Cu-exchanged SSZ-13: a comparative FTIR, UV-Vis, and EPR study with Cu-ZSM-5 and Cu-β with similar Si/Al and Cu/Al ratios

Filippo Giordanino、Peter N. R. Vennestrøm、L. F. Lundegaard 等 8 位作者2013-01-01Dalton Transactions

Cu-SSZ-13 has been characterized by different spectroscopic techniques and compared with Cu-ZSM-5 and Cu-β with similar Si/Al and Cu/Al ratios and prepared by the same ion exchange procedure. On vacuum activated samples, low temperature FTIR spectroscopy allowed us to appreciate a high concentration of reduced copper…

Advanced Photocatalysis TechniquesCatalytic Processes in Materials ScienceZeolite Catalysis and Synthesis

Advanced materials for solid-state refrigeration

Lluı́s Mañosa、Antoni Planes、M. Acet2013-01-01Journal of Materials Chemistry A

Recent progress on caloric effects are reviewed. The application of external stimuli such as magnetic field, hydrostatic pressure, uniaxial stress and electric field give rise respectively to magnetocaloric, barocaloric, elastocaloric and electrocaloric effects. The values of the relevant quantities such as isothermal…

Ferroelectric and Piezoelectric MaterialsMagnetic and transport properties of perovskites and related materialsShape Memory Alloy Transformations

Flammability behaviour of wood and a review of the methods for its reduction

Laura Anne Lowden、T. Richard Hull2013-01-01Fire Science Reviews

Wood is one of the most sustainable, aesthetically pleasing and environmentally benign materials. Not only is wood often an integral part of structures, it is also the main source of furnishings found in homes, schools, and offices around the world. The often inevitable hazards of fire make wood a very desirable mater…

Fire dynamics and safety researchFlame retardant materials and propertiesForensic Fingerprint Detection Methods

Nanoparticle toxicity by the gastrointestinal route: evidence and knowledge gaps

Ingrid L. Bergin、Frank A. Witzmann2013-01-01International Journal of Biomedical Nanoscience and Nanotechnology

The increasing interest in nanoparticles for advanced technologies, consumer products, and biomedical applications has led to great excitement about potential benefits but also concern over the potential for adverse human health effects. The gastrointestinal tract represents a likely route of entry for many nanomateri…

Nanoparticles: synthesis and applicationsMicroplastics and Plastic PollutionGraphene and Nanomaterials Applications

Salt concentration, pH and pressure controlled separation of small molecules through lamellar graphene oxide membranes

Hubiao Huang、Yiyin Mao、Yulong Ying 等 6 位作者2013-01-01Chemical Communications

For the first time, pressure, salt concentration and pH demonstrated advantages for tuning the nanochannels within lamellar graphene oxide (LGO) membranes to control the separation of small molecules. This provides a new avenue for designing and engineering efficient LGO membranes for molecular separation.

Graphene research and applicationsMembrane Separation TechnologiesNanopore and Nanochannel Transport Studies

In situ growth of NiCo2S4 nanosheets on graphene for high-performance supercapacitors

Shengjie Peng、Linlin Li、Chengchao Li 等 10 位作者2013-01-01Chemical Communications

We demonstrate a facile hydrothermal method for growth of ultrathin NiCo2S4 nanosheets on reduced graphene oxide (RGO), which exhibit remarkable electrochemical performance with higher capacitance and longer cycle life than the bare NiCo2S4 hollow spheres (HSs).

Advancements in Battery MaterialsElectrocatalysts for Energy ConversionSupercapacitor Materials and Fabrication

Investigation of solid/vapor interfaces using ambient pressure X-ray photoelectron spectroscopy

David E. Starr、Zhi Liu、Michael Hävecker 等 5 位作者2013-01-01Chemical Society Reviews

Heterogeneous chemical reactions at vapor/solid interfaces play an important role in many processes in the environment and technology. Ambient pressure X-ray photoelectron spectroscopy (APXPS) is a valuable tool to investigate the elemental composition and chemical specificity of surfaces and adsorbates on the molecul…

Advanced Chemical Physics StudiesElectron and X-Ray Spectroscopy TechniquesElectronic and Structural Properties of Oxides

Self-healable polymer networks based on the cross-linking of epoxidised soybean oil by an aqueous citric acid solution

Facundo I. Altuna、Valeria Pettarin、R. J. J. Williams2013-01-01Green Chemistry

Epoxidised soybean oil (ESO) was cross-linked with an aqueous citric acid (CA) solution without the addition of any other catalyst or solvent. Completely bio-based polymer networks were generated. The initial system was an emulsion, but it became a homogeneous and transparent polymer network by reaction. The ability o…

Advanced Polymer Synthesis and CharacterizationPolymer composites and self-healingCarbon dioxide utilization in catalysis

Plasma-enhanced chemical vapor deposition synthesis of vertically oriented graphene nanosheets

Zheng Bo、Yong Yang、Junhong Chen 等 6 位作者2013-01-01Nanoscale

Vertically oriented graphene (VG) nanosheets have attracted growing interest for a wide range of applications, from energy storage, catalysis and field emission to gas sensing, due to their unique orientation, exposed sharp edges, non-stacking morphology, and huge surface-to-volume ratio. Plasma-enhanced chemical vapo…

Graphene research and applicationsSupercapacitor Materials and FabricationGraphene and Nanomaterials Applications