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Self-healable polymer networks based on the cross-linking of epoxidised soybean oil by an aqueous citric acid solution

Facundo I. Altuna、Valeria Pettarin、R. J. J. Williams2013-01-01Green Chemistry

Epoxidised soybean oil (ESO) was cross-linked with an aqueous citric acid (CA) solution without the addition of any other catalyst or solvent. Completely bio-based polymer networks were generated. The initial system was an emulsion, but it became a homogeneous and transparent polymer network by reaction. The ability o…

Advanced Polymer Synthesis and CharacterizationPolymer composites and self-healingCarbon dioxide utilization in catalysis

Plasma-enhanced chemical vapor deposition synthesis of vertically oriented graphene nanosheets

Zheng Bo、Yong Yang、Junhong Chen 等 6 位作者2013-01-01Nanoscale

Vertically oriented graphene (VG) nanosheets have attracted growing interest for a wide range of applications, from energy storage, catalysis and field emission to gas sensing, due to their unique orientation, exposed sharp edges, non-stacking morphology, and huge surface-to-volume ratio. Plasma-enhanced chemical vapo…

Graphene research and applicationsSupercapacitor Materials and FabricationGraphene and Nanomaterials Applications

Narrow bandgap colloidal metal chalcogenide quantum dots: synthetic methods, heterostructures, assemblies, electronic and infrared optical properties

Stephen V. Kershaw、Andrei S. Susha、Andrey L. Rogach2013-01-01Chemical Society Reviews

The chemistry, material processing and fundamental understanding of colloidal semiconductor nanocrystals (quantum dots) are advancing at an astounding rate, bringing the prospects of widespread commercialization of these novel and exciting materials ever closer. Interest in narrow bandgap nanocrystals in particular ha…

Quantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin FilmsNanocluster Synthesis and Applications

Recent advances in free-standing two-dimensional crystals with atomic thickness: design, assembly and transfer strategies

Xiaodong Zhang、Yi Xie2013-01-01Chemical Society Reviews

Free-standing two-dimensional (2D) crystals with atomic thickness have attracted extensive attention because of their novel electronic, optical, mechanical and biocompatible properties, and so on. In recent years, the study of atomically thick 2D crystals has mainly focused on the layered materials with weak van der W…

Graphene research and applications2D Materials and ApplicationsMXene and MAX Phase Materials

Luminescent distyrylbenzenes: tailoring molecular structure and crystalline morphology

Johannes Gierschner、Soo Young Park2013-01-01Journal of Materials Chemistry C

The last few years have seen a steady increase in small molecule based conjugated materials, which promise innovative (opto)electronic applications. This requires however a systematic understanding of structure–property relationships, which can only be achieved via libraries of structurally well-defined single crystal…

Perovskite Materials and ApplicationsLuminescence and Fluorescent MaterialsOrganoboron and organosilicon chemistry

Thermoplastic starches: Properties, challenges, and prospects

Abdorreza Mohammadi Nafchi、Mahdiyeh Moradpour、Maliheh Saeidi 等 4 位作者2013-01-01Starch - Stärke

Abstract Thermoplastic starch (TPS) polymers were reviewed in this article. This review was categorized into the following studies: the role of starch as a thermoplastic polymer, transformation and melting mechanisms, plasticization and plasticizers, reactive extrusion (REX) and modifications, retrogradation, biodegra…

Nanocomposite Films for Food Packagingbiodegradable polymer synthesis and propertiesElectrospun Nanofibers in Biomedical Applications

Flexible PEDOT electrodes with large thermoelectric power factors to generate electricity by the touch of fingertips

Teahoon Park、Chihyun Park、Byeonggwan Kim 等 5 位作者2013-01-01Energy & Environmental Science

Highly conductive PEDOT films were prepared by solution casting polymerization using finely tuned oxidation solution and used as electrodes for the precise control of the oxidation level of the polymer electrochemically. They exhibited a large power factor of 1,270 μW m−1 K−2 and could be processed as flexible and cut…

Advanced Sensor and Energy Harvesting MaterialsAdvanced Thermoelectric Materials and DevicesConducting polymers and applications

Fabrication of highly fluorescent graphene quantum dots using l-glutamic acid for in vitro/in vivo imaging and sensing

Xu Wu、Fei Tian、Wenxue Wang 等 6 位作者2013-01-01Journal of Materials Chemistry C

A facile bottom-up method for the synthesis of highly fluorescent graphene quantum dots (GQDs) has been developed using a one-step pyrolysis of a natural amino acid, L-glutamic acid, with the assistance of a simple heating mantle device. The developed GQDs showed strong blue, green and red luminescence under irradiati…

Carbon and Quantum Dots ApplicationsNanocluster Synthesis and ApplicationsGraphene and Nanomaterials Applications

Extracellular synthesis of zinc oxide nanoparticle using seaweeds of gulf of Mannar, India

Sangeetha Nagarajan、K. Kuppusamy2013-01-01Journal of Nanobiotechnology

BACKGROUND: The biosynthesis of metal nanoparticles by marine resources is thought to be clean, nontoxic, and environmentally acceptable "green procedures". Marine ecosystems are very important for the overall health of both marine and terrestrial environments. The use of natural sources like Marine biological resourc…

Nanoparticles: synthesis and applicationsSeaweed-derived Bioactive CompoundsMarine Biology and Environmental Chemistry

Upconversion Nanoparticles for Photodynamic Therapy and Other Cancer Therapeutics

Chao Wang、Liang Cheng、Zhuang Liu2013-01-01Theranostics

Photodynamic therapy (PDT) is a non-invasive treatment modality for a variety of diseases including cancer. PDT based on upconversion nanoparticles (UCNPs) has received much attention in recent years. Under near-infrared (NIR) light excitation, UCNPs are able to emit high-energy visible light, which can activate surro…

Luminescence Properties of Advanced MaterialsNanoplatforms for cancer theranosticsPhotodynamic Therapy Research Studies

Towards high-performance polymer-based thermoelectric materials

Ming He、Feng Qiu、Zhiqun Lin2013-01-01Energy & Environmental Science

Thermoelectric materials have garnered considerable attention due to their unique ability to directly convert heat to electricity and vice versa. Polymers carry many intrinsic advantages such as low thermal conductivity, solution processability, and roll-to-roll production for fabricating high-performance, light-weigh…

Advanced Thermoelectric Materials and DevicesConducting polymers and applicationsThermal properties of materials

Self-healing systems based on disulfide–thiol exchange reactions

Mark P. F. Pepels、Ivo A. W. Filot、Bert Klumperman 等 4 位作者2013-01-01Polymer Chemistry

New thermoset systems based on disulfide bonds were synthesized with self-healing capabilities. The self-healing mechanism is not related to disulfide–disulfide exchange reactions, but to thiol–disulfide exchange reactions that are pH-dependent. Stress relaxation experiments showed large relaxation for systems having…

Polymer composites and self-healingSynthesis and properties of polymersPhotopolymerization techniques and applications

Lessons learned from dinuclear lanthanide nano-magnets

Fatemah Habib、Muralee Murugesu2013-01-01Chemical Society Reviews

The quest for higher density information storage has led to the investigation of Single-Molecule Magnets (SMMs) as potential molecules to be applied in materials such as hard discs. In order for this to occur, one must first design metal complexes which can retain magnetic information at temperatures where these appli…

Magnetism in coordination complexesLanthanide and Transition Metal ComplexesOrganic and Molecular Conductors Research

Techniques for fabrication and construction of three-dimensional scaffolds for tissue engineering

Tingli Lu、Yuhui Li、Tao Chen2013-01-01International Journal of Nanomedicine

Three-dimensional biomimetic scaffolds have widespread applications in biomedical tissue engineering because of their nanoscaled architecture, eg, nanofibers and nanopores, similar to the native extracellular matrix. In the conventional "top-down" approach, cells are seeded onto a biocompatible and biodegradable scaff…

Electrospun Nanofibers in Biomedical Applications3D Printing in Biomedical ResearchTissue Engineering and Regenerative Medicine

Synthesis of CuO Nanoparticles by Precipitation Method Using Different Precursors

Kankanit Phiwdang、Sineenart Suphankij、Wanichaya Mekprasart 等 4 位作者2013-01-01Energy Procedia

CuO nanoparticles were synthesized by precipitation method using different precursors as copper nitrate (Cu(NO3)2) and copper chloride (CuCl2) with post-heating comparing between as-synthesized and after calcinations. Relevant properties of as-synthesized nanoparticles were investigated by X-ray diffraction (XRD), sca…

ZnO doping and propertiesCopper-based nanomaterials and applicationsElectronic and Structural Properties of Oxides

Recent advances in water/alcohol-soluble π-conjugated materials: new materials and growing applications in solar cells

Chunhui Duan、Kai Zhang、Chengmei Zhong 等 5 位作者2013-01-01Chemical Society Reviews

Water/alcohol-soluble conjugated polymers (WSCPs) and small molecules (WSCSs) are materials that can be processed from water or other polar solvents. They provide good opportunities to fabricate multilayer organic optoelectronic devices without interface mixing by solution processing, and exhibit a promising interface…

Organic Electronics and PhotovoltaicsPerovskite Materials and ApplicationsConducting polymers and applications

Designing electrospun nanofiber mats to promote wound healing – a review

Katrina A. Rieger、Nathan P. Birch、Jessica D. Schiffman2013-01-01Journal of Materials Chemistry B

Current strategies to treat chronic wounds offer limited relief to the 7.75 million patients who suffer from burns or chronic skin ulcers. Thus, as long as chronic wounds remain a global healthcare problem, the development of alternate treatments remain desperately needed. This review explores the recent strategies em…

Electrospun Nanofibers in Biomedical ApplicationsWound Healing and TreatmentsSilk-based biomaterials and applications

Design of vanadium oxide structures with controllable electrical properties for energy applications

Changzheng Wu、Feng Feng、Yi Xie2013-01-01Chemical Society Reviews

The electrical properties of inorganic materials has been a long-standing pursued research topic, and successfully controlling the electrical property of an inorganic material has attracted significant attention for a wide range of energy-related applications, covering energy storage, energy conversion and energy util…

Magnetic and transport properties of perovskites and related materialsTransition Metal Oxide NanomaterialsAdvanced Condensed Matter Physics

Superparamagnetic Iron Oxide Nanoparticles as MRI contrast agents for Non-invasive Stem Cell Labeling and Tracking

Li Li、Wen Jiang、Kui Luo 等 7 位作者2013-01-01Theranostics

Stem cells hold great promise for the treatment of multiple human diseases and disorders. Tracking and monitoring of stem cells in vivo after transplantation can supply important information for determining the efficacy of stem cell therapy. Magnetic resonance imaging (MRI) combined with contrast agents is believed to…

Nanoparticle-Based Drug DeliveryMicrofluidic and Bio-sensing TechnologiesMolecular Communication and Nanonetworks

Porous carbon-based materials for hydrogen storage: advancement and challenges

Yongde Xia、Zhuxian Yang、Yanqiu Zhu2013-01-01Journal of Materials Chemistry A

The development of highly efficient hydrogen storage materials is one of the main challenges that must be tackled in a widely expected hydrogen economy. Physisorption in porous materials with high surface areas and chemisorption in hydrides are the two main options for solid state hydrogen storage, and both options po…

Hydrogen Storage and MaterialsAmmonia Synthesis and Nitrogen ReductionNanomaterials for catalytic reactions