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Synthesis of highly thermostable copper-nickel nanoparticles confined in the channels of ordered mesoporous SBA-15 silica

Adrian Ungureanu、Brînduşa Drăgoi、Alexandru Chirieac 等 6 位作者2011-01-01Journal of Materials Chemistry

CuNi nanoparticles were effectively confined in the mesopores of SBA-15 silica by a simple incipient wetness impregnation method. After impregnation, the samples were dried at room temperature, which is considered as the key preparation step to obtain high and stable dispersions of the supported CuNi nanoparticles, ir…

Catalytic Processes in Materials ScienceMesoporous Materials and CatalysisNanomaterials for catalytic reactions

A novel morphological model for carbon nanotube/polymer composites having high thermal conductivity and electrical insulation

Takuya Morishita、Mitsumasa Matsushita、Yoshihide Katagiri 等 4 位作者2011-01-01Journal of Materials Chemistry

Carbon nanotubes (CNTs), owing to their extremely high thermal conductivity (∼3000 W m−1 K−1), have recently attracted attention as notable nanofiller candidates to improve the thermal conductivity of polymers. However, CNTs cannot practically be used for highly electrically insulating polymers because even a few CNTs…

Carbon Nanotubes in CompositesThermal properties of materialsDielectric materials and actuators

One-step vapour-phase formation of patternable, electrically conductive, superamphiphobic coatings on fibrous materials

Hongxia Wang、Yuhua Xue、Tong Lin2011-01-01Soft Matter

Patternable, electrically conductive coatings having a superhydrophobic and superoleophobic surface have been prepared by one-step vapour-phase polymerisation of polypyrrole in the presence of a fluorinated alkyl silane directly on fibrous substrates. The coated fabrics showed a surface resistance of 0.5–0.8 kΩ □−1 wi…

Surface Modification and SuperhydrophobicityAdvanced Sensor and Energy Harvesting MaterialsElectrowetting and Microfluidic Technologies

Shape Memory and Superelastic Alloys : Technologies and Applications

I. Yamauchi、K Ohkata、修一 宮崎2011-01-01Medical Entomology and Zoology

Contributor contact details Preface Part I: Properties and processing Chapter 1: Mechanisms and properties of shape memory effect and superelasticity in alloys and other materials: a practical guide Abstract: 1.1 Introduction 1.2 Properties of shape memory alloys (SMAs) 1.3 Fundamentals of shape memory alloys (SMAs) 1…

Shape Memory Alloy Transformations

Mechanics of carbon nanotube networks: microstructural evolution and optimal design

Bo Xie、Yilun Liu、Yiting Ding 等 5 位作者2011-01-01Soft Matter

Carbon nanotube networks feature outstanding mechanical performance, and also hierarchical structures and network topologies. In this paper we investigate their structure–property relationship through mesoscale molecular dynamics simulations. We find that their microstructures undergo remarkable evolution under mechan…

Carbon Nanotubes in CompositesCellular and Composite StructuresFiber-reinforced polymer composites

A novel sandwich-type polyoxometalate compound with visible-light photocatalytic H2 evolution activity

Zhenyu Zhang、Qipu Lin、Shou‐Tian Zheng 等 5 位作者2011-01-01Chemical Communications

A tin(II) tungstosilicate derivative K(11)H[Sn(4)(SiW(9)O(34))(2)]·25H(2)O with four sandwiched Sn(2+) cations was prepared by reaction of SnCl(2), KCl and Na(10)[α-SiW(9)O(34)]·xH(2)O. Visible-light photocatalytic H(2) evolution activity was observed with Pt nanoparticles as co-catalyst and methanol as sacrificial ag…

Advanced Photocatalysis TechniquesPolyoxometalates: Synthesis and ApplicationsAdvanced Nanomaterials in Catalysis

Self-diffusion of the amorphous pharmaceutical indomethacin near Tg

Stephen F. Swallen、M. D. Ediger2011-01-01Soft Matter

Secondary ion mass spectrometry has been utilized to measure self-diffusion coefficients D in supercooled indomethacin from 310 K to 350 K (Tg = 315 K). Over this temperature range, D varies from 10−17 cm2s−1 to 10−11 cm2s−1. The temperature dependence of D is significantly weaker than the temperature dependence of th…

Phase Equilibria and ThermodynamicsMaterial Dynamics and PropertiesThermodynamic properties of mixtures

Hydrothermal synthesis of copper selenides with controllable phases and morphologies from an ionic liquid precursor

Xiaodi Liu、Xiaochuan Duan、Peng Peng 等 4 位作者2011-01-01Nanoscale

Cu2−xSe nanocrystals and CuSe nanoflakes are successfully synthesized through a convenient hydrothermal method from an ionic liquid precursor 1-n-butyl-3-ethylimidazolium methylselenite ([BMIm][SeO2(OCH3)]). The phases and morphologies of the copper selenides can be controlled by simply changing the atom ratio of Cu/S…

Quantum Dots Synthesis And PropertiesIonic liquids properties and applicationsCopper-based nanomaterials and applications

Formation mechanism of Fe2O3 hollow fibers by direct annealing of the electrospun composite fibers and their magnetic, electrochemical properties

Yongliang Cheng、Binglin Zou、Chunjie Wang 等 9 位作者2011-01-01CrystEngComm

Fe2O3 hollow fibers have been fabricated by direct annealing electrospun polyvinylpyrrolidone (PVP)/Fe(NO3)3 composite nanofibers. In this approach, composite fibers were firstly synthesized by electrospinning PVP/Fe(NO3)3 solution, and then calcined at high temperature with an appropriate heating rate to form hollow…

Advancements in Battery MaterialsSupercapacitor Materials and FabricationElectrospun Nanofibers in Biomedical Applications

Photochromic polymers bearing various diarylethene chromophores as the pendant: synthesis, optical properties, and multicolor photochromism

Hiroyasu Nishi、Tomoko Namari、Seiya Kobatake2011-01-01Journal of Materials Chemistry

Photochromic polymers with various diarylethene derivatives were synthesized by a conventional radical polymerization of styrene derivatives having diarylethene chromophores as the pendant. All the polymers exhibited reversible photochromism in the film as well as in solution, while the photocyclization conversion in…

Olfactory and Sensory Function StudiesPhotochromic and Fluorescence ChemistryPolydiacetylene-based materials and applications

A hybrid magnet with coexistence of ferromagnetism and photoinduced Fe(iii) spin-crossover

Miguel Clemente‐León、Eugenio Coronado、M. López-Jordà 等 7 位作者2011-01-01Chemical Science

The insertion of a [Fe(sal2-trien)]+ complex cation into a 2D oxalate network results in a hybrid magnet with coexistence of magnetic ordering and photoinduced spin-crossover (LIESST effect) in compound [FeIII(sal2-trien)][MnIICrIII(ox)3]·(CH2Cl2) (1). A complete photomagnetic characterization together with a detailed…

Magnetism in coordination complexesMetal-Catalyzed Oxygenation MechanismsOrganic and Molecular Conductors Research

pH-driven physicochemical conformational changes of single-layer graphene oxide

Raymond L. D. Whitby、Alina V. Korobeinyk、В.М. Гунько 等 12 位作者2011-01-01Chemical Communications

Single-layer graphene oxides (SLGOs) undergo morphological changes depending on the pH of the system and may account for restricted chemical reactivity. Herein, SLGO may also capture nanoparticles through layering and enveloping when the pH is changed, demonstrating potential usefulness in drug delivery or waste mater…

Advancements in Battery MaterialsGraphene research and applicationsGraphene and Nanomaterials Applications

Intercalation and grafting of benzene derivatives into zinc–aluminum and copper–chromium layered double hydroxide hosts: an XPS monitoring study

Solenne Fleutot、Jean‐Charles Dupin、Guillaume Renaudin 等 4 位作者2011-01-01Physical Chemistry Chemical Physics

We report an original strategy to describe, via X-ray photoelectron spectroscopy (XPS) measurements, the interactions between the organic and the mineral sub-systems within a multifunctional hybrid material. A tunable layered double hydroxide (LDH) host system, either a Zn(2)Al- or Cu(2)Cr-hydrotalcite like compound,…

Layered Double Hydroxides Synthesis and ApplicationsInorganic Chemistry and MaterialsMagnesium Oxide Properties and Applications

Direct evidence of potential barriers at grain boundaries in Y-doped BaZrO3 from dc-bias dependence measurements

Fumitada Iguchi、Chien‐Ting Chen、Hiroo Yugami 等 4 位作者2011-01-01Journal of Materials Chemistry

Y-doped BaZrO3 (BZY) is an outstanding proton conductor under wet atmosphere at relatively low temperatures (<600 °C). Dense polycrystalline ceramics of this material used in intermediate-temperature solid oxide fuel cells as solid electrolytes, however, suffer from uniquely high resistance across grain boundaries in…

Advancements in Solid Oxide Fuel CellsMagnetic and transport properties of perovskites and related materialsElectronic and Structural Properties of Oxides

Intrinsic Dissolution as a Tool for Evaluating Drug Solubility in Accordance with the Biopharmaceutics Classification System

Michéle Georges Issa、Humberto Gomes Ferraz2011-01-01Dissolution Technologies

The Biopharmaceutics Classification System (BCS) is a tool that was created to categorize drugs into different groups according to their solubility and permeability characteristics. Through a combination of these factors and physiological parameters, it is possible to understand the absorption behavior of a drug in th…

Drug Solubulity and Delivery SystemsProtein purification and stabilityCrystallization and Solubility Studies

Adsorption of core-shell nanoparticles at liquid–liquid interfaces

Lucio Isa、Esther Amstad、Konrad Schwenke 等 7 位作者2011-01-01Soft Matter

The use of nanoparticles as building blocks for the self-assembly of functional materials has been rapidly increasing in recent years. In particular, two-dimensional materials can be effectively self-assembled at liquid interfaces thanks to particle localization and mobility at the interface in combination with tailor…

Surfactants and Colloidal SystemsPolymer Surface Interaction StudiesPickering emulsions and particle stabilization

Room temperature photo-induced phase transitions of VO2 nanodevices

Jyh Ming Wu、Lian Bang Liou2011-01-01Journal of Materials Chemistry

We have successfully fabricated VO2 nanodevices using a photo-induced phase transition mechanism under an ultraviolet-light (λ = 365 nm, I = 7 μW cm−2). On the obtained VO2 nanowires, the photo-induced insulator-to-metal (IM) phase transition occurred from monoclinic (insulator or semiconductor) to tetragonal (metal)…

Gas Sensing Nanomaterials and SensorsTransition Metal Oxide NanomaterialsGa2O3 and related materials

Multimodality and nanoparticles in medical imaging

Wen-Yen Huang、Jason J. Davis2011-01-01Dalton Transactions

A number of medical imaging techniques are used heavily in the provision of spatially resolved information on disease and physiological status and accordingly play a critical role in clinical diagnostics and subsequent treatment. Though, for most imaging modes, contrast is potentially enhanced through the use of contr…

Nanoparticle-Based Drug DeliveryNanoplatforms for cancer theranosticsLanthanide and Transition Metal Complexes

Controlled synthesis of magnetic iron oxides@SnO2 quasi-hollow core–shell heterostructures: formation mechanism, and enhanced photocatalytic activity

Wei Wu、Shaofeng Zhang、Feng Ren 等 6 位作者2011-01-01Nanoscale

Iron oxide/SnO(2) magnetic semiconductor core-shell heterostructures with high purity were synthesized by a low-cost, surfactant-free and environmentally friendly hydrothermal strategy via a seed-mediated method. The morphology and structure of the hybrid nanostructures were characterized by means of high-resolution t…

Advanced Photocatalysis TechniquesZnO doping and propertiesCopper-based nanomaterials and applications

Production and Characterization of Cellulose Nanofibers from Wood Pulp

Nazia Siddiqui、Ryan H. Mills、Douglas J. Gardner 等 4 位作者2011-01-01Journal of Adhesion Science and Technology

Cellulose nanofibers with a size range of 5–100 nm have the potential to be a low cost renewable material that has application in a range of products. However, current chemical methods to produce crystalline nanofibers suffer from low yields and high chemical costs, while mechanical methods require high energy costs.…

Nanocomposite Films for Food PackagingAdvanced Cellulose Research StudiesLignin and Wood Chemistry