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Mechanistic Modeling of a 1-Phenyloctane/n-Hexadecane Mixture on Rare Earth Y Zeolite

Beth A. Watson、Michael T. Klein、Robert H. Harding1997-08-01Industrial & Engineering Chemistry Research

A mechanism-derived lumping strategy for modeling the acid-cracking kinetics of hydrocarbon mixtures based on a limited set of pure component experimental data was tested in terms of its ability to predict the kinetics and product spectra from the reaction of a 1-phenyloctane/ n -hexadecane mixture. The modeling appro…

Zeolite Catalysis and SynthesisInorganic and Organometallic ChemistryThermal and Kinetic Analysis

EPR of hole centers in nonlinear LiBO3 crystals

A. V. Porotnikov、И. Н. Огородников、S. V. Kudyakov 等 5 位作者1997-08-01Physics of the Solid State

Results are presented of an EPR study of theO − hole center in LiB 3 O 5 (lithium triborate) crystals. Analysis of angular dependences of EPR spectra is used to determine the principal values of the g tensor ( g XX =2.032, g YY =2.020, g ZZ =2.007), along with the modulus of the isotropic part of the A 2 tensor (| A |…

High-pressure geophysics and materialsCrystal Structures and PropertiesX-ray Diffraction in Crystallography

The Quantification of Different Forms of Cristobalite in Devitrified Alumino-Silicate Ceramic Fibres

M. A. Butler、D. J. Dyson1997-08-01Journal of Applied Crystallography

When heat treated, amorphous alumino-silicate fibres will devitrify into crystalline phases which on cooling become stable at room temperature. X-ray diffraction has been used to identify and quantify the phases present in such products; mullite and two distinct forms of cristobalite have been observed. One form of cr…

Advanced ceramic materials synthesisGlass properties and applicationsRecycling and utilization of industrial and municipal waste in materials production

High‐Temperature Automotive Catalytic Nitrogen Oxide Reduction over Copper–Lanthanum–Alumina

Masakuni Ozawa、Suguru SUZUKI、H. Toda1997-08-01Journal of the American Ceramic Society

The synthesis and nitrogen oxide (NO) removal activities of composite powders in the copper‐lanthanum‐alumina(Cu‐La‐Al 2 O 3 )system were studied, in regard to their high‐temperature application as an automotive lean‐burn exhaust catalyst. The solid‐state reaction between the copper, the lanthanum, and the Al 2 O 3 su…

Advanced ceramic materials synthesisCatalytic Processes in Materials ScienceMagnesium Oxide Properties and Applications

Dynamic Behavior of High Strength Armor Steels

H. Nahme、E. Lach1997-08-01Journal de Physique IV (Proceedings)

HAL is a multi-disciplinary open access archive for the deposit and dissemination of sci-entific research documents, whether they are pub-lished or not. The documents may come from teaching and research institutions in France or abroad, or from public or private research centers. L’archive ouverte pluridisciplinaire H…

Metal and Thin Film MechanicsHigh-Velocity Impact and Material BehaviorElectromagnetic Launch and Propulsion Technology

Minimizing the residual oxygen in modified atmosphere packaging of bakery products

Luciano Piergiovanni、Patrizia Fava1997-08-01Food Additives & Contaminants

The total elimination of air represents a serious hurdle in modified atmosphere packaging of bakery products, due both to the high spin-rates of the packaging lines and, particularly, to the typical texture of bakery products which retain large quantities of air inside their porous structure. Simulating the gas-flushi…

Postharvest Quality and Shelf Life ManagementNanocomposite Films for Food PackagingConsumer Packaging Perceptions and Trends

Experimental determination of Landau-expansion coefficients in ferroelectric liquid crystals

F. Gieβszelmann、A. Heimann、P. Zugenmaier1997-08-01Ferroelectrics

A technique of measuring basic Landau-expansion coefficients in ferroelectric liquidcrystals is proposed. The method is based on combined measurements of the tilt angle andthe total polarization of ferroelectric liquid crystals at various temperatures and electric field strength in the vicinity of the ferroelectric S*…

Liquid Crystal Research AdvancementsPlant Reproductive BiologyMolecular spectroscopy and chirality

End‐group dynamics of fluorescently labeled dendrimers

Ralph Wilken、Jörg Adams1997-08-01Macromolecular Rapid Communications

Abstract The molecular dynamics of dendrimer branches were studied by observing the excimer formation of pyrenyl end‐groups. By a selective synthesis only one pyrene moiety per dendron was attached, resulting in a dendrimer with 3 fluorophors per molecule. The first 3 generations of the dendrimer were synthesized by t…

Advanced Polymer Synthesis and CharacterizationLuminescence and Fluorescent MaterialsDendrimers and Hyperbranched Polymers

Influence of the network on the interaction parameter in system EPDM vulcanizate-solvent

Z. Hrnjak-Murgi、J. Jelen i、M. Bravar 等 4 位作者1997-08-01Journal of Applied Polymer Science

Swelling measurements in six organic solvents were carried out on samples of dicumyl peroxide crosslinked ethylene–propylene–diene (EPDM) having various crosslink densities. The Flory–Huggins interaction parameter χ was determined for EPDM vulcanizates 312 and 812 as well as their mixture 312/812 using the Flory–Rehne…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesAnalytical Chemistry and Sensors

Thermally-Stimulated Depolarization Studies of the Ice XI−Ice Ih Phase Transition

Susan M. Jackson、R. W. Whitworth1997-08-01The Journal of Physical Chemistry B

Thermally-stimulated depolarization measurements on single-crystal specimens of KOH-doped ice have shown that the crystal structure of ice XI has ferroelectric ordering parallel to its c -axis. The charge-release peak identified with the detransformation of ice XI to ice Ih is produced at the 72 K transition temperatu…

Liquid Crystal Research AdvancementsMaterial Dynamics and PropertiesSolid-state spectroscopy and crystallography

Segmental and chain orientational behavior of spandex fibers

Han Sup Lee、Jung Hwan Ko、Ki Suk Song 等 4 位作者1997-08-01Journal of Polymer Science Part B Polymer Physics

The internal structure and orientation behavior of two series of spandex fibers, which were made with different spinning methods and different soft and hard segment types, were studied by FTIR (Fourier Transform Infrared Spectroscopy), polarizing light microscopy, and Instron. The orientation behavior of hard and soft…

Advanced Sensor and Energy Harvesting MaterialsNatural Fiber Reinforced CompositesTextile materials and evaluations

The Application of ab-initio Linear Combination of Pseudo-Atomic-Orbital Scheme for the Electronic Structure of Lithium Azide LiN3

A. B. Gordienko、А. С. Поплавной1997-08-01physica status solidi (b)

The results of total energy, band structure, density of states and charge density calculations for lithium azide using an ab-initio technique of pseudo-atomic orbitals are presented. The computations are performed based on the density functional theory within a local density approximation applying the basis of sp3d5 p…

Machine Learning in Materials ScienceElectron and X-Ray Spectroscopy TechniquesInorganic Chemistry and Materials

Kinetics of Dealloying of a Copper‐5 Atomic Percent Gold Alloy

Badr G. Ateya、James D. Fritz、Howard W. Pickering1997-08-01Journal of The Electrochemical Society

The dealloying of a Cu‐5 atom percent Au (Cu5Au) alloy was studied using coulometry, rotating disk electrode, transmission electron microscopy, selected area diffraction, and x‐ray diffraction techniques. The polarization behavior of Cu5Au is similar to that of pure Cu, showing no discernible passive region or critica…

Copper-based nanomaterials and applicationsNanomaterials for catalytic reactionsNanoporous metals and alloys

Dislocation Mechanics Based analysis of Material Dynamics Behavior : Enhanced Ductility, Deformation Twinning, Shock Deformation, Shear Instability, Dynamic Recovery

Frank J. Zerilli、Ronald W. Armstrong1997-08-01Journal de Physique IV (Proceedings)

Further developments are described for the dislocation mechanics based constitutive equation analysis previously used to describe the separate dynamic stress-strain behavior of fcc and bcc metal polycrystals. An enhanced hardening and ductility in copper and certain tantalum materials at higher strain rates in split H…

Microstructure and mechanical propertiesMetal and Thin Film MechanicsHigh-Velocity Impact and Material Behavior

Variants of the receptor/channel clustering molecule gephyrin in brain: Distinct distribution patterns, developmental profiles, and proteolytic cleavage by calpain

Brian T. Kawasaki、Keith B. Hoffman、Robert S. Yamamoto 等 4 位作者1997-08-01Journal of Neuroscience Research

The postsynaptic molecule gephyrin is involved in clustering neurotransmitter receptors. To test for protein variants that correspond to alternatively spliced gephyrin mRNAs, antibodies were made against 1) an amino-terminal domain of gephyrin (GN(N)) and 2) its invariant carboxy-terminus (GN(C)). Both antibodies reco…

Neuroscience and Neuropharmacology ResearchLipid Membrane Structure and BehaviorPorphyrin and Phthalocyanine Chemistry

Impact Tensile Strength and Fracture of Concrete

M. Diamaruya、H. Kobayashi、T. Nonaka1997-08-01Journal de Physique IV (Proceedings)

This paper is concerned with a new measuring method for impact tensile strength of brittle materials such as ceramics, concrete and so forth. The method is based on the superposition and concentration of tensile stress waves reflected both from the free ends of a specimen and a striking bar. By making use of the Hopki…

High-Velocity Impact and Material BehaviorStructural Response to Dynamic LoadsEngineering and Material Science Research

A hydrous Ca-bearing magnesium carbonate from playa lake sediments, Salines Lake, Spain

I. Queralt、Ramón Julià、F. Plana 等 4 位作者1997-08-01American Mineralogist

Other| August 01, 1997 A hydrous Ca-bearing magnesium carbonate from playa lake sediments, Salines Lake, Spain Ignasi Queralt; Ignasi Queralt Institute of Earth Sciences "Jaume Almera" (CSIC), Barcelona, Spain Search for other works by this author on: GSW Google Scholar Ramon Julia; Ramon Julia Search for other works…

Paleontology and Stratigraphy of FossilsCalcium Carbonate Crystallization and InhibitionGeochemistry and Elemental Analysis

Thermochemistry and the enthalpy of formation of synthetic end-member (CaTiSiO 5 ) titanite

Dimitrios Xirouchakis、Sophie Fritsch、Robert L. Putnam 等 5 位作者1997-08-01American Mineralogist

Other| August 01, 1997 Thermochemistry and the enthalpy of formation of synthetic end-member (CaTiSiO5) titanite Dimitrios Xirouchakis; Dimitrios Xirouchakis State University of New York at Stony Brook, Center for High Pressure Research, Stony Brook, NY, United States Search for other works by this author on: GSW Goog…

Geological and Geochemical AnalysisGlass properties and applicationsClay minerals and soil interactions

Heterosupramolecular Chemistry: Self-Assembly of an Electron Donor (TiO2 Nanocrystallite)−Acceptor (Viologen) Complex

Lucy Cusack、Xavier Marguerettaz、S. Nagaraja Rao 等 5 位作者1997-08-01Chemistry of Materials

A TiO 2 nanocrystallite has been modified to selectively bind, by complementary hydrogen bonding, a uracil substrate incorporating a viologen moiety. Bandgap excitation of the self-assembled donor (TiO 2 nanocrystallite)−acceptor (viologen) complex results in electron transfer. Some implications of these findings for…

Gold and Silver Nanoparticles Synthesis and ApplicationsQuantum Dots Synthesis And PropertiesMolecular Junctions and Nanostructures