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New Renewable Resource Amphiphilic Molecular Design for Size-Controlled and Highly Ordered Polyaniline Nanofibers

Parambath Anilkumar、M. Jayakannan2006-05-19Langmuir

We demonstrate here, for the first time, a unique strategy for conducting polyaniline nanofibers based on renewable resources. Naturally available cardanol, which is an industrial waste and main pollutant from the cashew nut industry, is utilized for producing well-defined polyaniline nanofibers. A new amphiphilic mol…

Electrochemical sensors and biosensorsAdvanced Sensor and Energy Harvesting MaterialsConducting polymers and applications

Model-Based Construction of Calcium Sulfate Phase-Transition Diagrams in the HCl−CaCl2−H2O System between 0 and 100 °C

Zhibao Li、George P. Demopoulos2006-05-19Industrial & Engineering Chemistry Research

Phase-transition diagrams of three CaSO 4 phases, namely, dihydrate, hemihydrate, and anhydrate, in the HCl−CaCl 2 −H 2 O system are successfully constructed making use of a recently developed OLI-based chemical model. After initial validation of the model by comparison to experimentally determined CaSO 4 phase-transi…

Calcium Carbonate Crystallization and InhibitionCrystallization and Solubility StudiesChemical and Physical Properties in Aqueous Solutions

Amplified Fluorescence Quenching of a Conjugated Polyelectrolyte Mediated by Ca2+

Hui Jiang、Xiaoyong Zhao、Kirk S. Schanze2006-05-19Langmuir

The fluorescence of conjugated polyelectrolytes (CPEs) is quenched with very high efficiency by small molecule quenchers. This effect has been referred to as amplified quenching. In the present communication, we demonstrate that aggregation of a poly(phenylene ethynylene)-type CPE (PPE-CO2-) induced by Ca2+ has a pron…

Conducting polymers and applicationsLuminescence and Fluorescent MaterialsPolydiacetylene-based materials and applications

The Anomalous Infrared Transmission of Gold Films on Two‐Dimensional Colloidal Crystals

P. Zhan、Z. L. Wang、Han Dong 等 9 位作者2006-05-19Advanced Materials

Plasmonic crystals with submicrometer periodicity and extraordinary dispersion properties that depend on the polarization of incident light are obtained by partially covering silica or polystyrene spheres with a thin gold film (see figure). The optical properties of these two-dimensional ordered metallodielectric micr…

Gold and Silver Nanoparticles Synthesis and ApplicationsPlasmonic and Surface Plasmon ResearchPhotonic Crystals and Applications

Vapour-transport-deposition growth of ZnO nanostructures: switch betweenc-axial wires anda-axial belts by indium doping

Hong Jin Fan、Bodo Fuhrmann、Roland W. Scholz 等 11 位作者2006-05-19Nanotechnology

ZnO nanowires and nanobelts are two representatives of one-dimensional semiconductor nanomaterials possessing potential applications as optoelectronic and sensor devices. In this study, we applied a vapour-transport-deposition method to synthesize both types of nanostructures using relatively low temperatures (860 °C)…

ZnO doping and propertiesQuantum Dots Synthesis And PropertiesGas Sensing Nanomaterials and Sensors

Triply Fused ZnII–Porphyrin Oligomers: Synthesis, Properties, and Supramolecular Interactions with Single‐Walled Carbon Nanotubes (SWNTs)

Fuyong Cheng、Sheng Zhang、Alex Adronov 等 5 位作者2006-05-19Chemistry - A European Journal

The photophysical, electrochemical, and self-assembly properties of a novel triply fused Zn(II)-porphyrin trimer were investigated and compared to the properties of a triply fused porphyrin dimer and the analogous monomer. The trimer exhibited significantly red-shifted absorption bands relative to the corresponding mo…

Porphyrin and Phthalocyanine ChemistryMolecular Junctions and NanostructuresSurface Chemistry and Catalysis

Multiscale Experimental Approach for Developing High-Performance Intumescent Coatings

Maude Jimenez、Sophie Duquesne、Serge Bourbigot2006-05-19Industrial & Engineering Chemistry Research

The goal of this work is to combine small-scale screening tests permitting, during the laboratory research phase of a development, the optimization of intumescent mastic coatings formulated to protect steel in the case of hydrocarbon fire. This type of coating, applied on steel plates, beams, or columns, is usually ev…

Polymer Nanocomposites and PropertiesFire dynamics and safety researchFlame retardant materials and properties

Production and Characterization of Stable Superhydrophobic Surfaces Based on Copper Hydroxide Nanoneedles Mimicking the Legs of Water Striders

Xufeng Wu、Gaoquan Shi2006-05-19The Journal of Physical Chemistry B

The present work reports a simple and economic route for production and characterization of stable superhydrophobic surfaces from thin copper layers coated on arbitrary solid substrates. The thin copper layer was anodized in a 2 M aqueous solution of potassium hydroxide to form a thin film of copper hydroxide nanoneed…

Surface Modification and SuperhydrophobicityFluid Dynamics and Thin FilmsAerogels and thermal insulation

Study of Intercalation and Exfoliation Processes in Polymer Nanocomposites

Mosto Bousmina2006-05-19Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVNoteNEXTStudy of Intercalation and Exfoliation Processes in Polymer NanocompositesMosto BousminaView Author Information Department of Chemical Engineering, CREPEC, Canada Research Chair on Polymer Physics and Nanomaterials, Steacie Fellowship, Laval University, Ste-Foy, Quebec G1C 7P4,…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesPolymer Nanocomposite Synthesis and Irradiation

Gadolinium—a specific trigger for the development of nephrogenic fibrosing dermopathy and nephrogenic systemic fibrosis?

Thomas Grobner2006-05-19Nephrology Dialysis Transplantation

Nephrol Dial Transplant April 2006; 21: 1104–1108 The author would like to apologize for the error published in the article. After personal communication with the radiologists the administered Gd-contained contrast agent was documented in the MR examination reports of the mentioned nine patients incompletely and inexa…

Lanthanide and Transition Metal Complexes

Magnetic unipolar features in con- ductivity of point contacts between normal and ferromagnetic d-metals (Co, Ni, Fe)

Yu. G. Naidyuk、I. K. Yanson、D. L. Bashlakov 等 9 位作者2006-05-19arXiv

In nanocontacts between normal and ferromagnetic metals (N--F) abrupt changes of the order of 1% are detected in differential resistance, dV/dI(V), versus bias voltage, V, on achieving of high current densities, ~10^9 A/cm^2. These features in dV/dI(V) are observed when the electron flow is directed from the nonmagnet…

Materials Sciencecond-mat.other

Advantages of a Lowe-Andersen thermostat in molecular dynamics simulations

Evert A. Koopman、Chris Lowe2006-05-19The Journal of Chemical Physics

The Lowe-Andersen thermostat is a momentum conserving and Galilean invariant analog of the Andersen thermostat. Like the Andersen thermostat it has the advantage of being local. We show that by using a minimal thermostat interaction radius in a molecular dynamics simulation, it perturbs the system dynamics to a far le…

Material Dynamics and PropertiesBlock Copolymer Self-AssemblyNanopore and Nanochannel Transport Studies

KOH Activation of Needle Coke to Develop Activated Carbons for High-Performance EDLC

Wenming Qiao、Seong‐Ho Yoon、Isao Mochida2006-05-19Energy & Fuels

Petroleum-based needle coke was activated by KOH to develop high-performance activated carbons as carbon electrodes for an electric double-layer capacitor (EDLC). The effect of preparation parameters on the properties of activated carbons was investigated, and their EDLC properties were measured in an organic electrol…

Electrocatalysts for Energy ConversionSupercapacitor Materials and FabricationConducting polymers and applications

Heat flow in nonlinear molecular junctions: Master equation analysis

Dvira Segal2006-05-19Physical Review B

We investigate the heat conduction properties of molecular junctions comprising nonlinear interactions. We find that these interactions can lead to phenomena such as negative differential thermal conductance and heat rectification. Based on analytically solvable models we derive an expression for the heat current that…

Thermal properties of materialsMechanical and Optical ResonatorsThermal Radiation and Cooling Technologies

Adsorbate vibrational modes enhancement of radiative heat transfer and van der Waals friction

A. I. Volokitin、B. N. J. Persson2006-05-19arXiv

We study the dependence of the heat transfer and the van der Waals friction between two semi-infinite solids on the dielectric properties of the bodies. We show that the heat transfer and van der Waals friction at short separation between the solids may increase by many orders of magnitude when the surfaces are covere…

Materials Sciencecond-mat.other

Enhancement of noncontact friction between closely spaced bodies by two-dimensional systems

A. I. Volokitin、B. N. J. Persson2006-05-19arXiv

. We consider the effect of an external bias voltage and the spatial variation of the surface potential, on the damping of cantilever vibrations. The electrostatic friction is due to energy losses in the sample created by the electromagnetic field from the oscillating charges induced on the surface of the tip by the b…

Materials Sciencecond-mat.other

Quantum field theory of the van der Waals friction

A. I. Volokitin、B. N. J. Persson2006-05-19arXiv

The van der Waals friction between two semi-infinite solids, and between a small neutral particle and semi-infinite solid is reconsidered on the basis of thermal quantum field theory in the Matsubara formulation. The calculation of the friction to linear order in the sliding velocity is reduced to the finding of the e…

Materials Sciencecond-mat.other

Concept study for a high-efficiency nanowire based thermoelectric

M. F. O'Dwyer、T. E. Humphrey、Heiner Linke2006-05-19Nanotechnology

Materials capable of highly efficient, direct thermal-to-electric energy conversion would have substantial economic potential. Theory predicts that thermoelectric efficiencies approaching the Carnot limit can be achieved at low temperatures in one-dimensional conductors that contain an energy filter such as a double-b…

Advanced Thermoelectric Materials and DevicesAdvanced Thermodynamics and Statistical MechanicsThermal Radiation and Cooling Technologies

Calculated electronic structure and x-ray magnetic circular dichroism of CrO2

V. Kanchana、G. Vaitheeswaran、M. Alouani2006-05-19Journal of Physics Condensed Matter

A theoretical study of the electronic structure and magnetic properties of the half-metallic ferromagnet CrO 2 is performed by means of the relativistic full-potential linear muffin-tin orbital method within the generalized gradient approximation (GGA) to the exchange correlation potential. The calculated spin and orb…

Magnetic properties of thin filmsCopper-based nanomaterials and applicationsHeusler alloys: electronic and magnetic properties

Transient terahertz conductivity in photoexcited silicon nanocrystal films

David G. Cooke、A. Nicole MacDonald、Aaron C. Hryciw 等 7 位作者2006-05-19Physical Review B

Time-resolved terahertz spectroscopy is used to probe ultrafast carrier dynamics and terahertz conductivity in photoexcited thin films of silicon nanocrystals, polynanocrystalline silicon, and epitaxial silicon-on-sapphire. We show that a Drude-Smith model provides an excellent fit to the observed transient terahertz…

Terahertz technology and applicationsSilicon Nanostructures and PhotoluminescenceSemiconductor materials and interfaces