Materials Literature
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2D nanoelectronics based on single-layer MoS[subscript 2] offers great advantages for both conventional and ubiquitous applications. This paper discusses the large-scale CVD growth of single-layer MoS[subscript 2] and fabrication of integrated devices and circuits for the first time. Fundamental building blocks of dig…
전자를 끌어당기는 benzotriazole을 vinylene으로 thiophene과 연결한 3-(2-benzo-triazolovinyl)thiophene (BVT)을 합성하고, FT-IR 및 1H-NMR, 13C-NMR, 2D hetero-cosy spectra로 구조분석을 하였다. 합성한 BVT와 3-octylthiophene (OT)을 공중합 하였다. 공중합체들은 수평균 분자량 12000 (PDI 2.67)과 15000 (PDI 2.55)을 나타내었으며, THF, TCE와 chloroform 등의 유기용매에 잘 용해되었다. 공중합체들의 BVT와 OT의 공중합된…
The goal of this paper is to present the influence of temperature variation and iron substitution with Co on the structure and electrical properties of amorphous Fe75-xCoxCr1B7Si17 alloys (where x=1, 4, 7, and 10 at.%), obtained by melt-spinning technique. The electrical resistivity of the samples was measured by usin…
Scope and Method of Study: The purpose of this research work is to investigate polymer nanomaterial interaction to understand the properties of the polymer nanocomposites. The first part of the dissertation explored the dispersion of single-walled carbon nanotubes (SWNTs) that are non-covalently wrapped with a crossli…
To address the practical issues of polymer molecular weight determination, the first accurate polymer weight-average molecular weight determination method in diverse living/controlled polymerization via DOSY (diffusion-ordered NMR spectroscopy) is reported. Based on the linear correlation between the logarithm of diff…
Bio-composites have attracted considerable attention from the industry as potential substitutes for petroleum-derived composites. Starch is a potential candidate because it is biodegradable and is readily available sustainable polymer from agriculture resources. However, it is not easy to process like petroleum-derive…
The distinct optical properties of noble metal nanoparticles that stem from localized surface plasmon resonance (LSPR) have fascinated scientists for centuries. In recent years, frequency-shift LSPR sensors have been receiving intense attention for chemical/biological sensing. In this work, an SO2 nanosensor based on…
A Saltstone waste form was prepared in the Savannah River National Laboratory (SRNL) from a Tank 50H sample and Z-Area premix material for the third quarter of calendar year 2012 (3QCY12). After a 34 day cure, samples of the saltstone were collected, and the waste form was shown to meet the South Carolina Hazardous Wa…
Coherency elastic strain between γ and is one of the effective factors which affect the morphology, spatial re-arrangement and coarsening kinetics of precipitates in nickel-base superalloys. In this investigation, using X-ray diffraction (XRD) technique, the - constrained and unconstrained lattice misfits wer…
Dissertation presented to obtain the Ph.D degree in Chemistry.
Abstract not provided.
In 1963, by studying properties of volume hologram, P. J. van Heerden mathematically demonstrated that storing optical information in solids has huge potentials of capacity and data rate. In the search for future ”ultra” storage technologies volume holography is therefore considered as a potential candidate. In late 1…
Wetting phenomena plays a crucial role in a wide range of technological applications. Spreading of liquids on solids involving phase change is encountered in many areas ranging from biological systems to industrial applications such as coatings, printing, painting and spraying. The fundamental study on wetting of memb…
Binuclear complex, [N(n-C4H9)4][MnIIFeIII(ox)3] (ox=oxalate), has been synthesized and characterized. Binuclear complex with formula of [N(n-C4H9)4][MnIIFeIII(ox)3] was synthesized by forming precursor K3[Fe(ox)3] which was followed by adding manganese chloride and tetrabutyl ammonium chloride. Characteization of the…
전자·통신 산업이 발달하면서 도전성 재료의 사용이 증가하게 되었다. 그에 따라 주로 사용되어오던 귀금속들을 대신할 저렴한 재료들이 필요하게 되었다. 그 중 구리는 귀금속에 비해 값이 저렴하고, 유사한 열·전기적 특성을 가졌지만 대기 중에서 쉽게 산화가 되는 문제점이 있다. 산화를 방지하기 위해서는 제조공정이 복잡해져 사용에 제한이 되어왔다. 구리의 산화 방지를 위한 방법 중 하나로 산화에 강한 금속을 Core-Shell 구조로 도금시켜 고유의 특성을 유지하며 산화를 방지하는 방법이 있다. 본 연구에서는 무전해 도금법으로 구리분말에 주석(Sn) 도금을 했고, 도금에…
본 연구에서는 용액 중 플라즈마 공정을 이용하여 젤라틴/Ag 나노입자(AgNP) 용액을 제조하고 동결건조하여 3차원비계 형태의 생체복합재료를 성공적으로 제조하였다. 본 공정에서는 환원제 사용 없이 플라즈마 방전 중 수소 라디칼과 Ag 이온의 환원을 통해, 젤라틴 기지재 내에 지름 12~20nm 크기의 구형 AgNP가 효과적으로 형성되었다. 젤라틴 농도가 높을수록(3%) AgNP의 분산안정성이 좋았으며, 3차원비계 형태의 젤라틴의 미세공 조직이 작아지고 밀도가 높아지는 것으로 나타났다. 또한 AgNP의 농도가 높을수록(5mM) 항균효과가 좋았는데, Ag5G3 생체복합…
There are many remote traffic signals on the road that don’t have access to a regular power supply, so they use batteries that need to be changed quite often. A hydrogen fuel cell is an electrochemical device that combines hydrogen and oxygen to produce electricity. It offers a clean and high-efficiency energy source…
Abstract not provided.
將CuCl2．2H2O、吡啶－2，4－雙羧酸和1，10－菲羅啉加水混合，利用水熱合成反應，得到單核的銅（Ⅱ）錯合物，其化學式為[Cu(pdaH)2]．2H2O（1）（其中pdaH2=吡啶－2，4－雙羧酸）。利用X-Ray晶體繞射儀、FT-IR光譜儀、示差掃瞄量熱儀及元素分析儀，測定產物晶體結構及性質，結果顯示化合物（1）是以銅（Ⅱ）離子為配位中心，含兩個O原子，以及兩個N原子，和兩個未配位水分子；氧原子分別來自兩個吡啶雙羧酸上的第二位置的O原子，氮原子分別為兩個雙羧酸吡啶環上的氮原子，配位構成平面四方型的幾何結構。由於吡啶雙羧酸及配位水分子，經由分子間的氫鍵作用（O-H･･･O），亦有O-H･･･π及C-H･･･π吡啶環間的吸引力…
An alternatives analysis was performed for the Advanced Post-Irradiation Capabilities (APIEC) project in accordance with the U.S. Department of Energy (DOE) Order DOE O 413.3B, “Program and Project Management for the Acquisition of Capital Assets”. The Alternatives Analysis considered six major alternatives: ? No Acti…