Materials Literature
按标题、摘要、年份、主题和来源检索公开元数据。结果保留作者、摘要、分类与原始来源链接。
Two different phases of spin-crossover cis-bis(thiocyanato)-bis(N-2′-pyridylmethylene)-4-(aminobiphenyl) iron(II), Fe(PM-BiA)2(NCS)2 have been investigated by EPR in X- and Q-bands. The EPR parameters for Mn2± show that the phase II has similar behavior to intentionally doped compound. EPR spectra as function of the t…
Abstract A two‐layer model was developed to accurately represent low thermal IR emittance paint coatings. The coatings were formed by mixing aluminum flakes with polymeric binders. Because of the different densities of these two components, a two‐layer structure was constructed with a pure polymeric layer on top and a…
Blaßgelbe Einkristalle des bislang chloridreichsten Selten-Erd(III)-Sulfidchlorids mit der Zusammensetzung Sm2SCl4 erhält man durch Oxidation von Samarium-Metall mit Schwefel im molaren Verhältnis von 2 : 3 in einer Schmelze aus überschüssigem SmCl3 bei 850 °C (7 d) in evakuierten Quarzglasampullen. In der Kristallstr…
The temperature dependences of 7 Li and 15 N NMR spin-lattice relaxation times and spectra in LiNO 2 were measured in the range 120 K -473 K (m.p.). The 180°-flip motion of NO 2-- ions along or perpendicular to the molecular C 2 -axis and the self-diffusion of Li + ions (activation energies of 42 -44 and 100 kJ mol -1…
Amorphous polymers are viscoelastic materials. When they are subjected to dynamical loads, their behavior can be modeled by transform functions of stress and strain in the complex plane. In our work, a model based on the fractional calculus concept is proposed in order to predict the viscoelastic behavior of polymethy…
A dynamic Monte Carlo (MC) simulation is performed to investigate the phase behavior of mixtures of flexible polymers and low molecular weight thermotropic liquid crystals (LCs). The polymer is represented by three-dimensional self-avoiding lattice chains, while the LC is described by the Lebwohl-Lasher nematogen mode…
Chromium dioxide, CrO2, attracts significant interest as it has a unique electronic band structure, resulting in half-metallic ferromagnetism (TC ≈︂ 390 K) with completely spin-polarized electrons at EF. In this work we report the polarized Raman spectra of CrO2 between 5 and 420 K, as obtained from (110) and (001) or…
The properties of the mechanical behavior of porous ceramic based on partially stabilized zirconium dioxide are studied. The special features of the mechanical behavior of ceramic with different degrees of porosity are determined. It is shown that three macrodeformation mechanisms are observed simultaneously in the ma…
The development is described of a new environmental TLD dosemeter badge and dose computation algorithm based on the new LiF:Mg,Cu,P material. LiF:Mg,Cu,P, with its high sensitivity, tissue equivalence, energy independence, and low fading characteristics, is a natural choice for environmental dosimetry. The badge consi…
The crystal structures of a series of dithiadiazolyl free radicals, p-XC6F4CNSSN (X˭F,Cl,Br and CN) are described in terms of dipolar interactions which induce chain-like motifs in the solid state. When X˭CN two morphologies are observed; the β-phase is polar and undergoes a phase transition to a weakly ferromagnetic…
Poly(propylene)/aromatic polyamide blends were prepared by melt mixing, without or with the addition of an interfacial modifier, viz. a poly(propylene) polymer grafted with 1 wt.-% of maleic anhydride. The characteristics of these polymer blends were investigated by differential scanning calorimetry, dynamic mechanica…
The Lifshitz–van der Waals theory has been used to calculate the contact angles of dispersive liquids and solids: diiodomethane, α-bromonaphtalene, methylnaphtalene, benzene, and n-octane, liquids on polytetrafluoroethylene, polystyrene, polyisobutene, polyvinylchloride, and polyethylene. The theoretical calculation o…
Different methods for characterizing the morphology of multiphase blends were applied to a blend of thermoplastic polyurethane with 20 wt% polypropylene as the dispersed phase. Optical microscopy, scanning electron microscopy (SEM), transmission electron microscopy (TEM), atomic force microscopy (AFM), and light scatt…
In applications like space satellites, high-energy physics experiments, and nuclear power stations, epoxy structural adhesives are normally used in an ionizing radiation environment. To check the effects of γ-irradiation on room temperature epoxy adhesives, mechanical measurements were undertaken for three different r…
The stress-strain behaviour of polyethylene, determined from mechanical tests at constant true strain rate, is characterized by high strain hardening in uniaxial tension and strain softening in simple shear. The strong influence of the deformation path is correlated with the different crystalline textures developed. T…
The microstructure of Al-Zn alloys, with the Zn atom fraction, x(Zn) less than or equal to 62%, has been studied in detail by XRD in dependence on the composition, temperature and previous thermal treatment. Precipitation phenomena in alloys, transferred to the supersaturated state by rapid quenching from the solid so…
During the oxidation of zircaloy fuel cladding, large stresses develop in the oxide layer, due to the volumetric expansion related to phase change. The present paper deals with intermediate temperatures, typically 300-450°C. (1) The first section of the paper shows that the local geometry of interface must be taken in…
For improved understnding of the transport of low-molecular substances' in moderately hydrophobic polymers, the temperature dependence of water vapor sorption and diffusion in poly-(3-hydroxybutyrate) (PHB) was studied for the first time. Equilibrium sorption and diffusion kinetics were determined by a quartz McBain's…
The surface properties of two block copolyurethanes based on 1,2-ethylene bis(4-phenyl isocyanate) (P2PDI), poly(tetramethylene ether glycol) (PTMG) or poly(propylene glycol) (PPG), and ethylene diamine, were investigated by attenuated total reflectance (ATR) infrared spectroscopy and X-ray photoelectron spectroscopy…
The compatibilization of mixtures of polyolefins or of polyolefins with polystyrene using either liquid polybutadiene (l-PB)/organic peroxide or styrene-butadiene-styrene (SBS) block copolymers was investigated. Tensile impact strength was chosen as a measure of compatibility. Binary blends LDPE/high-impact polystyren…